Synthesis of Cu/SAPO-34 with variable copper loadings
    25.
    发明授权
    Synthesis of Cu/SAPO-34 with variable copper loadings 有权
    具有可变铜负载的Cu / SAPO-34的合成

    公开(公告)号:US09475040B2

    公开(公告)日:2016-10-25

    申请号:US13709137

    申请日:2012-12-10

    Abstract: A Cu-amine complex of hydrated copper sulfate and ethylene diamine or an oligomer of ethylene diamine is employed in a direct (one-pot) synthesis of a copper-cation containing silicoaluminophosphate (SAPO) zeolite material having the Cu/SAPO-34 structure. The copper-amine complex is included in an aqueous gel of precursors of the SiO2, Al2O3, and P2O5 constituents, which are mixed, aged, and thermally treated to form the desired Cu/SAPO-34 structure. The synthesized Cu/SAPO-34 material is demonstrated to be an effective catalyst material in conversion of nitric oxide to nitrogen (using ammonia as a reductant) in synthetic exhaust streams characteristic of diesel engine and other lean-burn vehicle engine exhaust streams.

    Abstract translation: 在具有Cu / SAPO-34结构的含铜阳离子的硅铝磷酸盐(SAPO)沸石材料的直接(一锅)合成中,使用水合硫酸铜和乙二胺或乙二胺的低聚物的Cu-胺络合物。 铜 - 胺络合物包含在SiO 2,Al 2 O 3和P 2 O 5组分的前体的水性凝胶中,其被混合,老化和热处理以形成所需的Cu / SAPO-34结构。 合成的Cu / SAPO-34材料被证明是在柴油发动机和其他贫燃汽车发动机排气流特征的合成排气流中将一氧化氮转化为氮气(使用氨作为还原剂)的有效催化剂材料。

    SYNERGISTIC COMBINATIONS OF LOW TEMPERATURE NOx ADSORBERS
    26.
    发明申请
    SYNERGISTIC COMBINATIONS OF LOW TEMPERATURE NOx ADSORBERS 审中-公开
    低温NOx吸附剂的协同组合

    公开(公告)号:US20160222852A1

    公开(公告)日:2016-08-04

    申请号:US14995441

    申请日:2016-01-14

    Abstract: Nitrogen oxides (NOx), carbon monoxide (CO), and residual hydrocarbons are adsorbed and stored from a low temperature, cold-start, diesel engine (or lean-burn gasoline engine) exhaust stream by a combination of a silver-based (Ag/Al2O3) NOx adsorber material and a zeolite-platinum group metal (zeolite-PGM) adsorber material for low temperature temporary storage of the NOx. The combination of NOx adsorber materials is formed as separate washcoats on channel walls of an extruded flow-through monolithic support. The monolith is located near the exhaust manifold of the lean burn engine where the combination of NOx adsorber particles temporarily adsorb exhaust constituents, and commence oxidation of them, until the progressively warming exhaust stream removes the stored constituents and carries them through the exhaust pipe to downstream NOx reduction converters which have been heated to their operating temperatures and complete the conversion of the NOx constituents to nitrogen and water for discharge from the vehicle's exhaust system.

    Abstract translation: 氮氧化物(NOx),一氧化碳(CO)和残留烃通过银基(Ag)的组合从低温,冷启动,柴油发动机(或稀燃汽油发动机)废气流中吸收和储存 / Al2O3)NOx吸附材料和用于低温临时储存NOx的沸石 - 铂族金属(沸石-PGM)吸附材料。 NOx吸附剂材料的组合形成为在挤出的流通整体式载体的通道壁上的单独的洗涂层。 整料位于稀燃发动机的排气歧管附近,其中NOx吸附剂颗粒的组合暂时吸附废气组分,并开始氧化,直到逐渐变暖的废气流除去储存的组分并将它们通过排气管运送到下游 已经被加热到其工作温度并完成NOx组分转化成氮气和水以从车辆排气系统排放的NOx还原转化器。

    LITHIATION ADDITIVE FOR A POSITIVE ELECTRODE

    公开(公告)号:US20230069776A1

    公开(公告)日:2023-03-02

    申请号:US17446116

    申请日:2021-08-26

    Abstract: The present disclosure provides an electrochemical cell that cycles lithium ions. The electrochemical cell includes a positive electrode and a negative electrode. The positive electrode includes a positive electroactive material and a lithiation additive blended with the positive electroactive material. The lithiation additive includes a lithium-containing material and one or more metals. The lithium-containing material is represented by LiX, where X is hydrogen (H), oxygen (O), nitrogen (N), fluorine (F), phosphorous (P), or sulfur (S). The one or more metals are selected from the group consisting of: iron (Fe), copper (Cu), cobalt (Co), manganese (Mn), and combinations thereof. The negative electrode may include a volume-expanding negative electroactive material.

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