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    Sequenced surfactant oligomers, process for preparing the same and compositions containing the same
    21.
    发明授权
    Sequenced surfactant oligomers, process for preparing the same and compositions containing the same 失效
    序列表面活性剂低聚物，其制备方法和含有它的组合物

    公开(公告)号：US4199562A

    公开(公告)日：1980-04-22

    申请号：US815847

    申请日：1977-07-14

    申请人： Guy Vanlerberghe ,  Henri Sebag

    发明人： Guy Vanlerberghe ,  Henri Sebag

    IPC分类号： A61K8/00 ,  A61K8/34 ,  A61K8/72 ,  A61K8/90 ,  A61K8/92 ,  A61K31/77 ,  A61K47/00 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/10 ,  B01F17/42 ,  C07C43/11 ,  C07C43/12 ,  C07C291/04 ,  C07C317/00 ,  C07D295/088 ,  C08G65/00 ,  C08G65/08 ,  C08G65/28 ,  C08G65/32 ,  C08G65/329 ,  C08L71/00 ,  C08L71/02 ,  C11D1/66 ,  A61K7/00

    CPC分类号： C07D295/088 ,  A61K8/90 ,  A61Q5/02 ,  A61Q5/10 ,  A61Q5/12 ,  C07C291/04 ,  C07C317/00 ,  C07C323/00 ,  C08G65/329 ,  Y10S424/01 ,  Y10S424/02 ,  Y10S424/04 ,  Y10S516/01 ,  Y10S516/05 ,  Y10S516/07

    摘要： Sequenced oligomer surfactant has the formula: P--O----C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' [C.sub.2 H.sub.3 (CH.sub.2 A)O].sub.m --C.sub.2 H.sub.3 C.sub.2 B)O].sub.n Q wherein one of P and Q represents hydrogen and the other represents alkyl having 1-20 carbon atoms; A represents R--CH.sub.2 -- or R'--O-- wherein R is alkyl having 4-16 carbon atoms and R' is alkyl having 4-20 carbon atoms; B is selected from OH, R.sub.1 R.sub.2 N, R.sub.1 R.sub.2 N.fwdarw.O, R.sub.1 R.sub.2 N--O.sup..sym. HV.sup..crclbar., R.sub.1 R.sub.2 N.sup..sym. HV.sup..crclbar., R.sub.1 R.sub.2 R.sub.3 N.sup..sym. Z.sup..crclbar. and R.sub.4 S.fwdarw.(O)a, wherein R.sub.1 and R.sub.2 represent alkyl or hydroxyalkyl, R.sub.3 is methyl or ethyl, R.sub.4 is alkyl, hydroxyalkyl or dihydroxyalkyl, Z.sup..crclbar. is an anion selected from HSO.sub.3.sup..crclbar., CH.sub.3 SO.sub.3.sup..crclbar., CH.sub.3 SO.sub.4.sup. .crclbar. and CH.sub.3 --C.sub.6 H.sub.4 --SO.sub.3.sup..crclbar., R.sub.1 R.sub.2 N.sup..sym. HV.sup..crclbar. and R.sub.1 R.sub.2 N--O.sup..sym. HV.sup..crclbar. represent a salt of an amine or amine oxide, a is 0 or 1; m is a number from 2-10; and n and n' are numbers from 2-25, with one of n and n' capable of being O.The oligomer surfactants are employed in cosmetic and pharmaceutical compositions.

    摘要翻译： 有序低聚物表面活性剂具有下式：PO-C 2 H 3（CH 2 B）O-n'[C 2 H 3（CH 2））O] m -C 2 H 3 C 2 B）O] n Q其中P和Q之一表示氢，另一个表示具有1-20 碳原子 A表示R-CH2-或R'-O-，其中R是具有4-16个碳原子的烷基，R'是具有4-20个碳原子的烷基; B选自OH，R1R2N，R1R2N-> O，R1R2N-O（+）HV（ - ），R1R2N（+）HV（ - ），R1R2R3N（+）Z（ - ）和R4S->（O） 其中R1和R2代表烷基或羟基烷基，R3是甲基或乙基，R4是烷基，羟基烷基或二羟基烷基，Z（ - ）是选自HSO3（ - ），CH3SO3（ - ），CH3SO4（ - ）和CH3-C6H4 -SO 3（ - ），R1R2N（+）HV（ - ）和R1R2N-O（+）HV（ - ）表示胺或氧化胺的盐，a为0或1; m是2-10的数字; n和n'是2-25的数，其中n和n'之一能够为O.低聚物表面活性剂用于化妆品和药物组合物中。

    Hair conditioning compositions containing crosslinked polyaminopolyamides
    22.
    发明授权
    Hair conditioning compositions containing crosslinked polyaminopolyamides 失效
    含有交联聚氨基多酰胺的调理组合物

    公开(公告)号：US4172887A

    公开(公告)日：1979-10-30

    申请号：US762804

    申请日：1977-01-26

    申请人： Guy Vanlerberghe ,  Henri Sebag ,  Jean-Francois Grollier ,  Alexandre Zysman

    发明人： Guy Vanlerberghe ,  Henri Sebag ,  Jean-Francois Grollier ,  Alexandre Zysman

    IPC分类号： A61K8/88 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/12 ,  A61K7/06 ,  A61K7/08 ,  A61K7/09 ,  A61K7/11

    CPC分类号： A61Q5/12 ,  A61K8/88 ,  A61Q5/06 ,  A61Q5/02 ,  A61Q5/04 ,  Y10S424/02

    摘要： A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer selected from the group consisting of (1) crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di- carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of epihalohydrins, diepoxides, dianhydrides and bis unsaturated derivatives, and being employed in amounts of 0.025-0.35 mole per amine group in said polyamino-polyamide and (2) the crosslinked polymer of (1) alkylated with an alkylating agent selected from the group consisting of (a) epoxides, (b) ethylenically unsaturated compounds, (c) chloroacetic acid, and (d) alkane sultone selected from the group consisting of propane sultone and butane sultone. The said crosslinked polymer is soluble in water in amounts of 10 weight percent thereof without essentially any gel formation and a 10 weight percent aqueous solution of the said crosslinked polymer has a viscosity greater than 3 centipoises at 25.degree. C.

    摘要翻译： 用于毛发的化妆品组合物包含至少一种水溶性交联聚合物，其选自（1）通过交联聚氨基 - 聚酰胺与交联剂交联而获得的交联聚合物，所述聚氨基聚酰胺是通过（a ）选自（i）有机二羧酸，（ii）烯键式不饱和脂族单或二羧酸的酸性化合物，（iii）所述酸（i）和（ii）的酯和（iv （i），（ii）和（iii）的混合物在（b）选自双原料和单 - 或二 - 仲聚亚烷基多胺的多胺中，所述多胺（b）可以由选自 由（1）0-20摩尔％六亚甲基二胺，（2）0-40摩尔％双 - 伯胺和（3）0-40摩尔％双仲胺组成的组，所述交联剂选自 的表卤代醇，二环氧化物，二酐和双 不饱和衍生物，并且在所述聚氨基聚酰胺中以每个胺基计0.025-0.35摩尔的量使用（2）（1）烷基化剂与（a）环氧化物，（b）的烷基化剂烷基化的交联聚合物 ）烯键式不饱和化合物，（c）氯乙酸和（d）选自丙烷磺内酯和丁烷磺内酯的烷基磺内酯。 所述交联聚合物以10重量％的量溶解在水中而基本上没有任何凝胶形成，并且所述交联聚合物的10重量％水溶液的粘度在25℃下具有大于3厘泊的粘度。

    Polycondensation of glycidol on alpha diols with fatty chain with alkaline catalysts, products thus obtained and utilization
    23.
    发明授权
    Polycondensation of glycidol on alpha diols with fatty chain with alkaline catalysts, products thus obtained and utilization 失效
    缩水甘油对α二醇与脂肪链与碱性催化剂的缩聚，得到的产物和利用

    公开(公告)号：US4087466A

    公开(公告)日：1978-05-02

    申请号：US678030

    申请日：1976-04-19

    申请人： Guy Vanlerberghe ,  Henri Sebag

    发明人： Guy Vanlerberghe ,  Henri Sebag

    IPC分类号： C07C41/02 ,  C07C43/10 ,  D06P3/06

    CPC分类号： A61Q5/02 ,  A61K8/39 ,  A61Q5/04 ,  A61Q5/065 ,  Y10S514/941 ,  Y10S514/975

    摘要： A method of preparing a novel non-ionic surfactant usefully employed in a cosmetic composition having the formulaR--CHOH--CH.sub.2 --O--CH.sub.2 --CHOH--CH.sub.2 --O].sub.n Hwherein R is selected from the group consisting of aliphatic, cycloaliphatic and arylaliphatic radicals and mixtures thereof having 7-21 carbon atoms, n is greater than 1 and equal to or less than 10, the method comprising condensing on an .alpha.-diol having the formulaR--CHOH--CH.sub.2 OHwherein R has the above meaning, n moles of glycidol having the formula ##STR1## in the presence of an alkaline catalyst at a temperature of 120.degree.-180.degree. C.

    摘要翻译： 一种制备可用于具有式R-CHOH-CH 2 -O-CH 2 -CHOH-CH 2 -O] n H的化妆品组合物中的新型非离子表面活性剂的方法，其中R选自脂族，脂环族和芳基脂族 具有7-21个碳原子的基团和其混合物，n大于1且等于或小于10，该方法包括在具有式R-CHOH-CH 2 OH的α-二醇上缩合，其中R具有上述含义，n摩尔 的具有式“IMAGE”的缩水甘油在碱性催化剂的存在下在120-180℃的温度下进行。

    Polyhydroxyl monosulfoxide shampoo compositions
    24.
    发明授权
    Polyhydroxyl monosulfoxide shampoo compositions 失效
    多羟基一磺酸洗发剂组合物

    公开(公告)号：US4058629A

    公开(公告)日：1977-11-15

    申请号：US703667

    申请日：1976-07-08

    申请人： Guy Vanlerberghe ,  Henri Sebag

    发明人： Guy Vanlerberghe ,  Henri Sebag

    IPC分类号： C11D1/755 ,  A61K7/50

    CPC分类号： A61Q5/02 ,  A61K8/46 ,  A61Q19/10 ,  C07C317/00 ,  C11D1/755 ,  A61Q19/00 ,  A61Q5/065 ,  A61Q5/10 ,  Y10S514/941 ,  Y10S514/943 ,  Y10S516/02 ,  Y10S516/03

    摘要： A polyhydroxyl monosulfoxide surfactant, usefully employed, for instance, in a cosmetic composition such as a shampoo, a hair dye formulation or a bath foam composition, has the formula ##STR1## wherein R is selected from the group consisting of linear or branched aliphatic saturated or unsaturated hydrocarbon having 8-22 carbon atoms, alkylbenzyl having 8-22 carbon atoms and mixtures thereof, and n has a statistical mean value greater than 1 and equal to or less than 10, and preferably 2-7.

    摘要翻译： 可用于化妆品组合物如洗发剂，染发剂制剂或浴泡沫组合物中的多羟基单亚砜表面活性剂具有下式：其中R选自直链或支链脂族饱和 或具有8-22个碳原子的不饱和烃，具有8-22个碳原子的烷基苄基及其混合物，n具有大于1且等于或小于10的统计平均值，优选2-7。

    Tensio-active polypod compounds, process for preparing them and compositions containing them
    30.
    发明授权
    Tensio-active polypod compounds, process for preparing them and compositions containing them 失效

    公开(公告)号：US4362714A

    公开(公告)日：1982-12-07

    申请号：US266992

    申请日：1981-05-26

    申请人： Henri Sebag ,  Guy Vanlerberghe

    发明人： Henri Sebag ,  Guy Vanlerberghe

    IPC分类号： A61K8/00 ,  A61K8/35 ,  A61K8/49 ,  A61Q5/02 ,  A61Q5/10 ,  B01F17/42 ,  C07D323/00 ,  C11D1/00 ,  A61K7/06

    CPC分类号： C07D323/00 ,  A61K8/4973 ,  A61Q5/02 ,  C07C323/00 ,  C07C327/00

    摘要： Tensio-active cyclic polyethers of the general formula: ##STR1## where A refers to a hydrophile block chosen from the amine, ammonium, ammonio alkyl carboxylate, ammonio alkyl sulfonate, amide, sulfonamide, ether, thioether, hydroxyl, ester and acid groupings.These polyethers may be prepared (1) by reaction of alcohol or of undecylenic acid with thioacetic acid, (2) saponification with an alkaline base, (3) reaction of the product obtained in (2) with the tetramer of epichlorohydrin or of epibromohydrin, (4) reaction of mesylate or tosylate of the compound obtained in (3) either (a) with dimethylamine or methylethanolamine, the resulting compound being able to be salified or alkylated, or (b) with the mercapto ethanol or mercapto glycerol; the compounds thereby obtained being then able to be submitted to reactions of polyaddition of ethylene oxide and/or of glycidol oxide.These tensio-active cyclic polyethers are suitable for use in the cosmetic, textile, insecticide and similar industries.