摘要:
Adhesive bonds can be formed by a process that includes applying a dispersion containing a polyurethane which has structural units of formula (I) —N═C═N— (I) to a surface. The dispersion is first coated onto the surface to form a coating. The coating is dried to give an essentially anhydrous coating. The dried coating is then subjected to heat activation. The adhesive bond is formed by joining the heat activated coating to itself or to another surface.
摘要:
Latent-crosslinking aqueous polyurethane dispersions comprising I) a disperse phase (P.I) comprising Ia) a polyurethane (Ia) which carries carbodiimide groups in addition to hydrophilic groups which make it dispersible in water but carries essentially no carboxyl groups or Ib) a physical mixture of Ibi) a polyurethane (Ibi) which carries hydrophilic groups which make it dispersible in water but carries essentially no carbodiimide or carboxyl groups and Ibii) a carbodiimide (Ibii) which carries essentially no hydrophilic groups which make it dispersible in water, and II) a disperse phase (P.II) comprising another polymer (II) which carries carboxyl groups and essentially no carbodiimide groups.
摘要:
A formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl groups can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, is useful as binder for renewable raw materials in the form of fibers or chips to produce shaped articles.
摘要:
Aqueous formulations comprising: i) at least one film-forming polymer A constructed from ethylenically unsaturated monomers M and present in dispersed form in the aqueous formulation, said monomers M comprising at least one monethylenically unsaturated monomer M1 of the formula I where X, R1, R2 and R3 are as defined in claim 1 and ii) at least one compound B having two or more aldehyde groups are used for coating substrates consisting essentially of polyurethanes.
摘要:
The present invention relates to a method of coating substrates, especially those with a hydrophobic surface, in which the substrate to be coated is coated with a coating composition whose binder is a formulation comprising an aqueous polymer dispersion in which the polymer has carbonyl or oxirane groups (component a)), and at least one compound having at least two NH.sub.2 groups per molecule, is applied to the substrate to be coated �sic!. It also relates to coating compositions including such binder formulations, and furthermore to a method of sealing using a sealing composition including such formulations as its binder.
摘要:
A dispersion or solution of a free radical polymer, polycondensate or polyadduct, which consist of from 0.001 to 20% by weight of aldehyde groups --CHO or keto groups --CO--, contains, as a crosslinking agent, a compound having at least two H.sub.2 N--O---groups or oxime ether groups derived therefrom.
摘要:
Aqueous dispersions which contain a synthetic polymer obtained by free radical polymerization and a rosin are prepared by a process in which an aqueous dispersion of the synthetic polymer obtained by free radical polymerization is mixed with an aqueous formulation of a rosin which contains from 0.1 to 0.5 mol, based on 100 g of rosin, of carboxyl groups.
摘要:
Low molecular weight polymers of acrylic esters which are suitable for use as external plasticizers in coated compositions on a synthetic resin basis are obtainable by subjecting(a) from 80 to 100% by weight of at least one acrylic ester of C.sub.1 -C.sub.8 -alkanol (monomer I) and(b) 0 to 20% by weight of one or more other copolymerizable monomers (monomer II)to a free radical polymerization in a solution in isopropanol in a pressure vessel at 130.degree.-140.degree. C. by introducing first from 70 to 95% by weight of a solvent and adding the remainder of the polymerization batch continuously over 3-7 hours in separate portions of which one contains the monomers and, after the polymerization has ended, distilling off the solvent under reduced pressure, the weight proportion of solvent being 5-15% by weight based on the monomers, the weight proportion of initiator being 0.5-3% by weight based on the monomers, and the half-life of the initiator at the polymerization temperature being from 10 seconds to 3 hours.
摘要:
A process for the preparation of aqueous polymer dispersions which have a low film-forming temperature but still give films having a high block resistance, and the use of these polymer dispersions as binders for coating materials.
摘要:
A process for the preparation of aqueous epoxy resin dispersions, wherein an epoxy resin having more than one 1,2-epoxide group per molecule is reacted with from 1 to 30% by weight, based on epoxy resin, of a protective colloid, containing basic nitrogen and having an amine number of from 10 to 90, in the presence of from 50 to 1,000 mole percent, relative to the amount of basic nitrogen in the protective colloid, of an acid, and in the presence or absence of one or more organic solvents, at from 50.degree. to 150.degree. C., the reaction product is dispersed by adding water, and any organic solvent present is distilled off. The novel aqueous epoxy resin dispersions are used, for example, to produce coatings.