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21.
公开(公告)号:US09103036B2
公开(公告)日:2015-08-11
申请号:US13837028
申请日:2013-03-15
Applicant: Kennametal Inc.
Inventor: Vineet Kumar , Ronald Penich , Yixiong Liu
CPC classification number: C23C28/044 , C23C28/042 , C23C28/42 , Y10T428/265 , Y10T428/31678
Abstract: Refractory coatings for cutting tool applications and methods of making the same are described herein which, in some embodiments, permit incorporation of increased levels of aluminum into nitride coatings while reducing or maintaining levels of hexagonal phase in such coatings. Coatings and methods described herein, for example, employ cubic phase forming compositions for limiting hexagonal phase in nitride coatings of high aluminum content.
Abstract translation: 本文描述了用于切削刀具应用的耐火涂层及其制造方法,在一些实施例中,其允许将增加水平的铝结合到氮化物涂层中,同时降低或维持这种涂层中的六方相的水平。 例如,本文所述的涂层和方法使用立方相形成组合物来限制高铝含量的氮化物涂层中的六方相。
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公开(公告)号:US08865260B2
公开(公告)日:2014-10-21
申请号:US13908085
申请日:2013-06-03
Applicant: Kennametal Inc.
Inventor: Zhigang Ban , Alfred S. Gates, Jr. , Yixiong Liu , Jie Wu
CPC classification number: B23B27/148 , B23B27/141 , B23B2226/18 , B23B2228/10 , B23B2260/144 , C04B41/009 , C04B41/52 , C04B41/89 , C23C28/044 , C23C28/42 , C23C30/005 , Y10T407/27 , C04B35/584 , C04B35/597 , C04B41/4531 , C04B41/5031 , C04B41/459 , C04B41/5061 , C04B41/5068
Abstract: A coated ceramic cutting insert for removing material from a workpiece, as well as a method for making the same, that includes a ceramic substrate with a rake surface and at least one flank surface wherein a cutting edge is at the juncture therebetween. A wear-resistant coating scheme that includes an alumina-containing base coating layer region, which has at least one exposed alumina coating layer, deposited by chemical vapor deposition on the substantially all of the surfaces of the ceramic substrate that experience wear during removal of material from the workpiece. The exposed alumina coating layer exhibits a blasted stress condition ranging between about 50 MPa (tensile stress) and about −2 GPa (compressive) as measured by XRD using the Psi tilt method and the (024) reflection of alumina. The exposed alumina coating layer is the result of wet blasting a titanium-containing outer coating layer region from the surface of the alumina-containing base coating layer region.
Abstract translation: 一种用于从工件去除材料的涂覆陶瓷切削刀片及其制造方法,其包括具有前刀面和至少一个侧面的陶瓷基体,其中切削刃处于它们之间的接合处。 一种耐磨涂层方案,其包括含氧化铝的基底涂层区域,其具有至少一个暴露的氧化铝涂层,其通过化学气相沉积沉积在陶瓷基底的基本上所有的表面上,在去除材料期间经历磨损 从工件。 暴露的氧化铝涂层表现出通过使用Psi倾斜法和氧化铝的(024)反射通过XRD测量的约50MPa(拉伸应力)和约-2GPa(压缩)之间的喷砂应力条件。 暴露的氧化铝涂层是从含氧化铝的基底涂层区域的表面湿式喷射含钛外涂层区域的结果。
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公开(公告)号:US20140291036A1
公开(公告)日:2014-10-02
申请号:US14226999
申请日:2014-03-27
Applicant: Kennametal Inc.
Inventor: Peter Rudolf Leicht , Zhenyu Liu , Mark S. Greenfield , Yixiong Liu
IPC: E21B10/573 , C23C16/06
CPC classification number: C23C16/06 , C23C16/30 , C23C16/403 , C23C28/042 , C23C28/044 , C23C28/42
Abstract: In one aspect, cutting tools are described having coatings adhered thereto which, in some embodiments, can demonstrate desirable wear resistance and increased cutting lifetimes. A coated cutting tool described herein comprises a substrate and a coating adhered to the substrate, the coating having a multilayer structure including a plurality of structural units each comprising a bonding layer and an adjacent alumina layer, the alumina layer having a thickness of less than 0.5 μm and the bonding layer having a thickness less than 1 μm, the bonding layer comprising TiCN and TiAlOC.
Abstract translation: 在一个方面,描述了具有粘附到其上的涂层的切割工具,在一些实施例中,可以显示出期望的耐磨性和增加的切割寿命。 本文所述的涂层切削工具包括基底和附着在基底上的涂层,所述涂层具有多层结构,所述多层结构包括多个结构单元,每个结构单元包括结合层和相邻的氧化铝层,所述氧化铝层的厚度小于0.5 并且所述接合层的厚度小于1μm,所述接合层包含TiCN和TiAlOC。
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24.
公开(公告)号:US20140271318A1
公开(公告)日:2014-09-18
申请号:US13832635
申请日:2013-03-15
Applicant: KENNAMETAL INC.
Inventor: Qingjun Zheng , Yixiong Liu , James A. Faust , Mark J. Rowe , Danie J. De Wet , Sudharsan Subbaiyan , Michael J. Meyer
CPC classification number: B22F7/008 , B22D23/06 , B22F3/10 , B22F5/106 , B22F2005/103 , B22F2007/066 , B22F2301/10 , B22F2301/15 , B22F2301/205 , B22F2301/35 , B22F2302/10 , B22F2302/253 , B22F2302/45 , B23K35/0222 , B23K35/0244 , B23K35/3033 , B23K35/304 , C22C1/1015 , C22C9/01 , C22C9/06 , C22C9/10 , C22C14/00 , C22C19/058 , C22C19/07 , C22C29/02 , C22C32/0047 , C22C38/22 , C22C38/36 , C22C38/38
Abstract: In one aspect, methods of making freestanding metal matrix composite articles and alloy articles are described. A method of making a freestanding composite article described herein comprises disposing over a surface of the temporary substrate a layered assembly comprising a layer of infiltration metal or alloy and a hard particle layer formed of a flexible sheet comprising organic binder and the hard particles. The layered assembly is heated to infiltrate the hard particle layer with metal or alloy providing a metal matrix composite, and the metal matrix composite is separated from the temporary substrate. Further, a method of making a freestanding alloy article described herein comprises disposing over the surface of a temporary substrate a flexible sheet comprising organic binder and powder alloy and heating the sheet to provide a sintered alloy article. The sintered alloy article is then separated from the temporary substrate.
Abstract translation: 一方面,描述制造独立金属基复合制品和合金制品的方法。 制造本文所述的独立复合制品的方法包括在临时衬底的表面上设置包括渗透金属或合金层的层状组件以及由包含有机粘合剂和硬颗粒的柔性片形成的硬颗粒层。 加热层状组件以提供金属或合金以提供金属基质复合材料渗透硬颗粒层,并将金属基质复合物与临时衬底分离。 此外,制造本文所述的独立式合金制品的方法包括在临时基材的表面上设置包含有机粘合剂和粉末合金的柔性片材,并加热片材以提供烧结合金制品。 然后将烧结合金制品与临时基材分离。
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公开(公告)号:US20130302521A1
公开(公告)日:2013-11-14
申请号:US13908097
申请日:2013-06-03
Applicant: Kennametal Inc.
Inventor: Volkmar Sottke , Hartmut Westphal , Hendrikus Van Den Berg , Zhigang Ban , Yixiong Liu , Mark S. Greenfield
IPC: C23C16/30
CPC classification number: C23C16/308 , C22C29/00 , C22C29/08 , C22C29/12 , C22C29/16
Abstract: A coated article such as a coated cutting tool or coated wear part, which includes a substrate and a coating scheme on the substrate. The coating scheme has a titanium-containing coating layer, and an aluminum oxynitride coating layer on the titanium-containing coating layer. The aluminum oxynitride includes a mixture of phases having a hexagonal aluminum nitride type structure (space group: P63mc), a cubic aluminum nitride type structure (space group: Fm-3m), and optionally amorphous structure. The aluminum oxynitride coating layer has a composition of aluminum in an amount between about 20 atomic percent and about 50 atomic percent, nitrogen in an amount between about 40 atomic percent and about 70 atomic percent, and oxygen in an amount between about 1 atomic percent and about 20 atomic percent. The method of making the coated article includes a step of providing a substrate and depositing an aluminum oxynitride coating layer from a gaseous mixture that includes nitrogen, aluminum tri-chloride, ammonia, carbon dioxide, hydrogen chloride, optionally carbon monoxide, optionally argon, and hydrogen.
Abstract translation: 涂覆的制品,例如涂覆的切削工具或涂覆的磨损部件,其包括衬底和在衬底上的涂覆方案。 涂布方案在含钛涂层上具有含钛涂层和氮氧化铝涂层。 氮氧化铝包括具有六方氮化铝型结构(空间群:P63mc),立方氮化铝型结构(空间群:Fm-3m)和任选的非晶结构的相的混合物。 铝氮氧化物涂层的组成为约20原子%至约50原子%的量的铝,约40原子%至约70原子%之间的氮,约1原子%与约1原子%之间的量的氧, 约20原子%。 制备涂覆制品的方法包括提供基材和从包括氮,三氯化铝,氨,二氧化碳,氯化氢,任选的一氧化碳,任选的氩气的气体混合物沉积氧氮化铝涂层的步骤,以及 氢。
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公开(公告)号:US10570521B2
公开(公告)日:2020-02-25
申请号:US15631799
申请日:2017-06-23
Applicant: KENNAMETAL INC.
Inventor: Zhenyu Liu , Peter Rudolf Leicht , Yixiong Liu
Abstract: Cutting tools are described having coatings which can demonstrate desirable wear resistance and increased cutting lifetimes. A coated cutting tool described herein has a substrate and a coating with a plurality of alternating layers of a first layer of Al2O3 and a second layer of at least one of MeAl2O3 and MeAl2O3/MeO2 composite, wherein Me is Zr, Hf, Ti or a combination thereof. The coating has a superlattice-like structure.
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公开(公告)号:US10273575B2
公开(公告)日:2019-04-30
申请号:US15253460
申请日:2016-08-31
Applicant: Kennametal Inc.
Inventor: Rodrigo Alejandro Cooper , Karl Heinz Wendt , Peter Leicht , Bhaskar Alok , Yixiong Liu
Abstract: In one aspect, articles are described comprising wear resistant coatings employing one or more composite refractory layers. For example, a coated article described herein comprises a substrate and a coating deposited by CVD adhered to the substrate, the coating including a multiphase refractory layer comprising an alumina phase and a zirconia phase, wherein the zirconia phase has a texture coefficient for the (200) growth direction, TC(200), greater than 4.
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公开(公告)号:US09862029B2
公开(公告)日:2018-01-09
申请号:US13832635
申请日:2013-03-15
Applicant: Kennametal Inc.
Inventor: Qingjun Zheng , Yixiong Liu , James A Faust , Mark J Rowe , Danie J De Wet , Sudharsan Subbaiyan , Michael J Meyer
IPC: B22F7/00 , B22D23/06 , B22F5/10 , C22C1/10 , C22C29/02 , C22C32/00 , B23K35/30 , B23K35/02 , B22F7/06
CPC classification number: B22F7/008 , B22D23/06 , B22F3/10 , B22F5/106 , B22F2005/103 , B22F2007/066 , B22F2301/10 , B22F2301/15 , B22F2301/205 , B22F2301/35 , B22F2302/10 , B22F2302/253 , B22F2302/45 , B23K35/0222 , B23K35/0244 , B23K35/3033 , B23K35/304 , C22C1/1015 , C22C9/01 , C22C9/06 , C22C9/10 , C22C14/00 , C22C19/058 , C22C19/07 , C22C29/02 , C22C32/0047 , C22C38/22 , C22C38/36 , C22C38/38
Abstract: In one aspect, methods of making freestanding metal matrix composite articles and alloy articles are described. A method of making a freestanding composite article described herein comprises disposing over a surface of the temporary substrate a layered assembly comprising a layer of infiltration metal or alloy and a hard particle layer formed of a flexible sheet comprising organic binder and the hard particles. The layered assembly is heated to infiltrate the hard particle layer with metal or alloy providing a metal matrix composite, and the metal matrix composite is separated from the temporary substrate. Further, a method of making a freestanding alloy article described herein comprises disposing over the surface of a temporary substrate a flexible sheet comprising organic binder and powder alloy and heating the sheet to provide a sintered alloy article. The sintered alloy article is then separated from the temporary substrate.
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公开(公告)号:US09764986B2
公开(公告)日:2017-09-19
申请号:US14602745
申请日:2015-01-22
Applicant: Kennametal Inc.
Inventor: Zhenyu Liu , Qingjun Zheng , Peter Rudolf Leicht , Yixiong Liu
CPC classification number: C04B35/58014 , C23C16/34
Abstract: In one aspect, articles employing CVD coatings deposited at low temperatures are described herein. Briefly, a coated article described herein comprises a substrate and a refractory coating adhered to the substrate, the refractory coating including a layer of TiN deposited by thermal CVD, the layer of TiN having an average crystallite size of 0.05 μm to 0.5 μm and residual tensile stress of 100 MPa to 700 MPa.
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公开(公告)号:US20160215387A1
公开(公告)日:2016-07-28
申请号:US14602745
申请日:2015-01-22
Applicant: Kennametal Inc.
Inventor: Zhenyu LIU , Qingjun Zheng , Peter Rudolf Leicht , Yixiong Liu
CPC classification number: C04B35/58014 , C23C16/34
Abstract: In one aspect, articles employing CVD coatings deposited at low temperatures are described herein. Briefly, a coated article described herein comprises a substrate and a refractory coating adhered to the substrate, the refractory coating including a layer of TiN deposited by thermal CVD, the layer of TiN having an average crystallite size of 0.05 μm to 0.5 μm and residual tensile stress of 100 MPa to 700 MPa.
Abstract translation: 在一个方面,本文描述了使用在低温下沉积的CVD涂层的制品。 简而言之,本文描述的涂覆制品包括基底和粘附到基底的耐火涂层,耐火涂层包括通过热CVD沉积的TiN层,所述TiN层具有0.05μm至0.5μm的平均微晶尺寸和残余拉伸强度 应力为100MPa至700MPa。
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