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公开(公告)号：US09988547B2
公开(公告)日：2018-06-05
申请号：US14949159
申请日：2015-11-23
发明人： James C. Bohling , Wei Gao , Michael W. Leonard , Qing Zhang
IPC分类号： C09D125/12 , C08F275/00 , C08J3/18 , C09D133/08 , C09C1/36 , C08J3/205 , C09C3/10 , C09D5/02 , C09D7/12 , C08F265/04 , C08F285/00 , C08F8/44 , C08K3/22 , C09D17/00
CPC分类号： C09D125/12 , C01P2004/62 , C08F8/44 , C08F265/04 , C08F275/00 , C08F285/00 , C08F2800/20 , C08J3/18 , C08J3/205 , C08J2333/12 , C08J2425/12 , C08J2433/08 , C08K3/22 , C08K2003/2241 , C08L2207/53 , C09C1/3676 , C09C3/10 , C09D5/027 , C09D5/028 , C09D7/65 , C09D7/68 , C09D7/69 , C09D7/70 , C09D17/008 , C09D133/08 , C08F212/08 , C08F230/02 , C08F2220/1825 , C08L51/003
摘要： The present invention relates to opaque polymers functionalized with phosphorus acid groups, composites of TiO2 particles and the opaque polymers, and methods for their preparation. The composites are useful in coatings formulations and have been shown to exhibit improved hiding benefits in coated substrates over compositions containing non-functionalized opaque polymer and TiO2.
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公开(公告)号：US09796793B2
公开(公告)日：2017-10-24
申请号：US14479113
申请日：2014-09-05
申请人： The Regents of the University of California , Dow Global Technologies LLC , Rohm and Haas Company
CPC分类号： C08B37/0024 , B01J20/3204 , B01J20/3272 , B01J20/3274 , B01J20/3278 , B01J20/3289 , C01P2002/88 , C01P2004/03 , C01P2004/04 , C08B11/20 , C09C1/3054 , C09C1/3072 , C09C1/3081 , C09C1/309 , C09C1/3661 , C09C1/3676 , C09C1/3684 , C09C1/3692 , C09C1/407 , C09C3/10 , C09D101/28 , C09D105/00
摘要： The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.
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23.发明申请公开(公告)号：US20170096575A1
公开(公告)日：2017-04-06
申请号：US15311624
申请日：2014-06-20
发明人： Wei Cui , Tao Wang , Longlan Cui , James C. Bohling
IPC分类号： C09D133/14 , C08F220/18
CPC分类号： C09D133/14 , C08F220/18 , C08F275/00 , C08F2220/1825 , C08L2308/00 , C09D133/08 , C09D143/02 , C09D151/003 , C08F230/02 , C08F212/08 , C08F220/14 , C08F220/06 , C08F220/40
摘要： A latex polymer of multi-stage polymerization comprising a first stage polymer and a second stage polymer wherein the first stage polymer comprises a first portion of an acrylic monomer and a first portion of a phosphorus acid monomer, and the second stage polymer comprises a second portion of an acrylic monomer and a second portion of a phosphorus acid monomer. A process of making such latex polymer.
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公开(公告)号：US09528023B2
公开(公告)日：2016-12-27
申请号：US14650875
申请日：2013-12-11
CPC分类号： C09D133/12 , C08K9/02 , C09D5/00 , C09D7/00 , C09D7/62
摘要： The present invention relates to a stable aqueous dispersion of multiphase amphoteric polymer particles comprising a crosslinked polymer phase comprising structural units of a phosphorus acid monomer, a carboxylic acid monomer, a multiethylenically unsaturated monomer, and an ethylenically unsaturated nonionic monomer; and a second polymer phase comprising a carboxylic acid monomer and an ethylenically unsaturated nonionic monomer. The present invention also relates to composites of the particles and pigment particles such as TiO2. The composition is useful for preparing dried coatings with improved hiding.
摘要翻译： 本发明涉及多相两性聚合物颗粒的稳定水性分散体，其包含含有磷酸单体，羧酸单体，多烯属不饱和单体和烯属不饱和非离子单体的结构单元的交联聚合物相; 和包含羧酸单体和烯属不饱和非离子单体的第二聚合物相。 本发明还涉及颗粒和颜料颗粒如TiO 2的复合材料。 该组合物可用于制备具有改进隐藏性的干燥涂料。
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公开(公告)号：US20160152854A1
公开(公告)日：2016-06-02
申请号：US14949159
申请日：2015-11-23
发明人： James C. Bohling , Wei Gao , Michael W. Leonard , Qing Zhang
IPC分类号： C09D125/12 , C09D133/08 , C08J3/18
CPC分类号： C09D125/12 , C01P2004/62 , C08F8/44 , C08F265/04 , C08F275/00 , C08F285/00 , C08F2800/20 , C08J3/18 , C08J3/205 , C08J2333/12 , C08J2425/12 , C08J2433/08 , C08K3/22 , C08K2003/2241 , C08L2207/53 , C09C1/3676 , C09C3/10 , C09D5/027 , C09D5/028 , C09D7/65 , C09D7/68 , C09D7/69 , C09D7/70 , C09D17/008 , C09D133/08 , C08F212/08 , C08F230/02 , C08F2220/1825 , C08L51/003
摘要： The present invention relates to opaque polymers functionalized with phosphorus acid groups, composites of TiO2 particles and the opaque polymers, and methods for their preparation. The composites are useful in coatings formulations and have been shown to exhibit improved hiding benefits in coated substrates over compositions containing non-functionalized opaque polymer and TiO2.
摘要翻译： 本发明涉及用磷酸基官能化的不透明聚合物，TiO 2颗粒和不透明聚合物的复合材料及其制备方法。 复合材料在涂料配方中是有用的，并且已显示出在涂覆的基材上显示出比非官能化的不透明聚合物和TiO 2的组合物具有改进的隐藏效果。
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公开(公告)号：US20210332259A1
公开(公告)日：2021-10-28
申请号：US17270698
申请日：2018-10-16
发明人： Yan Li , Junyu Chen , Cheng Shen , James C. Bohling , Zhi Juan Gong , Tao Wang
IPC分类号： C09D133/08 , C08F220/14 , C08L43/02 , C08F2/22 , C08L71/02 , C09D133/12 , C08F220/18
摘要： An aqueous dispersion of polymeric particles comprising an emulsion polymer and a polyalkylene oxide with a weight average molecular weight in the range of 450 to 1,500 g/mole, and an aqueous coating composition with low VOCs comprising the aqueous dispersion and providing coatings made therefrom with improved water whitening resistance and hardness.
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公开(公告)号：US10968284B2
公开(公告)日：2021-04-06
申请号：US15422925
申请日：2017-02-02
申请人： The Regents of the University of California , Dow Global Technologies LLC , Rohm and Haas Company
IPC分类号： C08B37/00 , C09D105/00 , C09C1/36 , C09C3/10 , C09C1/30 , B01J20/32 , C08B11/20 , C09C1/40 , C09D101/28
摘要： The present invention is a multilayered composite comprising porous metal oxide particles that are covalently bonded by way of inorganic ether groups to one or more sites of a first polyhydroxyl-functionalized polymer. This first polymer is in turn covalently bonded by way of inorganic ether groups to one or more sites of a second polyhydroxyl-functionalized polymer. The multilayered composites can be prepared by contacting porous inorganic-oxide particles with a sufficient amount of OH-reactive crosslinking agent to form metal oxide particles imbibed with the crosslinking agent, and then contacting the inorganic-oxide particles with a solution of polyhydroxyl-functionalized polymer under reactive conditions.
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公开(公告)号：US20200172745A1
公开(公告)日：2020-06-04
申请号：US16628062
申请日：2017-07-11
发明人： Daoshu Lin , Jianming Xu , Qingwei Zhang , James C. Bohling , Paul Doll , Jian Zou , Liu Yang , Gongwei Pu
IPC分类号： C09D7/65 , C09D133/06 , C09D125/14 , C09D7/40 , C09D7/20
摘要： An aqueous dispersion having reduced VOCs and/or odor and an aqueous coating composition comprising the aqueous dispersion.
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29.发明申请公开(公告)号：US20190322889A1
公开(公告)日：2019-10-24
申请号：US16299470
申请日：2019-03-12
发明人： James C. Bohling , Pu Luo , Qing Zhang
IPC分类号： C09D125/14 , C09D7/45 , C09D7/43 , C09D5/16
摘要： The present invention is related to a coating composition comprising a) an aqueous dispersion of acrylic or styrene-acrylic polymer particles functionalized with structural units of a monomer with keto functionality and structural units of a phosphorus acid monomer; b) a dispersant comprising structural units of a carboxylic acid monomer and a monomer with keto functionality; and c) a dihydrazide crosslinking agent. The composition of the present invention is useful for improving scrub resistance in a coating formed from the composition.
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30.发明授权公开(公告)号：US10227500B2
公开(公告)日：2019-03-12
申请号：US15311624
申请日：2014-06-20
发明人： Wei Cui , Tao Wang , Longlan Cui , James C. Bohling
IPC分类号： C08F275/00 , C08F230/02 , C09D133/14 , C08F220/18 , C09D133/08 , C09D151/00 , C09D143/02
摘要： A latex polymer of multi-stage polymerization comprising a first stage polymer and a second stage polymer wherein the first stage polymer comprises a first portion of an acrylic monomer and a first portion of a phosphorus acid monomer, and the second stage polymer comprises a second portion of an acrylic monomer and a second portion of a phosphorus acid monomer. A process of making such latex polymer.
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