摘要:
A process for improving the intercoat adhesion in a multicoat paint system utilizing a primer coat, an aqueous basecoat, and a clearcoat, where the multicoat paint system has been produced by means of a wet-on-wet technique. The clearcoat is produced using a pseudoplastic powder clearcoat slurry prepared by a secondary dispersion process or a melt emulsification process. The aqueous basecoat material used to produce the aqueous basecoat comprises a dispersed graft copolymer whose particles are composed of a hydrophobic core of copolymerized olefinically unsaturated monomers and of a hydrophilic shell which comprises a polyurethane, wher said copolymer is prepared by free-radical (co)polymerization of the monomers in the presence of at least one polyurethane containing specially selected olefinically unsaturated groups.
摘要:
A hydrophilic or hydrophobic polyurethane having at least one olefinically unsaturated group selected from the group consisting of pendant olefinically unsaturated groups, terminal olefinically unsaturated groups, and mixtures thereo wherein the pendant olefinically unsaturated groups are sele consisting of pendant olefinically unsaturated groups which are attached to a cycloaliphatic group which represents a link in the polymer main chain and pendant olefinically unsaturated groups which are present as a double bond in a cycloolefinic group which constitutes a link in the polymer main chain, and the terminal olefinically unsaturated groups are selected from the group consisting of terminal olefinically unsaturated groups which are attached to a cycloaliphatic group which forms an endgroup of the polymer main chain and terminal olefinically unsaturated groups which are present as a double bond in a cycloolefinic structure which forms en endgroup of the polymer main chain.
摘要:
Self crosslinking polyurethane comprising lateral or terminal ethenylarylene groups, produced by reacting a polyurethane pre-polymer with an adduct, obtained by reacting an ethenylarylene mono-isocyanate with a compound containing hydroxyl groups or amino groups such that at least one group that is reactive to isocyanate remains in the adduct. Also, a self crosslinking graft copolymer containing at least one (meth)acrylate copolymer and at least one polyurethane produced by dispersing at least one self crosslinking olefinically unsaturated polyurethane comprising lateral or terminal ethenylarylene groups and blocked isocyanate groups in an aqueous medium and by radical copolymerization of a mixture of a monomer comprising at least one functional group that is reactive to isocyanate with a monomer that can be copolymerised with the mixture.
摘要:
The present invention relates to a method of coating substrates, preferably of metal, by cleaning the substrate surface, applying, if desired, an organic and/or inorganic pretreatment composition, applying a primer, applying a coating material by spraying, dipping, knifecoating, rollercoating or brushing, the coating material comprising an amine-modified epoxy resin and a crosslinking agent suitable for crosslinking.
摘要:
The present invention relates to films coated with two or more coats, whereinA the surface of a plastic film having a thickness of from 10 to 500 .mu.m is coated if desired with a filler composition,B the surface of the plastic film, or the filler coat, is overcoated with at least one pigmented paint coat,C the pigmented paint coat is coated if desired with a transparent plastic film.
摘要:
The present invention relates to films for coating molding blanks, wherein the surface of a pigmented plastic base film having a thickness of from 10 to 500 .mu.m is coated if desired with an affect coat, if desired with a transparent varnish coat or with a transparent plastic film.
摘要:
The invention relates to a process for the preparation of a two-coat finish on a substrate surface, in which process a basecoat is employed which contains as binder a polymer which can be obtained by subjecting an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers to free-radical polymerization in an aqueous dispersion of a polyurethane resin which has a number-average molecular weight of from 1000 to 30,000 and contains on average from 0.05 to 1.1 polymerizable double bonds per molecule, and in the presence of a water-insoluble initiator or of a mixture of water-insoluble initiators, the weight ratio of the polyurethane resin to the ethylenically unsaturated monomer or to the mixture of ethylenically unsaturated monomers being between 1:10 and 10:1.
摘要:
The invention relates to coating materials containing a water-dilutable polyurethane resin as binder. The resin can be prepared by reacting some of the free isocyanate groups present in a prepolymer (I) which contains acidic groups and isocyanate groups with a blocking agent so as to form a prepolymer (II) which contains blocked isocyanate groups, the blocking agent being employed in a quantity such that the prepolymer (II) still contains on average at least one free isocyanate group per molecule, reacting the prepolymer (II) with a compound which contains at least one primary or secondary amino group and at least one hydroxyl group in the molecule, to give a polyurethane resin, and finally converting the polyurethane resin prepared in this way into a water-dilutable polyurethane resin by at least partial neutralization of the acidic groups.
摘要:
Solvent-containing clearcoat coating composition comprising (A) an OH-functional (meth)acrylate (co)polymer comprising (A1) 30%-99% by weight, based on the mass of the nonvolatile fraction of (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and glass transition temperature Tg of 15° C. to 100° C., and (A2) 1%-70% by weight, based on the mass of the nonvolatile fraction of (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of −100° C. to −20° C., (B) a crosslinker component comprising functional groups reactive toward OH, (C) 0.02%-1.2% by weight, based on the mass of the nonvolatile fraction of (A), of at least one polyamide and (D) 0.04%-2.9% by weight, based on the mass of the nonvolatile fraction of (A), of at least one urea adduct of a polyisocyanate and benzylamine.
摘要:
Water-based coating composition comprising at least one resin composition for a water-based coating composition and as a rheological assistant at least one polyamide and at least one acrylate thickener based on poly(meth)acrylic acid.