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公开(公告)号：US5414054A
公开(公告)日：1995-05-09
申请号：US252295
申请日：1994-06-01
申请人： Erik H. Jonsson , Rick L. Archey , Robert J. Kumpf , Aaron D. Meltzer , Harald Pielartzik , Raymond A. Yourd
发明人： Erik H. Jonsson , Rick L. Archey , Robert J. Kumpf , Aaron D. Meltzer , Harald Pielartzik , Raymond A. Yourd
IPC分类号： C08G63/695 , C08G64/00 , C08G64/18 , C08G64/42 , C08G77/448 , C08G77/48 , C08G81/00 , C08G63/64
CPC分类号： C08G77/448 , C08G64/186
摘要： A thermoplastic copolycarbonate resin having improved low temperature impact strength and a process for the preparation of the resin are disclosed. Accordingly the structure of the copolycarbonate contains(i) units of the formula ##STR1## wherein D is a divalent residue of a dihydroxy compound, and (ii) units of the formula ##STR2## wherein m is 1-90, n is 5-300, R is an alkyl or a phenyl radical p is 2-12 and q is 2-20. The preparation of the copolycarbonate entails reactive blending of polycarbonate with a suitable lactone siloxane copolymer in the presence of a transesterification catalyst.
摘要翻译： 公开了具有改进的低温冲击强度的热塑性共聚碳酸酯树脂和制备树脂的方法。 因此，共聚碳酸酯的结构包含（i）式“IMAGE”的单元，其中D是二羟基化合物的二价残基，和（ii）下式的单元，其中m是1-90，n是5- 300，R是烷基或苯基，p是2-12，q是2-20。 在酯交换催化剂存在下，共聚碳酸酯的制备需要聚碳酸酯与合适的内酯硅氧烷共聚物的反应性共混。
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公开(公告)号：US5364913A
公开(公告)日：1994-11-15
申请号：US98531
申请日：1993-07-28
IPC分类号： C08G18/02 , C08G18/60 , C08G18/70 , C08L33/24 , C09D177/00 , C08F283/04 , C08L67/00
CPC分类号： C08G18/02 , C08G18/701
摘要： A thermosetting composition is prepared by reacting a highly crosslinked nylon-1 which contains structural units corresponding to ##STR1## where R is an organic radical with a isocyanate-reactive compound. In carrying out the reaction the molar ratio of carbonyl groups to NCO-reactive groups is about 0.5:1 to 20:1. Desirable properties characterize the reaction product thus prepared.
摘要翻译： 通过使含有对应于其中R为有机基团的结构单元的高度交联的尼龙-1与异氰酸酯反应性化合物反应来制备热固性组合物。 在进行反应时，羰基与NCO反应性基团的摩尔比为约0.5:1至20:1。 所需的性能表征如此制备的反应产物。
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公开(公告)号：US5102935A
公开(公告)日：1992-04-07
申请号：US403133
申请日：1989-09-05
申请人： Hans-Detlef Heinz , Harald Pielartzik , Aziz El-Sayed , Rolf-Volker Meyer , Martin Wandel , Peter-Roger Nyssen
发明人： Hans-Detlef Heinz , Harald Pielartzik , Aziz El-Sayed , Rolf-Volker Meyer , Martin Wandel , Peter-Roger Nyssen
摘要： The invention relates to new, free-flowing polyamide molding compounds and blends, characterized in that they are prepared by mixing of polyamides known per se in the melt with low molecular weight, liquid-crystalline esters and/or ester amides corresponding to formula (I) and/or liquid-crystalline, oligomeric esters and/or ester amides corresponding to formula (II) and, optionally, other additives, at least one polymeric blending component being used as a further additive in the case of polyamide blends, and to the use of these liquid-crystalline (LC) additives I and/or II as flow promoters in polyamide molding compounds and blends and to a process for the production of the new polyamide molding compounds and blends. The invention also relates to the new oligomeric esters and/or ester amides corresponding to formula (II).
摘要翻译： 本发明涉及新的自由流动的聚酰胺模塑料和共混物，其特征在于它们通过将熔体中本身已知的聚酰胺与对应于式（I）的低分子量，液晶酯和/或酯酰胺 ）和/或对应于式（II）的液晶，低聚酯和/或酯酰胺和任选的其它添加剂，在聚酰胺共混物的情况下使用至少一种聚合共混组分作为另外的添加剂，并且 使用这些液晶（LC）添加剂I和/或II作为聚酰胺模塑料和共混物中的流动促进剂，以及生产新的聚酰胺模塑料和共混物的方法。 本发明还涉及对应于式（II）的新的低聚酯和/或酯酰胺。
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公开(公告)号：US5071896A
公开(公告)日：1991-12-10
申请号：US632536
申请日：1990-12-24
摘要： This invention relates to polyamide moulding compounds with improved processibility; to a process for their preparation, to their use for the production of moulded parts, sheet products, fibres and composite materials and to the moulded parts, sheet products, fibres, semi-finished products, composite materials and other articles produced from these moulding compounds. The invention is characterized by the use of small quantities of special amides and/or ureas which impart significantly improved flowability to the moulding compounds.
摘要翻译： 本发明涉及具有改进的加工性的聚酰胺模塑料; 其制备方法，其用于生产模制件，片材，纤维和复合材料的用途以及由这些模塑料制成的模制件，片材产品，纤维，半成品，复合材料和其它制品 。 本发明的特征在于使用少量特殊酰胺和/或脲，其赋予模塑料显着改善的流动性。
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25.发明授权Bisesters of unsaturated carboxylic acids, their production and their use in curable mixtures 失效不饱和羧酸的Bisesters，它们的生产及其在可固化混合物中的用途
公开(公告)号：US5011972A
公开(公告)日：1991-04-30
申请号：US398991
申请日：1989-08-28
IPC分类号： C07C67/14 , C07C69/773 , C07C69/90 , C08F222/14 , C08K5/10 , C08L67/06
CPC分类号： C07C67/14 , C08F222/14
摘要： The new bisesters of unsaturated carboxylic acids corresponding to the following formula ##STR1## may be used in curable polyester resin mixtures which may in turn be used for the production of moldings. The curable mixtures obtainable from the new bisesters of unsaturated carboxylic acids show a higher glass transition temperature than normal polyester resins and, despite a higher crosslink density, show broader-mesh crosslinking.
摘要翻译： 对应于下式“IMAGE”的不饱和羧酸的新型双酚A可用于可固化的聚酯树脂混合物中，其可以用于生产模制品。 由不饱和羧酸的新型双酚A可获得的可固化混合物显示比普通聚酯树脂更高的玻璃化转变温度，尽管交联密度较高，但显示较宽的网状交联。
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公开(公告)号：US6093793A
公开(公告)日：2000-07-25
申请号：US8986
申请日：1998-01-20
申请人： Jorg Hofmann , Pramod Gupta , Harald Pielartzik
发明人： Jorg Hofmann , Pramod Gupta , Harald Pielartzik
CPC分类号： C08G65/266
摘要： Polyether polyols are produced by acid-catalyzed polyaddition of alkylene oxides to starter compounds having active hydrogen atoms. Perfluoroalkylsulfonic acid salts of metals from Group IIIA of the Periodic Table of Elements (corresponding to the IUPAC Convention of 1970) are used as the catalyst. The polyaddition reaction is carried out at a temperature of from 40 to 200.degree. C. at normal pressure or pressures from 0 to 20 mbar (absolute). An inert organic solvent may optionally be included in the reaction mixture. Substantially all of the catalyst is removed from the polyether polyol-containing reaction mixture by lowering the temperature and/or by addition of a precipitating agent and/or by extraction with water. If desired, the recovered catalyst may be used in subsequent polyaddition reactions.
摘要翻译： 聚醚多元醇通过酸式催化加成环氧烷生成具有活性氢原子的起始化合物来制备。 使用元素周期表IIIA族金属的全氟烷基磺酸盐（对应于1970年的IUPAC公约）作为催化剂。 加成反应在常压或0至20毫巴（绝对）的压力下在40至200℃的温度下进行。 惰性有机溶剂可以任选地包括在反应混合物中。 通过降低温度和/或通过加入沉淀剂和/或通过用水萃取，将基本上所有的催化剂从含聚醚多元醇的反应混合物中除去。 如果需要，回收的催化剂可用于随后的加聚反应。
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27.发明授权High heat resistant molded parts produced by structural reaction injection molding 失效通过结构反应注射成型生产的高耐热成型部件
公开(公告)号：US5688590A
公开(公告)日：1997-11-18
申请号：US517541
申请日：1995-08-21
IPC分类号： B29C45/00 , B29C45/14 , B29K75/00 , B29K105/08 , C08G18/32 , C08G18/65 , C08G18/66 , C08G18/76 , C08J5/04 , C08J5/10
CPC分类号： C08G18/3256 , C08G18/6685 , C08G2120/00 , Y10S525/92 , Y10S525/935 , Y10T428/249994 , Y10T428/31551 , Y10T428/31601
摘要： The invention is directed to a process for preparing SRIM molded article. The process broadly requires the use of a fiber reinforcement mat which is placed inside the mold cavity, and then a polyurethane reaction system is injected into the mold. The system comprising a polyisocyanate and a blend of active hydrogen containing compounds requires aldimines as part of the blend of active hydrogen containing compounds.
摘要翻译： 本发明涉及一种制备SRIM模塑制品的方法。 该方法广泛地需要使用放置在模腔内的纤维增强垫，然后将聚氨酯反应体系注入模具中。 包含多异氰酸酯和含活性氢化合物的共混物的体系需要Aldimines作为含活性氢化合物的共混物的一部分。
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公开(公告)号：US5399658A
公开(公告)日：1995-03-21
申请号：US146284
申请日：1993-10-29
CPC分类号： C08G64/42 , C08G64/081 , C08L69/00
摘要： A gamma radiation-resistant polycarbonate-disulfide resin is disclosed. The incorporation of disulfide linkages in the structure of polycarbonate was found to enhance the resistance of the resin to the discoloration caused by exposure to gamma radiation. Accordingly, processes for the incorporation of disulfide linkages in the molecular backbone, as end-groups or as side chains are disclosed. The polycarbonate-disulfide resin may be used as a molding resin in the context of thermoplastic molding compositions as well as a stabilizing additive in polycarbonate resin.
摘要翻译： 公开了一种耐伽马辐射的聚碳酸酯 - 二硫化物树脂。 发现在聚碳酸酯结构中引入二硫键增加了树脂对由于暴露于γ辐射引起的变色的抵抗力。 因此，公开了在分子主链中作为端基或作为侧链引入二硫键的方法。 聚碳酸酯 - 二硫化物树脂可以在热塑性模塑组合物和聚碳酸酯树脂中的稳定添加剂的情况下用作模制树脂。
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29.发明授权Modified polyester resins, a process for their preparation and toners containing such polyester resins 失效改性聚酯树脂，其制备方法和含有这种聚酯树脂的调色剂
公开(公告)号：US5368968A
公开(公告)日：1994-11-29
申请号：US800196
申请日：1991-11-27
申请人： Rolf Wehrmann , Matthias Kocher , Harald Pielartzik , Gunter Klug
发明人： Rolf Wehrmann , Matthias Kocher , Harald Pielartzik , Gunter Klug
IPC分类号： C08G63/12 , C08G63/16 , C08G63/20 , C08G63/60 , C08G63/78 , C08G63/91 , G03G9/087 , G03G9/083
CPC分类号： C08G63/60 , C08G63/20 , G03G9/08755
摘要： Modified polyester resins contain polyester blocks which have been obtained from dicarboxylic acids and dialcohols, groupings of the formulae ##STR1## where X=Z=a hydrocarbon radical having 1 to 20 C atoms and Y=a hydrocarbon radical having 2 to 25 C atoms, and if appropriate groupings originating from crosslinking agents. They can be used as base polymers for toners.
摘要翻译： 改性聚酯树脂含有由二羧酸和二醇得到的聚酯嵌段，其中X = Z =具有1-20个碳原子的烃基，Y =具有2-25个C原子的烃基的式 以及来自交联剂的适当组合。 它们可用作调色剂的基础聚合物。
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30.发明授权
公开(公告)号：US5169907A
公开(公告)日：1992-12-08
申请号：US614787
申请日：1990-11-14
CPC分类号： C08G64/183 , C08G81/00
摘要： A block copolymer represented by the formula ##STR1## are formed by contracting an ester group containing poly(aryl ether) composed of the recurring units ##STR2## with a polyarylcarbonate composed of the recurring units ##STR3## in which B, Z, E.sup.5, E.sup.1, E.sup.2 x, y, n and p represent specified groups or valuesunder conditions such that ester/carbonate interchange reactions will occur.
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