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公开(公告)号:US06328854B1
公开(公告)日:2001-12-11
申请号:US09522982
申请日:2000-03-10
申请人: Jeffrey H. Sherman , Philip Grosso
发明人: Jeffrey H. Sherman , Philip Grosso
IPC分类号: C07C2948
CPC分类号: C01B3/38 , B01F2003/04858 , B01F2215/0431 , B01J8/009 , B01J10/007 , B01J12/007 , B01J19/123 , B01J19/2415 , B01J19/2475 , B01J35/002 , B01J35/004 , B01J2219/00081 , B01J2219/00139 , B01J2219/00162 , B01J2219/00189 , B01J2219/0869 , B01J2219/0877 , B01J2219/0884 , B01J2219/0892 , C01B2203/0233 , C01B2203/1035 , C01B2203/1041 , C01B2203/1241 , C07C29/48 , C12C11/02 , Y02P20/52 , C07C31/04
摘要: A porous tube is positioned coaxially around and in axial alignment with a tubular lamp forming an annulus therebetween. Methane is directed through the porous tube and forms submicron size bubbles in a liquid flowing through the annulus. Energy from the tubular lamp generates hydroxyl radicals in the liquid which combine with the methane to form methanol. Photocatalytic material may be provided in the annulus either in the form of a layer of photocatalytic material formed on the interior surface of the porous tube or in the form of particles of photocatalytic material circulating through the annulus with the flowing liquid. A heat transfer apparatus may be provided in the annulus for removing heat generated by operation of the lamp.
摘要翻译: 多孔管同轴地与管状灯同轴地定位,并在其间形成环形空间。 甲烷被引导通过多孔管并在流过环空的液体中形成亚微米尺寸的气泡。 来自管状灯的能量在与甲烷结合形成甲醇的液体中产生羟基自由基。 光催化材料可以以形成在多孔管的内表面上的光催化材料层的形式或以流动的液体循环通过环形的光催化材料的颗粒的形式提供在环形空间中。 可以在环形空间中设置传热装置,以除去灯的操作产生的热量。
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公开(公告)号:US20070251382A1
公开(公告)日:2007-11-01
申请号:US11703277
申请日:2007-02-05
申请人: Sagar Gadewar , Peter Stoimenov , Philip Grosso , Eric McFarland , Ashley Breed , Michael Weiss , Michael Wyrsta
发明人: Sagar Gadewar , Peter Stoimenov , Philip Grosso , Eric McFarland , Ashley Breed , Michael Weiss , Michael Wyrsta
IPC分类号: B01D19/00
CPC分类号: B01D3/10 , B01D1/16 , B01D53/685 , B01D53/75 , B01D2251/60 , B01D2257/2022 , B01D2257/2025 , C01B7/0743 , C01B7/096 , C01B21/0433 , C01B21/045 , C01B2210/0009 , C01B2210/0015
摘要: A process is provided for separating one or more light gases from bromine or chlorine using one or more physical separations and contact with a chemical scrubber to recover additional halogen. In one aspect, the process comprises (a) providing a feed of halogen containing one or more light gases to a distillation column or flash vaporizer; (b) operating the distillation column or flash vaporizer to separate the feed into (i) a first liquid containing a major amount of halogen and no more than a minor amount of light gas(es), and (ii) a first vapor containing a major amount of light gas(es) and no more than a minor amount of halogen; and (c) providing the vapor to a chemical scrubber to recover halogen from the vapor.
摘要翻译: 提供了一种使用一种或多种物理分离从溴或氯中分离一种或多种轻质气体的方法,并与化学洗涤器接触以回收额外的卤素。 一方面,该方法包括(a)向蒸馏塔或闪蒸器提供含有一种或多种轻质气体的卤素进料; (b)操作蒸馏塔或闪蒸器以将进料分离成(i)含有主要量的卤素和不多于少量轻质气体的第一液体,和(ii)含有 主要量的轻质气体,不超过少量的卤素; 和(c)将蒸汽提供给化学洗涤器以从蒸气中回收卤素。
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公开(公告)号:US20050043572A1
公开(公告)日:2005-02-24
申请号:US10958519
申请日:2004-10-04
申请人: Philip Grosso
发明人: Philip Grosso
IPC分类号: C07C29/124 , C07C41/01 , C07C19/00
CPC分类号: C07C29/124
摘要: Gas phase hydrocarbons resulting from the operation of offshore petroleum wells are converted into corresponding liquid products which are mixed with liquid phased hydrocarbons resulting from operation of the offshore petroleum well for delivery therewith.
摘要翻译: 由海上石油井运行产生的气相烃转化为相应的液体产物,这些液体产物与由海上石油井的运行产生的液相烃混合,用于输送。
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公开(公告)号:US06525230B2
公开(公告)日:2003-02-25
申请号:US10114579
申请日:2002-04-02
申请人: Philip Grosso
发明人: Philip Grosso
IPC分类号: C07C2700
CPC分类号: C07C29/124 , C07C41/16 , C07C31/04 , C07C43/043
摘要: In a method of converting alkanes to their corresponding alcohols and ethers a vessel comprises a hollow, unsegregated interior defined first, second, and third zones. In a first embodiment of the invention oxygen reacts with metal bromide in the first zone to provide bromine; bromine reacts with the alkane in the second zone to form alkyl bromide; and the alkyl bromide reacts with metal oxide in the third zone to form the corresponding alcohol and/or ether. Metal bromide from the third zone is transported through the vessel to the first zone and metal oxide from the first zone is recycled to the third zone. A second embodiment of the invention differs from the first embodiment in that metal oxide is transported through the vessel from the first zone to the third zone and metal bromide is recycled from the third zone to the first zone. In a third embodiment of the invention the flow of gases through the vessel is reversed to convert the metal oxide back to metal bromide and to convert the metal bromide back to the metal oxide.
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25.
公开(公告)号:US20070238909A1
公开(公告)日:2007-10-11
申请号:US11703358
申请日:2007-02-05
申请人: Sagar Gadewar , Michael Wyrsta , Philip Grosso , Aihua Zhang , Eric McFarland , Zachary Komon , Jeffrey Sherman
发明人: Sagar Gadewar , Michael Wyrsta , Philip Grosso , Aihua Zhang , Eric McFarland , Zachary Komon , Jeffrey Sherman
IPC分类号: C07C2/00
CPC分类号: C07C15/02 , C07C1/26 , C07C11/04 , C07C11/06 , C07C17/10 , C07C17/37 , C07C2527/053 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/48 , C07C2529/83 , C07C2529/85 , C07C2529/89 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C19/075
摘要: An improved continuous process for converting methane, natural gas, or other hydrocarbon feedstocks into one or more higher hydrocarbons or olefins by continuously cycling through the steps of alkane halogenation, product formation (carbon-carbon coupling), product separation, and regeneration of halogen is provided. Preferably, the halogen is continually recovered by reacting hydrobromic acid with air or oxygen. The invention provides an efficient route to aromatic compounds, aliphatic compounds, mixtures of aliphatic and aromatic compounds, olefins, gasoline grade materials, and other useful products.
摘要翻译: 通过连续循环通过烷烃卤化,产物形成(碳 - 碳偶联),产物分离和卤素再生的步骤将甲烷,天然气或其它烃原料转化成一种或多种高级烃或烯烃的改进的连续方法是 提供。 优选地,通过使氢溴酸与空气或氧反应来连续地回收卤素。 本发明提供了芳香化合物,脂肪族化合物,脂族和芳族化合物的混合物,烯烃,汽油级材料和其它有用产物的有效途径。
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26.
公开(公告)号:US08921625B2
公开(公告)日:2014-12-30
申请号:US12504880
申请日:2009-07-17
申请人: Sagar Gadewar , Saydul Amin Sardar , Philip Grosso , Aihua Zhang , Vivek Julka , Peter Stolmanov
发明人: Sagar Gadewar , Saydul Amin Sardar , Philip Grosso , Aihua Zhang , Vivek Julka , Peter Stolmanov
IPC分类号: C07C21/00 , C07C17/00 , C07C23/00 , C07C25/00 , C07C17/08 , C01B7/01 , C07C17/23 , C01B7/09 , C07C17/06 , C07C17/26 , B01J8/00 , C01B7/19 , C01B7/13 , C07C17/10 , B01J8/18
CPC分类号: B01J8/00 , B01J8/18 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C17/06 , C07C17/10 , C07C17/23 , C07C17/26 , Y02C20/30 , C07C19/075 , C07C25/02
摘要: A method comprising: providing a halogen stream; providing an alkane stream; providing a decoking agent; and reacting at least a portion of the halogen stream with at least a portion of the alkane stream in the presence of a halogenation catalyst and the decoking agent to form a halogenated stream.
摘要翻译: 一种方法,包括:提供卤素流; 提供烷烃流; 提供除焦剂; 以及在卤化催化剂和脱焦剂的存在下使至少一部分卤素物流与烷烃物流的至少一部分反应以形成卤化物流。
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27.
公开(公告)号:US08273929B2
公开(公告)日:2012-09-25
申请号:US12504894
申请日:2009-07-17
申请人: Peter Stoimenov , Charles Ian Cutier , Jihong Cheng , Charles J. Coronelia , Krishna Janmanchi , Zachary J. A. Komon , Saydul Amin Sardar , Vivek Julka , Sagar Gadewar , Philip Grosso , Daniel J. Auerbach , Jean Wheeler
发明人: Peter Stoimenov , Charles Ian Cutier , Jihong Cheng , Charles J. Coronelia , Krishna Janmanchi , Zachary J. A. Komon , Saydul Amin Sardar , Vivek Julka , Sagar Gadewar , Philip Grosso , Daniel J. Auerbach , Jean Wheeler
IPC分类号: C07C1/00
CPC分类号: B01J8/00 , B01J8/18 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C17/06 , C07C17/10 , C07C17/23 , C07C17/26 , Y02C20/30 , C07C19/075 , C07C25/02
摘要: A method comprising: providing an alkyl halide stream; contacting at least some of the alkyl halides with a coupling catalyst to form a product stream comprising higher hydrocarbons and hydrogen halide; contacting the product stream with a solid reactant to remove at least a portion of the hydrogen halide from the product stream; and reacting the solid reactant with a source of oxygen to generate a corresponding halogen.
摘要翻译: 一种方法,包括:提供烷基卤流; 使至少一些烷基卤与偶联催化剂接触以形成包含高级烃和卤化氢的产物流; 使产物流与固体反应物接触以从产物流中除去至少一部分卤化氢; 并使固体反应物与氧源反应以产生相应的卤素。
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公开(公告)号:US07361794B2
公开(公告)日:2008-04-22
申请号:US10369148
申请日:2003-02-19
申请人: Philip Grosso
发明人: Philip Grosso
CPC分类号: C07C29/124 , C07C41/16 , C07C31/04 , C07C43/043
摘要: In a method of converting alkanes to their corresponding alcohols and ethers a vessel comprises a hollow, unsegregated interior defined first, second, and third zones. In a first embodiment of the invention oxygen reacts with metal bromide in the first zone to provide bromine; bromine reacts with the alkane in the second zone to form alkyl bromide; and the alkyl bromide reacts with metal oxide in the third zone to form the corresponding alcohol and/or ether. Metal bromide from the third zone is transported through the vessel to the first zone and metal oxide from the first zone is recycled to the third zone. A second embodiment of the invention differs from the first embodiment in that metal oxide is transported through the vessel from the first zone to the third zone and metal bromide is recycled from the third zone to the first zone. In a third embodiment of the invention the flow of gases through the vessel is reversed to convert the metal oxide back to metal bromide and to convert the metal bromide back to the metal oxide.
摘要翻译: 在将烷烃转化成其相应的醇和醚的方法中,容器包括中空的未分离的内部限定的第一,第二和第三区域。 在本发明的第一个实施方案中,氧与第一区中的金属溴化物反应以提供溴; 溴与第二区中的烷烃反应形成烷基溴; 并且烷基溴与第三区中的金属氧化物反应形成相应的醇和/或醚。 来自第三区域的金属溴化物通过容器运输到第一区域,并且来自第一区域的金属氧化物被再循环到第三区域。 本发明的第二实施例与第一实施例的不同之处在于金属氧化物通过容器从第一区域传送到第三区域,金属溴化物从第三区域再循环到第一区域。 在本发明的第三个实施方案中,反过来通过容器的气体流将金属氧化物转换回金属溴化物并将金属溴化物转化回金属氧化物。
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29.
公开(公告)号:US20100099930A1
公开(公告)日:2010-04-22
申请号:US12504894
申请日:2009-07-17
申请人: Peter Stoimenov , Charles Ian Cutier , Jihong Cheng , Charles J. Coronelia , Krishna Janmanchi , Zachary J.A. Komon , Saydul Amin Sardar , Vivek Julka , Sagar Gadewar , Philip Grosso , Daniel J. Auerbach , Jean Wheeler
发明人: Peter Stoimenov , Charles Ian Cutier , Jihong Cheng , Charles J. Coronelia , Krishna Janmanchi , Zachary J.A. Komon , Saydul Amin Sardar , Vivek Julka , Sagar Gadewar , Philip Grosso , Daniel J. Auerbach , Jean Wheeler
CPC分类号: B01J8/00 , B01J8/18 , C01B7/01 , C01B7/093 , C01B7/096 , C01B7/13 , C01B7/19 , C07C17/06 , C07C17/10 , C07C17/23 , C07C17/26 , Y02C20/30 , C07C19/075 , C07C25/02
摘要: A method comprising: providing an alkyl halide stream; contacting at least some of the alkyl halides with a coupling catalyst to form a product stream comprising higher hydrocarbons and hydrogen halide; contacting the product stream with a solid reactant to remove at least a portion of the hydrogen halide from the product stream; and reacting the solid reactant with a source of oxygen to generate a corresponding halogen.
摘要翻译: 一种方法,包括:提供烷基卤流; 使至少一些烷基卤与偶联催化剂接触以形成包含高级烃和卤化氢的产物流; 使产物流与固体反应物接触以从产物流中除去至少一部分卤化氢; 并使固体反应物与氧源反应以产生相应的卤素。
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公开(公告)号:US07019182B2
公开(公告)日:2006-03-28
申请号:US10958519
申请日:2004-10-04
申请人: Philip Grosso
发明人: Philip Grosso
IPC分类号: C07B41/02
CPC分类号: C07C29/124
摘要: Gas phase hydrocarbons resulting from the operation of offshore petroleum wells are converted into corresponding liquid products which are mixed with liquid phased hydrocarbons resulting from operation of the offshore petroleum well for delivery therewith.
摘要翻译: 由海上石油井运行产生的气相烃转化为相应的液体产物,这些液体产物与由海上石油井的运行产生的液相烃混合,用于输送。
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