摘要:
Disclosed are composite electrodes for use in a solid oxide fuel cell devices. The electrodes are comprised of a sintered mixture of lanthanum strontium ferrite phase and yttria stabilized zirconia phase. The lanthanum strontium ferrite phase has the general formula (LaxSry)i±δ(FeaMnbCoc)O3; wherein 1.O≧x≧0.65; 0.35≧y≧0.0; x+y=1.0, δ=0-0.1, a+b+c=1, and a>0.6. Also disclosed are methods of making the composite electrodes and solid oxide fuel cell devices comprising same.
摘要翻译:公开了用于固体氧化物燃料电池装置的复合电极。 电极由锶锶铁素体相和氧化钇稳定的氧化锆相的烧结混合物组成。 镧锶铁素体相具有通式(LaxSry)i±δ(FeaMnbCoc)O3; 其中,1.0≥x≥0.65; 0.35≥y≥0.0; x + y = 1.0,δ= 0-0.1,a + b + c = 1,a> 0.6。 还公开了制造复合电极和包括其的固体氧化物燃料电池装置的方法。
摘要:
Disclosed is a segmented modular solid oxide fuel cell device having a plurality of independently controllable electrical power producing segments disposed within a common thermal environment. Also disclosed are methods for selectively operating one or more segments of the disclosed segmented modular solid oxide fuel cell device. Also disclosed are methods for performing a maintenance process on one or more segments of a segmented modular fuel cell device during fuel cell operation.
摘要:
An electrolyte sheet comprising two major surfaces, the electrolyte sheet including regions of differing compositions, so that (i) at least one of these regions has at least 1.5 times higher ionic conductivity than at least one other region; (ii) wherein the at least one other region has 20% more tetragonal phase zirconia per volume than the least one region with higher ionic conductivity; and (iii) when viewed in cross-section taken through said major surfaces at least one of the regions exhibits a non-uniform thickness.
摘要:
Disclosed is a segmented modular solid oxide fuel cell device having a plurality of independently controllable electrical power producing segments disposed within a common thermal environment. Also disclosed are methods for selectively operating one or more segments of the disclosed segmented modular solid oxide fuel cell device. Also disclosed are methods for performing a maintenance process on one or more segments of a segmented modular fuel cell device during fuel cell operation.
摘要:
The invention is directed to highly crystalline, frit-sintered glass-ceramic materials and seals made using them that are suitable for solid oxide fuel cell applications. The seals have a coefficient of thermal expansion in the range of 70-130×10−7° C., preferably 85-115×10−7° C. The glass-ceramic materials have a crystalline component and a glass component, the crystalline component being>50% of the glass-ceramic and the glass component being 75%. Regarding the crystalline component only,>50% of the crystals in the crystalline component of the glass-ceramic has a structure selected from the structural groups represented by walstromite, cyclowollastonite, μ-(Ca,Sr)SiO3, kalsilite, kaliophilite and wollastonite (the primary crystalline phase) and the remaining
摘要:
An exemplary method of making a fuel cell device assemblies includes the steps of: (i) providing a ceramic batch; (ii) extruding the ceramic batch through a die and a mask to form green extrudate that, in cross-section, has at least 10 cells/in2 and wall thickness of 50 mils or less; (iii) cutting the green extrudate to an appropriate length to form a green frame blank; (iv) sintering the green frame blank at a temperature of at least 1200° C., preferably at a temperature of between 1400° C. and 1600° C. for at least one hour to form a ceramic frame with a plurality of parallel channels; (v) inserting at least one fuel cell array into its designated position within the ceramic frame; and (vi) sealing the at least one fuel cell array to the frame.
摘要:
According to one embodiment of the present invention a fuel cell system comprises: (i) a plurality of fuel cell packets, each packet comprising at least one fuel inlet, at least one fuel outlet, a frame, and two multi-cell fuel cell devices, the fuel cell devices situated such that an anode side of one fuel cell device faces an anode side of another fuel cell device, and the two fuel cell devices, in combination, at least partially form a fuel chamber connected to the fuel inlet and the fuel outlet; (ii) a plurality of heat exchange packets, each packet comprising at least one oxidant inlet, at least one oxidant outlet, and an internal oxidant chamber connected to the at least one oxidant inlet and the least one oxidant outlet; the heat exchange packets being parallel to and interspersed between the fuel cell packets, such that the heat exchange packets face the fuel cell packets and form, at least in part, a plurality of cathode reaction chambers between the heat exchange packets and the fuel cell packets; (iii) a housing supporting and enclosing the fuel packets and the heat exchange packets; (iv) an oxidant inlet plenum operatively connected to oxidant inlets of the heat exchange packets; (v) an oxidant exhaust plenum operatively connected to the cathode reaction chambers; (vi) an inlet fuel manifold connected to fuel inlets of the fuel cell packets; and (vii) an exhaust fuel manifold connected to the fuel outlets of the fuel cell packets.
摘要:
Embodiments are directed to glass frits containing phosphors that can be used in LED lighting devices and for methods associated therewith for making the phosphor containing glass frit and their use in glass articles, for example, LED devices.
摘要:
A flame spray pyrolysis method for making nanoscale, lithium ion-conductive ceramic powders comprises providing a precursor solution comprising chemical precursors dissolved in an organic solvent, and spraying the precursor solution into an oxidizing flame to form a nanoscale, lithium ion-conductive ceramic powder, wherein a concentration of the chemical precursors in the solvent ranges from 1 to 20 M. The precursor solution can comprise 1-20% excess lithium with respect to a stoichiometric composition of the ceramic powder. Nominal compositions of the nanoscale, ceramic powders are Li1.4Al0.4M1.6(PO4)3 where M is Ti or Ge.
摘要:
A method of forming a solid, dense, hermetic lithium-ion electrolyte membrane comprises combing an amorphous, glassy, or low melting temperature solid reactant with a refractory oxide reactant to form a mixture, casting the mixture to form a green body, and sintering the green body to form a solid membrane. The resulting electrolyte membranes can be incorporated into lithium-ion batteries.