Method for improving the adhseion of the intermediate layer in a multi-layer paint finish
    21.
    发明申请
    Method for improving the adhseion of the intermediate layer in a multi-layer paint finish 有权
    改善多层漆面中间层的吸附性的方法

    公开(公告)号:US20060193989A1

    公开(公告)日:2006-08-31

    申请号:US10549055

    申请日:2004-03-03

    申请人: Egon Wegner

    发明人: Egon Wegner

    IPC分类号: B05D3/02 B05D7/00

    摘要: A process for improving the intercoat adhesion in a multicoat paint system utilizing a primer coat, an aqueous basecoat, and a clearcoat, where the multicoat paint system has been produced by means of a wet-on-wet technique. The clearcoat is produced using a pseudoplastic powder clearcoat slurry prepared by a secondary dispersion process or a melt emulsification process. The aqueous basecoat material used to produce the aqueous basecoat comprises a dispersed graft copolymer whose particles are composed of a hydrophobic core of copolymerized olefinically unsaturated monomers and of a hydrophilic shell which comprises a polyurethane, wher said copolymer is prepared by free-radical (co)polymerization of the monomers in the presence of at least one polyurethane containing specially selected olefinically unsaturated groups.

    摘要翻译: 一种利用底漆涂层,底漆底漆和透明涂料在多涂漆系统中改进涂层间附着力的方法,其中通过湿法湿式技术生产多涂漆体系。 使用通过二次分散法或熔融乳化法制备的假塑性粉末透明涂料浆料制备透明涂层。 用于制备水性底漆的水性底漆材料包括分散的接枝共聚物,其颗粒由共聚的烯属不饱和单体的疏水核心和包含聚氨酯的亲水壳组成,所述共聚物由自由基(共) 在含有特别选择的烯属不饱和基团的至少一种聚氨酯的存在下聚合单体。

    Self crosslinking polyurethanes and graft copolymers and based on polyurethane, for producing coating materials, adhesives and sealing masses
    23.
    发明授权
    Self crosslinking polyurethanes and graft copolymers and based on polyurethane, for producing coating materials, adhesives and sealing masses 有权
    自交联聚氨酯和接枝共聚物,基于聚氨酯,用于生产涂料,粘合剂和密封块

    公开(公告)号:US06602972B1

    公开(公告)日:2003-08-05

    申请号:US10111730

    申请日:2002-04-26

    IPC分类号: C08G1880

    摘要: Self crosslinking polyurethane comprising lateral or terminal ethenylarylene groups, produced by reacting a polyurethane pre-polymer with an adduct, obtained by reacting an ethenylarylene mono-isocyanate with a compound containing hydroxyl groups or amino groups such that at least one group that is reactive to isocyanate remains in the adduct. Also, a self crosslinking graft copolymer containing at least one (meth)acrylate copolymer and at least one polyurethane produced by dispersing at least one self crosslinking olefinically unsaturated polyurethane comprising lateral or terminal ethenylarylene groups and blocked isocyanate groups in an aqueous medium and by radical copolymerization of a mixture of a monomer comprising at least one functional group that is reactive to isocyanate with a monomer that can be copolymerised with the mixture.

    摘要翻译: 自交联聚氨酯,其包含通过使聚氨酯预聚物与加成物反应制得的侧链或末端乙烯基亚苯基,其通过使乙烯基亚芳基单异氰酸酯与含羟基或氨基的化合物反应获得,使得至少一个与异氰酸酯反应的基团 保留在加合物中。 此外,含有至少一种(甲基)丙烯酸酯共聚物和至少一种聚氨酯的自交联接枝共聚物,其通过将包含侧链或末端乙烯基亚芳基和封端异氰酸酯基团的至少一种自交联烯属不饱和聚氨酯分散在水性介质中并通过自由基共聚 包含至少一种与异氰酸酯反应的官能团的单体与可与该混合物共聚的单体的混合物的混合物。

    Process for the preparation of a two-coat finish, and aqueous coating
materials
    27.
    发明授权
    Process for the preparation of a two-coat finish, and aqueous coating materials 失效
    双层涂层的制备方法和水性涂料

    公开(公告)号:US6001424A

    公开(公告)日:1999-12-14

    申请号:US646288

    申请日:1996-05-16

    CPC分类号: B05D7/532 C09D151/08

    摘要: The invention relates to a process for the preparation of a two-coat finish on a substrate surface, in which process a basecoat is employed which contains as binder a polymer which can be obtained by subjecting an ethylenically unsaturated monomer or a mixture of ethylenically unsaturated monomers to free-radical polymerization in an aqueous dispersion of a polyurethane resin which has a number-average molecular weight of from 1000 to 30,000 and contains on average from 0.05 to 1.1 polymerizable double bonds per molecule, and in the presence of a water-insoluble initiator or of a mixture of water-insoluble initiators, the weight ratio of the polyurethane resin to the ethylenically unsaturated monomer or to the mixture of ethylenically unsaturated monomers being between 1:10 and 10:1.

    摘要翻译: PCT No.PCT / EP94 / 03824 Sec。 371日期:1996年5月16日 102(e)日期1996年5月16日PCT 1994年11月18日PCT公布。 公开号WO95 / 14721 日期1995年6月1日本发明涉及一种在基材表面上制备双层涂层的方法,其中使用底漆,其含有作为粘合剂的聚合物,该聚合物可以通过使烯属不饱和单体或 烯属不饱和单体的混合物在数均分子量为1000〜30,000的聚氨酯树脂的水性分散体中进行自由基聚合,每分子平均含有0.05〜1.1个可聚合双键,并且在 水不溶性引发剂或水不溶性引发剂的混合物,聚氨酯树脂与烯属不饱和单体的重量比或烯属不饱和单体的混合物的重量比为1:10至10:1。

    Aqueous coating materials and their use for the production of filler
coats in automotive finishing
    28.
    发明授权
    Aqueous coating materials and their use for the production of filler coats in automotive finishing 失效
    水性涂​​料及其在汽车整理中生产填料涂料的用途

    公开(公告)号:US5905132A

    公开(公告)日:1999-05-18

    申请号:US640748

    申请日:1996-05-06

    摘要: The invention relates to coating materials containing a water-dilutable polyurethane resin as binder. The resin can be prepared by reacting some of the free isocyanate groups present in a prepolymer (I) which contains acidic groups and isocyanate groups with a blocking agent so as to form a prepolymer (II) which contains blocked isocyanate groups, the blocking agent being employed in a quantity such that the prepolymer (II) still contains on average at least one free isocyanate group per molecule, reacting the prepolymer (II) with a compound which contains at least one primary or secondary amino group and at least one hydroxyl group in the molecule, to give a polyurethane resin, and finally converting the polyurethane resin prepared in this way into a water-dilutable polyurethane resin by at least partial neutralization of the acidic groups.

    摘要翻译: PCT No.PCT / EP94 / 03446 Sec。 371日期:1996年5月6日 102(e)日期1996年5月6日PCT 1994年10月20日PCT公布。 公开号WO95 / 12626 日期1995年5月11日本发明涉及含有水可稀释性聚氨酯树脂作为粘合剂的涂料。 树脂可以通过将存在于含有酸性基团和异氰酸酯基团的预聚物(I)中的一些游离异氰酸酯基与封端剂反应以形成含有封端异氰酸酯基团的预聚物(II)来制备,所述封闭剂为 其使用量使得预聚物(II)每分子平均含有至少一个游离异氰酸酯基团,使预聚物(II)与含有至少一个伯或仲氨基和至少一个羟基的化合物反应 分子,得到聚氨酯树脂,最后通过酸性基团的至少部分中和将以这种方式制备的聚氨酯树脂转化成水可稀释的聚氨酯树脂。

    SOLVENT-BORNE CLEARCOAT COATING COMPOSITION, METHOD FOR PRODUCING IT AND USE THEREOF
    29.
    发明申请
    SOLVENT-BORNE CLEARCOAT COATING COMPOSITION, METHOD FOR PRODUCING IT AND USE THEREOF 审中-公开
    溶剂-BORNE CLEARCOAT涂料组合物,其生产方法及其用途

    公开(公告)号:US20140147596A1

    公开(公告)日:2014-05-29

    申请号:US14111042

    申请日:2012-04-12

    IPC分类号: C09D133/06

    摘要: Solvent-containing clearcoat coating composition comprising (A) an OH-functional (meth)acrylate (co)polymer comprising (A1) 30%-99% by weight, based on the mass of the nonvolatile fraction of (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and glass transition temperature Tg of 15° C. to 100° C., and (A2) 1%-70% by weight, based on the mass of the nonvolatile fraction of (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of −100° C. to −20° C., (B) a crosslinker component comprising functional groups reactive toward OH, (C) 0.02%-1.2% by weight, based on the mass of the nonvolatile fraction of (A), of at least one polyamide and (D) 0.04%-2.9% by weight, based on the mass of the nonvolatile fraction of (A), of at least one urea adduct of a polyisocyanate and benzylamine.

    摘要翻译: 含有溶剂的透明涂料组合物包含(A)OH-官能(甲基)丙烯酸酯(共)聚合物,其包含(A1)基于(A)的非挥发成分的质量至少为30重量%至99重量% OH值为60-200mg KOH / g的OH官能(甲基)丙烯酸酯(共)聚合物,玻璃化转变温度Tg为15℃至100℃,和(A2)1%-70% 至少一种羟值为60-200mg KOH / g的OH-官能(甲基)丙烯酸酯(共)聚合物和玻璃化转变温度Tg为 - (B)包含对OH有反应性的官能团的交联剂组分,(C)基于(A)的不挥发物组分的质量为0.02重量%-2.2重量%的交联剂组分, 至少一种聚酰胺和(D)0.04%-2.9重量%,基于(A)的不挥发成分的质量,至少一种多异氰酸酯和苄胺的尿素加合物。