公开(公告)号：US07214844B2

公开(公告)日：2007-05-08

申请号：US11039294

申请日：2005-01-20

申请人： Yun-feng Chang ,  Stephen N. Vaughn ,  Luc R. M. Martens ,  Joseph E. Baumgartner ,  Stuart L. Soled ,  Kenneth R. Clem

发明人： Yun-feng Chang ,  Stephen N. Vaughn ,  Luc R. M. Martens ,  Joseph E. Baumgartner ,  Stuart L. Soled ,  Kenneth R. Clem

IPC分类号： C07C1/00

CPC分类号： B01J37/10 ,  B01J29/85 ,  B01J35/10 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/36 ,  B01J2229/42 ,  C07C1/20 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C2529/00 ,  C07C2529/85 ,  C10G3/48 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/1022 ,  C10G2400/20 ,  Y02P20/52 ,  Y02P30/42

摘要： The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a making a molecular sieve catalyst composition by forming a slurry by combining a molecular sieve, a binder and a matrix material, wherein the slurry has a pH, above or below the isoelectric point of the molecular sieve. The catalyst composition has improved attrition resistance, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.

摘要翻译： 本发明涉及分子筛催化剂组合物，制备或形成分子筛催化剂组合物的方法，以及使用该催化剂组合物的转化方法。 特别地，本发明涉及通过组合分子筛，粘合剂和基质材料形成浆料来制备分子筛催化剂组合物，其中所述浆料具有高于或低于分子筛等电点的pH。 催化剂组合物具有改善的耐磨性，特别适用于从原料，优选含氧化合物原料生产烯烃，优选乙烯和/或丙烯的转化方法。

公开(公告)号：US07033971B2

公开(公告)日：2006-04-25

申请号：US10774859

申请日：2004-02-09

申请人： Shun C. Fung ,  Richard B. Hall ,  Hafedh Kochkar ,  Karl G. Strohmaier ,  Nicolas P. Coute ,  Kenneth R. Clem

发明人： Shun C. Fung ,  Richard B. Hall ,  Hafedh Kochkar ,  Karl G. Strohmaier ,  Nicolas P. Coute ,  Kenneth R. Clem

IPC分类号： B01J27/182 ,  B01J21/20

CPC分类号： B01J29/90 ,  B01J38/12 ,  C10G3/48 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/708 ,  C10G2300/802 ,  C10G2300/805 ,  C10G2400/20 ,  Y02P30/20

摘要： A method for maintaining the activity of silicoaluminophosphate (SAPO) molecular sieve catalyst particles during oxygenate to olefin conversion reactions. After regeneration of SAPO catalyst particles, the regenerated particles are mixed with particles having coke on their surface in a manner that maintains their catalytic activity at a predetermined level.

摘要翻译： 一种在含氧化合物转化成烯烃转化反应期间维持硅铝磷酸盐（SAPO）分子筛催化剂颗粒的活性的方法。 在SAPO催化剂颗粒再生后，将再生颗粒与其表面上具有焦炭的颗粒以保持其催化活性在预定水平的方式混合。

公开(公告)号：US06872680B2

公开(公告)日：2005-03-29

申请号：US10178518

申请日：2002-06-24

申请人： Yun-feng Chang ,  Stephen N. Vaughn ,  Luc R. M. Martens ,  Joseph E. Baumgartner ,  Stuart L. Soled ,  Kenneth R. Clem

发明人： Yun-feng Chang ,  Stephen N. Vaughn ,  Luc R. M. Martens ,  Joseph E. Baumgartner ,  Stuart L. Soled ,  Kenneth R. Clem

IPC分类号： B01J29/85 ,  B01J35/10 ,  B01J37/00 ,  B01J37/10 ,  C07C1/20 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C10G3/00 ,  B01J29/06

CPC分类号： B01J37/10 ,  B01J29/85 ,  B01J35/10 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/36 ,  B01J2229/42 ,  C07C1/20 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C2529/00 ,  C07C2529/85 ,  C10G3/48 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/1022 ,  C10G2400/20 ,  Y02P20/52 ,  Y02P30/42

摘要： The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a making a molecular sieve catalyst composition by forming a slurry by combining a molecular sieve, a binder and a matrix material, wherein the slurry has a pH, above or below the isoelectric point of the molecular sieve. The catalyst composition has improved attrition resistance, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.

摘要翻译： 本发明涉及分子筛催化剂组合物，制备或形成分子筛催化剂组合物的方法，以及使用该催化剂组合物的转化方法。 特别地，本发明涉及通过组合分子筛，粘合剂和基质材料形成浆料来制备分子筛催化剂组合物，其中所述浆料具有高于或低于分子筛等电点的pH。 催化剂组合物具有改善的耐磨性，特别适用于从原料，优选含氧化合物原料生产烯烃，优选乙烯和/或丙烯的转化方法。

公开(公告)号：US06710008B2

公开(公告)日：2004-03-23

申请号：US10052058

申请日：2002-01-17

申请人： Yun-Feng Chang ,  Stephen N. Vaughn ,  Jeffery W. Sprinkle ,  Fran A. Shipley ,  Kenneth R. Clem

发明人： Yun-Feng Chang ,  Stephen N. Vaughn ,  Jeffery W. Sprinkle ,  Fran A. Shipley ,  Kenneth R. Clem

IPC分类号： B01J27182

CPC分类号： B01J37/0009 ,  B01J29/83 ,  B01J29/85 ,  B01J29/90 ,  B01J35/023 ,  B01J35/10 ,  B01J37/0045 ,  B01J37/10 ,  B01J2229/26 ,  B01J2229/42 ,  C07C1/20 ,  C07C2529/85 ,  C10G3/49 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/584 ,  Y02P30/20

摘要： Disclosed is a method for making molecular sieve catalyst particles. Dried molecular sieve catalyst particles are used to make the catalyst. The dried molecular sieve catalyst particles are put into an aqueous solution and stirred to make a slurry. The slurry is dried to make the molecular sieve catalyst particles. Optionally, the dried molecular sieve catalyst particles made from the slurry are calcined.

公开(公告)号：US5211838A

公开(公告)日：1993-05-18

申请号：US805334

申请日：1991-12-09

申请人： Staubs, David W. ,  Stuart S. Goldstein ,  Paul W. Kamienski ,  Gerrit S. Swart ,  George A. Swan, III ,  Kenneth R. Clem

发明人： Staubs, David W. ,  Stuart S. Goldstein ,  Paul W. Kamienski ,  Gerrit S. Swart ,  George A. Swan, III ,  Kenneth R. Clem

IPC分类号： C10G59/02

CPC分类号： C10G59/02

摘要： A two stage process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock. The reforming is conducted in two stages wherein the first stage is operated in a fixed bed mode, and the second stage is operated in a moving bed continual catalyst regeneration mode. A gaseous stream comprised of hydrogen and predominantly C.sub.4.sup.- and a C.sub.5.sup.+ liquid stream are produced between stages. A portion of the hydrogen-rich stream is recycled and the and the remaining portion and an aromatics-lean stream, which is obtained during aromatics separation between stages, is sent to second stage reforming.

摘要翻译： 催化重整汽油沸程烃原料的两阶段方法。 重整在两个阶段进行，其中第一阶段以固定床模式操作，第二阶段在移动床连续催化剂再生模式下操作。 在级之间产生由氢气和主要为C4-和C5 +液体流组成的气流。 一部分富氢流被再循环，并且在阶段之间的芳烃分离期间获得的剩余部分和贫芳烃流被送到第二阶段重整。

公开(公告)号：US4872967A

公开(公告)日：1989-10-10

申请号：US197233

申请日：1988-05-23

申请人： Kenneth R. Clem ,  Kenneth J. Heider ,  James E. Kegerreis ,  Ehsan I. Shoukry

发明人： Kenneth R. Clem ,  Kenneth J. Heider ,  James E. Kegerreis ,  Ehsan I. Shoukry

IPC分类号： B01J29/06 ,  C10G61/02

CPC分类号： C10G61/02

摘要： Disclosed is a process for catalytically reforming a gasoline boiling range hydrocarbonaceous feedstock wherein the reforming is conducted in two or more stages wherein each stage is separated from another stage by aromatics removal from the reaction stream of a preceding stage. The resulting aromatics-lean stream is passed to a downstream reforming stage.

公开(公告)号：US20070175326A1

公开(公告)日：2007-08-02

申请号：US11641383

申请日：2006-12-19

申请人： Kenneth R. Clem

发明人： Kenneth R. Clem

IPC分类号： B01D51/08

CPC分类号： B01D49/006 ,  B01D51/08

摘要： This invention is directed to a process for removing catalyst particles from a gas. The invention is particularly suited to separating particles from the gas in a vessel that has a dilute phase zone and a dense phase zone. An acoustic waveform is applied to the dilute phase zone to assist in separating small particles from the gas in the dilute phase zone.

摘要翻译： 本发明涉及从气体中除去催化剂颗粒的方法。 本发明特别适用于在具有稀相区和致密相区的容器中从气体中分离颗粒。 声学波形被施加到稀相区，以帮助从稀相区中的气体中分离出小颗粒。

公开(公告)号：US07160831B2

公开(公告)日：2007-01-09

申请号：US10178374

申请日：2002-06-24

申请人： Stephen N. Vaughn ,  Yun-feng Chang ,  Luc R. M. Martens ,  Kenneth R. Clem ,  Machteld M. Mertens ,  Albert E. Schweizer

发明人： Stephen N. Vaughn ,  Yun-feng Chang ,  Luc R. M. Martens ,  Kenneth R. Clem ,  Machteld M. Mertens ,  Albert E. Schweizer

IPC分类号： B01J29/06

CPC分类号： C10G3/49 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/12 ,  B01J2229/14 ,  B01J2229/24 ,  B01J2229/34 ,  B01J2229/42 ,  C07C1/20 ,  C07C7/04 ,  C07C7/08 ,  C07C2529/85 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/52 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02 ,  C07C11/04 ,  C08F4/12 ,  C08F4/16 ,  C08F4/025 ,  C08F4/005

摘要： The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to making a formulated molecular sieve catalyst composition from a slurry of formulation composition of a synthesized molecular sieve that has not been fully dried, a binder and an optional matrix material. In a more preferred embodiment, the weight ratio of the binder to the molecular sieve and/or the solid content of the slurry is controlled to provide an improved attrition resistant catalyst composition, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.

摘要翻译： 本发明涉及分子筛催化剂组合物，制备或形成分子筛催化剂组合物的方法，以及使用该催化剂组合物的转化方法。 特别地，本发明涉及从尚未完全干燥的合成分子筛的配方组合物的浆料，粘合剂和任选的基质材料制备配制的分子筛催化剂组合物。 在更优选的实施方案中，控制粘合剂与分子筛的重量比和/或浆料的固体含量，以提供改进的耐磨性催化剂组合物，特别可用于生产烯烃的转化方法 乙烯和/或丙烯，优选含有氧化合物的原料。

公开(公告)号：US07071136B2

公开(公告)日：2006-07-04

申请号：US10442586

申请日：2003-05-21

申请人： Yun-Feng Chang ,  Stephen N. Vaughn ,  Luc R. M. Martens ,  Kenneth R. Clem

发明人： Yun-Feng Chang ,  Stephen N. Vaughn ,  Luc R. M. Martens ,  Kenneth R. Clem

IPC分类号： B01J29/06

CPC分类号： B01J37/0045 ,  B01J29/06 ,  B01J29/85 ,  C07C1/20 ,  C07C2529/83 ,  C07C2529/85 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02

摘要： This invention is directed to a hardened molecular sieve catalyst composition, a method of making the composition and a method of using the composition. The catalyst composition is made by mixing together molecular sieve, liquid, and an effective hardening amount of a dried molecular sieve catalyst to form a slurry. The slurry is dried, and then calcined to form the hardened molecular sieve catalyst composition. The hardened molecular sieve catalyst is highly attrition resistant.

公开(公告)号：US06787501B2

公开(公告)日：2004-09-07

申请号：US10178578

申请日：2002-06-24

申请人： Stephen N. Vaughn ,  Yun-feng Chang ,  Luc R. M. Martens ,  Kenneth R. Clem ,  Machteld M. Mertens ,  Albert E. Schweizer

发明人： Stephen N. Vaughn ,  Yun-feng Chang ,  Luc R. M. Martens ,  Kenneth R. Clem ,  Machteld M. Mertens ,  Albert E. Schweizer

IPC分类号： B01J2906

CPC分类号： C10G3/49 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J37/0009 ,  B01J37/0045 ,  B01J2229/12 ,  B01J2229/14 ,  B01J2229/24 ,  B01J2229/34 ,  B01J2229/42 ,  C07C1/20 ,  C07C7/04 ,  C07C7/08 ,  C07C2529/85 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/52 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02 ,  C07C11/04 ,  C08F4/12 ,  C08F4/16 ,  C08F4/025 ,  C08F4/005

摘要： The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to making a formulated molecular sieve catalyst composition from a slurry of formulation composition of a synthesized molecular sieve that has not been fully dried, a binder and an optional matrix material. In a more preferred embodiment, the weight ratio of the binder to the molecular sieve and/or the solid content of the slurry is controlled to provide an improved attrition resistant catalyst composition, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.

摘要翻译： 本发明涉及分子筛催化剂组合物，制备或形成分子筛催化剂组合物的方法，以及使用该催化剂组合物的转化方法。 特别地，本发明涉及从尚未完全干燥的合成分子筛的配方组合物的浆料，粘合剂和任选的基质材料制备配制的分子筛催化剂组合物。 在更优选的实施方案中，控制粘合剂与分子筛的重量比和/或浆料的固体含量，以提供改进的耐磨性催化剂组合物，特别可用于生产烯烃的转化方法 乙烯和/或丙烯，优选含有氧化合物的原料。