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21.
公开(公告)号:US11274198B2
公开(公告)日:2022-03-15
申请号:US16632914
申请日:2018-07-25
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Tobias Schulz , Norbert Niessner , Hans-Werner Schmidt , Tristan Kolb , Sascha Ehlert , Stephan Foerster
IPC: C08L25/08 , C08K3/013 , C08F212/08 , C08F220/18 , C08F220/44 , C08F222/06 , C08K3/22 , C08K5/00 , C08L67/00 , C08L83/04 , C08L83/10 , B82Y30/00 , B82Y40/00
Abstract: A scratch-resistant thermoplastic polymer composition (P) comprising 40 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 20 wt.-% of at least one inorganic metal compound nanoparticle, and optionally at least one polymeric compatibilizing agent, at least one modified polysiloxane compound, at least one colorant, dye or pigment, and/or at least one further additive has improved scratch properties.
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公开(公告)号:US11225571B2
公开(公告)日:2022-01-18
申请号:US16633362
申请日:2018-07-25
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Tobias Schulz , Norbert Niessner , Eike Jahnke , Hans-Werner Schmidt , Tristan Kolb
Abstract: Thermoplastic polymer compositions (P) comprising 90 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 10 wt.-% of at least one copolymer at least comprising repeating units derived from at least one α-olefin monomer and at least one vinyl-aromatic monomer, at least one inorganic phosphate compound, at least one polyolefin wax and optionally at least one colorant, dye or pigment, and/or at least one further additive show improved properties with respect to residual gloss after abrasion combined with improved melt flow characteristics while heat resistance is not affected.
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公开(公告)号:US11220594B2
公开(公告)日:2022-01-11
申请号:US16632916
申请日:2018-07-25
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Tobias Schulz , Norbert Niessner , Eike Jahnke , Hans-Werner Schmidt , Tristan Kolb
IPC: C08L25/08 , C08K3/013 , B29C45/00 , C08F212/08 , C08F220/18 , C08F220/44 , C08K5/00 , C08K5/20 , C08L23/00 , C08L69/00 , C08L77/00
Abstract: Scratch-resistant thermoplastic polymer compositions (P) comprising 90 to 99.9 wt.-% of at least one styrene-based copolymer, 0.1 to 10 wt.-% of an aliphatic amide wax additive comprising at least one aliphatic amide wax composition having a melting point in the range of 80° C. to 115° C., and optionally at least one colorant, dye, pigment and/or further additive, have improved properties.
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公开(公告)号:US10711110B2
公开(公告)日:2020-07-14
申请号:US15567480
申请日:2016-04-22
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert Niessner , Eike Jahnke
Abstract: The invention relates to a method for producing a thermoplastic fibre composite containing a thermoplastic moulding compound (A) as a polymer-matrix (M), reinforcement fibres (B), and optionally additive (C). Said method comprises the following steps: i) flat structures (F) made from reinforcing fibres (B) treated with a silane sizing material are provided, ii) the flat structures (F) are placed in a thermoplastic molding compound (A) which comprises at least 0.3 mol %, with respect to components (A), of a chemically reactive functionality, iii) chemically reactive groups of the thermoplastic molding compound (A) are reacted in the polymer matrix (M) with the polar groups of the treated reinforcing fibres (B), iv) the at least one additive (C) is optionally incorporated v) cooling. Said method is particularly suitable for producing fibrous composites.
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公开(公告)号:US10150830B2
公开(公告)日:2018-12-11
申请号:US15117364
申请日:2015-02-09
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Thomas W. Cochran , Norbert Niessner
IPC: C08F220/14 , C08F212/08 , C08L25/06 , C08L33/12 , C09D125/14
Abstract: A copolymer comprising (A) 20-50% (w/w) of methyl methacrylate (MMA), (B) 40-80% (w/w) of one or more vinylaromatic(s) and, optionally, (C) 0-10% (w/w) of one or more aliphatic vinyl(s) can be used in a polymer composition for generating translucent final products.
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公开(公告)号:US10059791B2
公开(公告)日:2018-08-28
申请号:US15103669
申请日:2014-04-16
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert Niessner , SangJun Ahn , Rudy Verstraeten , Gisbert Michels , Florian Patcas , YoungHwa Hwang , Brian J. Banaszak , Roland Walker , Michel Pepers , Johannes Barth
IPC: C08F279/04 , C08J5/00 , C08J5/18 , C08L25/12 , C08L55/02 , C08L67/00 , C08L69/00 , C08L77/02 , C08L77/06
CPC classification number: C08F279/04 , C08F2500/17 , C08F2800/20 , C08J5/00 , C08J5/18 , C08J2325/12 , C08L25/12 , C08L55/02 , C08L67/00 , C08L69/00 , C08L69/005 , C08L77/02 , C08L77/06 , C08L2201/02 , C08L2201/10 , C08L2203/30 , C08L2205/025 , C08L2205/035 , C08L2207/04 , C08F2/22
Abstract: The invention relates to thermoplastic ABS molding compositions comprising components A) and B): A) from 5 to 80% by weight of a graft polymer A) having bimodal particle size distribution; and B) from 20 to 95% by weight of a thermoplastic polymer B) having a viscosity number VN of from 50 to 120 ml/g. The invention further relates to a process for the preparation of graft copolymer A and to the graft copolymer made by that process.
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公开(公告)号:US09714310B2
公开(公告)日:2017-07-25
申请号:US14914495
申请日:2014-08-26
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert Niessner , Phillip Boeckmann , Maarten Staal , Rolf Minkwitz
IPC: C08L51/00 , C08F265/04
CPC classification number: C08F265/04 , C08L51/003 , C08L2205/025 , C08L2207/53 , C08L25/12 , C08L51/04 , C08F212/10
Abstract: Thermoplastic copolymer compositions which contain 50 to 82 wt.-% of a SAN copolymer AI and 15 to 55 wt.-% of a graft copolymer A2, which has an average particle size of 50 to 150 nm and is constituted of at least one rubber-like graft base with a glass transition temperature Tg
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公开(公告)号:US12116337B2
公开(公告)日:2024-10-15
申请号:US17641474
申请日:2020-09-17
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert Niessner , Bianca Wilhelmus , Achim Schmidt-Rodenkirchen , Konstantin Mierdel , Frank Neuner
CPC classification number: C07C4/22 , C08J11/12 , C07C2527/224 , C08J2325/06
Abstract: The invention relates to a process for the preparation of styrene monomers by depolymerising polystyrene, to a device for carrying out the process and to the use of a fluidised bed reactor for the depolymerisation of polystyrene. Said process comprising the following steps: a) feeding a polymer composition (A) containing 60 to 99.9 wt. polystyrene, based on the total weight of the polymer composition (A), into the reaction zone (R) of a pyrolysis reactor (P); b) thermally cracking the polystyrene contained in the polymer composition (A) in the reaction zone (R) of the pyrolysis reactor (P) at a temperature of between 400° C. to 1000° C. to obtain a product mixture (G) containing styrene monomers and other components; c) removing the product mixture (G) obtained in step b) from the reaction zone (R) of the pyrolysis reactor (P); d) cooling the product mixture (G) removed in step c) to obtain a condensed product mixture (K) containing styrene monomers and further components; and e) separating the styrene monomers from the further components of the condensed product mixture (K) obtained in step d), wherein the average residence time (Z) of the polymer composition (A) in the reaction zone (R) of the pyrolysis reactor (P) is from 0.01 sec to 10 sec.
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公开(公告)号:US11441014B2
公开(公告)日:2022-09-13
申请号:US16741829
申请日:2020-01-14
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert Niessner , Philipp Deitmerg , Eike Jahnke , Marko Blinzler , Achim Bernhardt , Tobias Schulz
IPC: C08K7/14 , C08L25/12 , C08L25/08 , C08J5/08 , C03C25/26 , B32B5/02 , B32B5/26 , B32B19/02 , B32B5/08 , B32B27/08 , C08L25/14
Abstract: The present invention relates to a fibre composite material W of increased translucency and/or mechanical strength, comprising a copolymer C encompassing monomers A-1, where A-1 form covalent bonds with functional groups B-1 on the surface of fibres B embedded in the fibre composite material W, and this fibre composite material W has greater translucency and/or mechanical strength than a fibre composite material Win which the copolymer C contains no A-1. The present invention further embraces a method for producing a fibre composite material W of increased translucency and/or mechanical strength.
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公开(公告)号:US11326014B2
公开(公告)日:2022-05-10
申请号:US16622520
申请日:2018-06-18
Applicant: INEOS STYROLUTION GROUP GMBH
Inventor: Norbert Niessner , Daniel Wagner , Michiel Verswyvel
IPC: C08F297/04 , C08F6/10
Abstract: The invention relates to a vinyl aromatic/diene-block copolymer A, obtained by an anionic polymerization of a monomer composition, comprising: Al: 60-95 wt.-% of at least one vinyl aromatic monomer, and A2:5-40 wt.-% of at least one diene monomer, wherein the vinyl aromatic/diene-block copolymer A in total comprises less than 10 parts per million (ppm) of acetaldehyde, methacrolein and styrene based on the total amount of vinyl aromatic/diene-block copolymer A; the vinyl aromatic/diene-block copolymer A has improved orgnoleptic properties and is in particular suitable for producing food packaging materials.
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