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    Synthesis of vinyl polymers by controlled radical polymerization
    21.
    发明授权
    Synthesis of vinyl polymers by controlled radical polymerization 失效
    通过控制自由基聚合合成乙烯基聚合物

    公开(公告)号：US07351781B2

    公开(公告)日：2008-04-01

    申请号：US11041154

    申请日：2005-01-21

    申请人： Daniela White ,  James B. O'Dwyer

    发明人： Daniela White ,  James B. O'Dwyer

    IPC分类号： C08F4/04

    CPC分类号： C08F4/00 ,  C08F2/32 ,  C08F293/005

    摘要： A controlled free radical polymerization process, which includes the steps of: adding a monofunctional iniferter compound to an oxygen-free solvent; heating the solution to a temperature sufficient to allow the iniferter compound to form two carbon centered radical residues; adding a first monomer composition comprising one or more monomers to the solution containing the radical containing residues; polymerizing the first monomer composition to form a quasi-living polymer; and optionally polymerizing a second monomer composition comprising one or more monomers, which are different than the first monomer composition. The resulting non-random copolymer having the general formula: φ-[-Ap-Bs-]t-φ where A and B are different compositions of ethylenically unsaturated monomers; p is an integer from 1 to 1,000; s is an integer from 0 to 1,000; t is an integer from 1 to 100; and φ is a residue from the iniferter.

    摘要翻译： 一种受控的自由基聚合方法，其包括以下步骤：将单官能异构体化合物加入到无氧溶剂中; 将溶液加热至足以允许引发剂化合物形成两个碳中心自由基残基的温度; 将含有一种或多种单体的第一单体组合物加入到含有基团的残基的溶液中; 聚合第一单体组合物以形成准活性聚合物; 并且任选地聚合包含与第一单体组合物不同的一种或多种单体的第二单体组合物。 所得到的具有以下通式的非无规共聚物：<？in-line-formula description =“In-line Formulas”end =“lead”？> phi - [ - A

    其中A和B是不饱和烯键式的不同组成，其中A和B是不同组成的烯键式不饱和键 单体; p是1至1,000的整数; s是0到1,000之间的整数; t为1〜100的整数; phi是来自引物的残基。

    Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization
    25.
    发明授权
    Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization 失效
    含有使用原子转移自由基聚合制备的羟基官能聚合物的热固性组合物

    公开(公告)号：US06517905B2

    公开(公告)日：2003-02-11

    申请号：US09964964

    申请日：2001-09-27

    申请人： Daniela White ,  James B. O'Dwyer ,  Dennis A. Simpson

    发明人： Daniela White ,  James B. O'Dwyer ,  Dennis A. Simpson

    IPC分类号： C08F440

    CPC分类号： C08L53/00 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/01 ,  C08G18/6229 ,  C09D153/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  C08L2666/02

    摘要： A thermosetting composition that includes: (a) a crosslinking agent having at least two functional groups reactive with hydroxyl groups; and (b) a non-gelled, hydroxyl functional polymer prepared by atom transfer radical polymerization. The polymer contains at least one of the following polymer chain structures: —{(M)p—(G)q}x—  or —{(G)q—(M)p}x— wherein M is a residue, that is free of hydroxyl functionality, of at least one monomer; G is a residue, that has hydroxyl functionality, of at least one monomer; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q, and x are each independently selected for each structure such that the hydroxyl functional polymer has a number average molecular weight of at least 250. Also provided are methods of coating a substrate using compositions of the present invention and substrates coated by such methods, as well as color-plus-clear composite coatings.

    摘要翻译： 一种热固性组合物，其包括：（a）具有至少两个与羟基反应的官能团的交联剂; 和（b）通过原子转移自由基聚合制备的非胶凝的羟基官能聚合物。 该聚合物含有至少一种以下聚合物链结构：或其中M是至少一种单体不含羟基官能团的残基; G是具有至少一个单体的羟基官能团的残基; p和q表示在每个聚合物链结构的残基块中发生的残基的平均数目; 对于每种结构，p，q和x各自独立地选择，使得羟基官能聚合物的数均分子量为至少250.还提供了使用本发明的组合物涂覆底物的方法和由其涂覆的底物 方法，以及彩色+透明复合涂层。

    Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization
    26.
    发明授权
    Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization 有权
    含有使用原子转移自由基聚合制备的羟基官能聚合物的热固性组合物

    公开(公告)号：US06319987B1

    公开(公告)日：2001-11-20

    申请号：US09375019

    申请日：1999-08-16

    申请人： Daniela White ,  James B. O'Dwyer ,  Dennis A. Simpson

    发明人： Daniela White ,  James B. O'Dwyer ,  Dennis A. Simpson

    IPC分类号： C08L5300

    CPC分类号： C08L53/00 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/01 ,  C08G18/6229 ,  C09D153/00 ,  Y10T428/31504 ,  Y10T428/31855 ,  C08L2666/02

    摘要： A thermosetting composition is provided comprising: (a) a crosslinking agent having at least two functional groups that are reactive with hydroxyl groups; and (b) a non-gelled, hydroxyl functional polymer prepared by atom transfer radical polymerization, in the presence of an initiator having at least one radically transferable group. The polymer contains at least one of the following polymer chain structures: —{(M)p—(G)q}x— or —{(G)q—(M)p}x— wherein M is a residue, that is free of hydroxyl functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has hydroxyl functionality, of at least one ethylenically unsaturated radically polymerizable monomer; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q, and x are each independently selected for each structure such that the hydroxyl functional polymer has a number average molecular weight of at least 250.

    摘要翻译： 提供一种热固性组合物，其包括：（a）具有至少两个与羟基反应的官能团的交联剂; 和（b）在具有至少一个可自由基转移基团的引发剂的存在下通过原子转移自由基聚合制备的非胶凝的羟基官能聚合物。 聚合物含有至少一种以下聚合物链结构：或其中M是至少一种烯属不饱和自由基聚合单体的残基，其不含羟基官能团; G是具有至少一个烯属不饱和自由基聚合性单体的羟基官能团的残基; p和q表示在每个聚合物链结构的残基块中发生的残基的平均数目; 对于每种结构，p，q和x各自独立地选择，使得羟基官能聚合物的数均分子量至少为250。

    Thermosetting compositions containing epoxy functional polymers prepared by atom transfer radical polymerization
    29.
    发明授权
    Thermosetting compositions containing epoxy functional polymers prepared by atom transfer radical polymerization 失效
    含有通过原子转移自由基聚合制备的环氧官能聚合物的热固性组合物

    公开(公告)号：US06472085B2

    公开(公告)日：2002-10-29

    申请号：US09864904

    申请日：2001-05-24

    申请人： Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

    发明人： Karen A. Barkac ,  Simion Coca ,  James R. Franks ,  Kurt A. Humbert ,  Paul H. Lamers ,  Roxalana L. Martin ,  James B. O'Dwyer ,  Kurt G. Olson ,  Daniela White

    IPC分类号： B32B1508

    CPC分类号： C08G59/3209 ,  C08G59/4207 ,  Y10T428/31699 ,  Y10T428/31928

    摘要： A multi-component composite coating composition comprising a base coat deposited from a pigmented film-forming composition and a transparent top coat applied over the base coat in which the base coat is a thermosetting composition comprising a co-reactable solid, particulate mixture of (i) an epoxy functional polymer containing at least one of the polymer chain structures -[(M)p-(G)q]x- or -[(G)q-(M)p]x- wherein M is an oxirane-free residue of at least one ethylenically unsaturated monomer, G is a glycidyl-functional ethylenically unsaturated monomer, p and q each independently has a value of 0 to typically less than 100, and x has a value of at least 1 to typically less than 100, the total value of p, q and x selected such that said epoxy functional polymer has a number average molecular weight of at least 250, and (ii) a co-reactant having functional groups reactive with the epoxy groups of (i). The epoxy functional polymer is prepared by atom transfer radical polymerization and has a polydispersity index of less than 2.5.

    摘要翻译： 一种多组分复合涂料组合物，其包含从着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明顶涂层，其中底涂层为热固性组合物，其包含可共反应的固体，（i ）包含至少一种聚合物链结构的环氧官能聚合物 - [（M）p-（G）q] x-或 - [（G）q-（M）p] x-，其中M是无环氧乙烷 至少一种烯属不饱和单体的残基，G是缩水甘油基官能的烯属不饱和单体，p和q各自独立地具有0至典型地小于100的值，x具有至少1至通常小于100的值， 所选择的p，q和x的总值使得所述环氧官能聚合物的数均分子量至少为250，和（ii）具有与（i）的环氧基反应的官能团的共反应物。 环氧官能聚合物通过原子转移自由基聚合制备，多分散指数小于2.5。