Corrosion resistant steel sheets improved in corrosion resistance and
other characteristics
    23.
    发明授权
    Corrosion resistant steel sheets improved in corrosion resistance and other characteristics 失效
    耐腐蚀钢板提高了耐腐蚀性等特点

    公开(公告)号:US5510196A

    公开(公告)日:1996-04-23

    申请号:US204298

    申请日:1994-03-08

    IPC分类号: C25D3/56 B32B15/18

    摘要: Zn--Cr alloy plated steel sheets have excellent corrosion resistance. It has now been found that the phase structures of Zn--Cr alloy platings are such that they comprise yet to be known phases .eta.x, .delta.x and .GAMMA.x. Furthermore, these phases when taken either singly or with two or more phases being mixed together, exhibit the following characteristics (1)-(6). The characteristics of the respective phases are also identified below.______________________________________(1) .eta.x Resistance to cosmetic corrosion(2) .GAMMA.x Formability(3) .eta.x + .delta.x Chipping resistance(4) .eta.x + .GAMMA.x Corrosion resistance in the as-formed state(5) .delta.x + .GAMMA.x Water resistant secondary adherence of coating(6) .eta.x + .delta.x + .GAMMA.x Perforation corrosion resistance.eta.x: Hexagonal crystal a = 2.66-2.74 .ANG. c = 4.61-4.95 .ANG..delta.x: Hexagonal crystal a = 2.72-2.78 .ANG. c = 4.43-4.60 .ANG..GAMMA.x: Cubic crystal a = 3.00-3.06 .ANG.______________________________________

    摘要翻译: PCT No.PCT / JP93 / 00956 Sec。 371日期:1994年3月8日 102(e)1994年3月8日PCT 1993年7月9日PCT公布。 第WO94 / 01602号公报 1994年1月20日.Zn-Cr合金镀层钢板具有优异的耐腐蚀性。 现在已经发现,Zn-Cr合金电镀的相结构使得它们还包括尚未知的相,ηx和GAMMA x。 此外,当单独或两相或更多相混合时,这些相具有以下特征(1) - (6)。 各个阶段的特征也在下面确定。 - (1)eta x耐化妆品腐蚀 - (2)GAMMA x成型性 - (3)eta x +δx抗剪切性 - (4)eta x + GAMMA x形成状态下的耐腐蚀性 - (5) δx + GAMMA x涂层的防水二次附着力(6)eta x + delta x + GAMMA x穿孔耐腐蚀性等级x:六方晶体a = 2.66-2.74 ANGSTROM - c = 4.61-4.95 ANGSTROM - δx :六角晶体 - a = 2.72-2.78 ANGSTROM - c = 4.43-4.60 ANGSTROM - GAMMA x:立方晶体a = 3.00-3.06 ANGSTROM -

    Method of producing zinc-chromium alloy plated steel sheet with
excellent plating adhesiveness
    24.
    发明授权
    Method of producing zinc-chromium alloy plated steel sheet with excellent plating adhesiveness 失效
    生产镀锌钢板的优良镀层粘合性的方法

    公开(公告)号:US5273643A

    公开(公告)日:1993-12-28

    申请号:US46764

    申请日:1993-04-13

    CPC分类号: C25D3/565

    摘要: The present invention provides a method of producing a zinc-chromium alloy-plated steel sheet having excellent properties such as bare corrosion resistance, corrosion resistance after coating, plating adhesiveness and weldability.The method is characterized by plating the surface of the steel sheet using an acid plating bath containing zinc ion (Zn.sup.2+) and chromium ion (Cr.sup.3+) at a molar concentration ratio of about 0.1.ltoreq.Cr.sup.3+ /(Zn.sup.3+ +Cr.sup.3+).ltoreq.0.9 in a total amount of at least about 0.5 mol/1 within the dissolution range, and about 0.1 to 30 g/1 of at least one nonionic organic additive having at least a triple bond, at a bath temperature of about 25.degree. to 70.degree. C. and a pH of about 1.0 to 4.0 with a current density of about 50 to 200 A/dm.sup.2.

    摘要翻译: 本发明提供一种具有耐腐蚀性,涂层耐蚀性,电镀粘合性和焊接性等优异性能的镀锌 - 铬合金镀覆钢板的方法。 该方法的特征在于,使用含有约0.1 Cr 3+ /(Zn 3+ ++ Cr 3+)摩尔浓度的锌离子(Zn 2+)和铬离子(Cr 3+)的酸性电镀电镀钢板的表面, 在溶解范围内的总量为至少约0.5mol / l的0.9,以及约0.1至30g / l的至少一种具有至少三重键的非离子有机添加剂,在浴温为约25℃至 70℃,pH为约1.0至4.0,电流密度为约50至200A / dm 2。