公开(公告)号：US09540457B1

公开(公告)日：2017-01-10

申请号：US14863528

申请日：2015-09-24

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Lloyd W. Guatney ,  Jeffrey F. Greco

IPC: C08F4/52 ,  C08F4/64 ,  C08F4/76 ,  B01J37/00 ,  C08F4/6592 ,  B01J21/12 ,  B01J31/16 ,  B01J37/26 ,  B01J37/02 ,  B01J31/22 ,  C08F4/10 ,  C08F4/02 ,  C08F4/68

CPC classification number: C08F4/65927 ,  B01J21/12 ,  B01J31/1616 ,  B01J31/2295 ,  B01J37/024 ,  B01J37/26 ,  C08F4/02 ,  C08F4/10 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/68 ,  C08F4/76 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/6343 ,  C08F4/6543 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/12

Abstract: Catalyst systems having both a metallocene catalyst component and a Ziegler-type catalyst component are disclosed. Such catalyst systems can contain a metallocene compound, a co-catalyst, and a supported catalyst containing a fluorided silica-coated alumina, a magnesium compound, and vanadium and/or tetravalent titanium.

Abstract translation: 公开了具有金属茂催化剂组分和齐格勒型催化剂组分的催化剂体系。 这种催化剂体系可以含有茂金属化合物，助催化剂和含有氟化二氧化硅涂覆的氧化铝，镁化合物和钒和/或四价钛的负载型催化剂。

公开(公告)号：US20150126692A1

公开(公告)日：2015-05-07

申请号：US14072819

申请日：2013-11-06

Applicant: Chevron Phillips Chemical Company LP

Inventor： Ashish M. Sukhadia ,  Max P. McDaniel ,  Errun Ding ,  Guylaine St. Jean ,  Qing Yang ,  Daniel G. Hert ,  Chung Ching Tso

IPC: C08F210/16 ,  C08J5/18

CPC classification number: C08F10/02 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/02 ,  C08F210/08 ,  C08F210/14 ,  C08F210/16 ,  C08F2410/02 ,  C08F2420/01 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/26

Abstract: Disclosed herein are ethylene-based polymers produced using dual metallocene catalyst systems. These polymers have low densities, high molecular weights, and broad molecular weight distributions, as well as having the majority of the long chain branches in the lower molecular weight component of the polymer, and the majority of the short chain branches in the higher molecular weight component of the polymer. Films produced from these polymers have improved impact and puncture resistance.

Abstract translation: 本文公开了使用双金属茂催化剂体系制备的基于乙烯的聚合物。 这些聚合物具有低密度，高分子量和宽分子量分布，以及在聚合物的较低分子量组分中具有大多数长链分支，并且大部分分子量较高的短链分支 聚合物的组分。 由这些聚合物制成的膜具有改善的抗冲击性和抗穿刺性。

公开(公告)号：US09006367B2

公开(公告)日：2015-04-14

申请号：US14072828

申请日：2013-11-06

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Ashish M. Sukhadia ,  Errun Ding ,  Chung Ching Tso ,  Albert P. Masino ,  Qing Yang ,  Lloyd W. Guatney ,  Guylaine St. Jean ,  Daniel G. Hert

IPC: C08F210/02 ,  C08F210/16 ,  C08F210/14 ,  C08J5/18 ,  C08L23/08

CPC classification number: C08F210/16 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/14 ,  C08F2410/02 ,  C08F2500/05 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  C08F4/65904 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/26

Abstract: Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.

Abstract translation: 本文公开了具有在0.895至0.930g / cm 3范围内的密度并具有改善的耐冲击性和抗撕裂性的宽分子量分布烯烃聚合物。 这些聚合物可以具有8至35范围内的Mw / Mn比，4至50范围内的高负荷熔体指数，每1000个总碳原子小于约0.008LCB，反向共聚单体分布。

公开(公告)号：US20150065669A1

公开(公告)日：2015-03-05

申请号：US14018455

申请日：2013-09-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Errun Ding ,  Paul DesLauriers ,  Yongwoo Inn ,  Lili Cui ,  Qing Yang ,  Ashish Sukhadia ,  Guylaine St. Jean ,  Richard M. Buck

IPC: C08F4/6592 ,  C08F210/16

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/12

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有两种或三种茂金属组分的催化剂体系，产生可具有中等密度和改善的抗应力开裂性的乙烯基共聚物。

公开(公告)号：US08865846B2

公开(公告)日：2014-10-21

申请号：US13625898

申请日：2012-09-25

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Youlu Yu ,  Lloyd W. Guatney ,  Jim B. Askew

IPC: C08F4/642 ,  C08F4/643 ,  C08F4/6592 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10 ,  C08F4/659 ,  C08F10/00

CPC classification number: C08F4/76 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/02 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10 ,  C08F110/02 ,  C08F2500/04 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有锆或铪基茂金属化合物和含有茚基的钛基半茂金属化合物的双重催化剂体系。

公开(公告)号：US08748546B2

公开(公告)日：2014-06-10

申请号：US13888419

申请日：2013-05-07

Applicant: Chevron Phillips Chemical Company LP

Inventor： Albert P. Masino ,  Rex E. Murray ,  Qing Yang ,  Steve J. Secora ,  Kumudini C. Jayaratne ,  William B. Beaulieu ,  Errun Ding ,  Gary L. Glass ,  Alan L. Solenberger ,  Ted H. Cymbaluk

IPC: C08F4/653 ,  C08F4/642 ,  C08F4/643 ,  C08F4/6592

CPC classification number: C08F4/642 ,  C08F4/12 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/76 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/14

Abstract: The present invention provides dual catalyst systems and polymerization processes employing these dual catalyst systems. The disclosed polymerization processes can produce olefin polymers at higher production rates, and these olefin polymers may have a higher molecular weight and/or a lower melt index.

Abstract translation: 本发明提供了使用这些双重催化剂体系的双重催化剂体系和聚合方法。 公开的聚合方法可以以更高的生产速率生产烯烃聚合物，并且这些烯烃聚合物可以具有较高的分子量和/或较低的熔体指数。

公开(公告)号：US20140128563A1

公开(公告)日：2014-05-08

申请号：US14072828

申请日：2013-11-06

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Ashish M. Sukhadia ,  Errun Ding ,  Chung Ching Tso ,  Albert P. Masino ,  Qing Yang ,  Lloyd W. Guatney ,  Guylaine St. Jean ,  Daniel G. Hert

IPC: C08F210/14

CPC classification number: C08F210/16 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/14 ,  C08F2410/02 ,  C08F2500/05 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  C08F4/65904 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/26

Abstract: Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.

Abstract translation: 本文公开了具有在0.895至0.930g / cm 3范围内的密度并具有改善的耐冲击性和抗撕裂性的宽分子量分布烯烃聚合物。 这些聚合物可以具有8至35范围内的Mw / Mn比，4至50范围内的高负荷熔体指数，每1000个总碳原子小于约0.008LCB，反向共聚单体分布。

公开(公告)号：US11851505B2

公开(公告)日：2023-12-26

申请号：US17142312

申请日：2021-01-06

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Randall S. Muninger ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F10/02 ,  C08F2/34 ,  C08F4/6592

CPC classification number: C08F10/02 ,  C08F2/34 ,  C08F4/65922 ,  C08F2500/01 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17

Abstract: Disclosed herein are ethylene-based polymers generally characterized by a melt index of less than 1 g/10 min, a density from 0.93 to 0.965 g/cm3, a CY-a parameter at 190° C. of less than 0.2, an average number of short chain branches per 1000 total carbon atoms of the polymer in a molecular weight range of 400,000 to 600,000 g/mol that is greater than that in a molecular weight range of 40,000 to 60,000 g/mol, and an average number of long chain branches per 1000 total carbon atoms of the polymer in a molecular weight range of 400,000 to 600,000 g/mol that is greater than that in a molecular weight range of 4,000,000 to 6,000,000 g/mol. The ethylene polymers can be used to fabricate pipes, blown films, and blow molded products, and the ethylene polymers can be produced with a dual catalyst system containing a single atom bridged or two carbon atom bridged metallocene compound with two indenyl groups or an indenyl group and a cyclopentadienyl group, and a single atom bridged metallocene compound with a fluorenyl group and a cyclopentadienyl group with an alkenyl substituent.

公开(公告)号：US20220267579A1

公开(公告)日：2022-08-25

申请号：US17732628

申请日：2022-04-29

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung Ching Tso ,  Max P. McDaniel ,  Ashish M. Sukhadia ,  Youlu Yu ,  Randall S. Muninger ,  Aaron M. Osborn ,  Christopher E. Wittner

IPC: C08L23/08 ,  C08F4/6592 ,  C08F210/16

Abstract: Disclosed herein are ethylene-based polymers generally characterized by a melt index of less than 15 g/10 min, a density from 0.91 to 0.945 g/cm3, a CY-a parameter at 190° C. from 0.2 to 0.6, an average number of long chain branches per 1,000,000 total carbon atoms of the polymer in a molecular weight range of 500,000 to 2,000,000 g/mol of less than 5, and a maximum ratio of ηE/3η at an extensional rate of 0.03 sec−1 in a range from 3 to 15. The ethylene polymers have substantially no long chain branching in the high molecular weight fraction of the polymer, but instead have significant long chain branching in the lower molecular weight fraction, such that polymer melt strength and bubble stability are maintained for the fabrication of blown films and other articles of manufacture. These ethylene polymers can be produced using a dual catalyst system containing a single atom bridged metallocene compound with an indenyl group and a cyclopentadienyl group, and an unbridged hafnium metallocene compound with two cyclopentadienyl groups.

公开(公告)号：US11174378B2

公开(公告)日：2021-11-16

申请号：US17237119

申请日：2021-04-22

Applicant: Chevron Phillips Chemical Company LP

Inventor： Chung Ching Tso ,  Errun Ding ,  Randall S. Muninger ,  John T. Blagg ,  Yongwoo Inn ,  Max P. McDaniel ,  Ashish M. Sukhadia ,  Sarah Eppinger

IPC: C08F210/16 ,  C08L23/06 ,  C08F4/6592 ,  C08L23/16

Abstract: Ethylene polymers having a density from 0.908 to 0.925 g/cm3, a melt index from 0.5 to 3 g/10 min, a ratio of Mw/Mn from 2 to 4, a ratio of Mz/Mw from 1.6 to 2.3, a CY-a parameter from 0.45 to 0.6, and an ATREF profile characterized by a single peak at a peak ATREF temperature from 76 to 88° C., and by less than 4.5 wt. % of the polymer eluting above a temperature of 91° C. These ethylene polymers can be used to produce various articles of manufacture, such as blown and cast films with a beneficial combination of high tear resistance and low haze.