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    Preparation of cross-linked modified organopolysiloxanes
    21.
    发明授权
    Preparation of cross-linked modified organopolysiloxanes 失效
    交联改性有机聚硅氧烷的制备

    公开(公告)号：US4170610A

    公开(公告)日：1979-10-09

    申请号：US895835

    申请日：1978-04-13

    申请人： Bernward Deubzer ,  Erich Brunner

    发明人： Bernward Deubzer ,  Erich Brunner

    IPC分类号： C08G77/00 ,  C08F283/12 ,  C08G77/42

    CPC分类号： C08F283/122 ,  C08K5/0008

    摘要： A process for preparing cross-linked, modified organopolysiloxanes which comprises polymerizing at least one monomer having at least one aliphatic multiple bond in the presence of a free radical initiator and at least one cross-linked organopolysiloxane containing at least 40 mol percent of monoorganosiloxane units. When the organopolysiloxane is not crosslinked, then the polymerization of the monomer having at least one aliphatic multiple bond is conducted in the presence of an organopolysiloxane having at least 40 mol percent mono-organosiloxane units, and a free radical initiator and a catalyst which promotes cross-linking of the organopolysiloxane.

    摘要翻译： 一种制备交联改性的有机聚硅氧烷的方法，该方法包括在自由基引发剂和至少一种含有至少40mol％单有机硅氧烷单元的交联的有机聚硅氧烷的存在下聚合至少一种具有至少一个脂族多重键的单体。 当有机聚硅氧烷不交联时，具有至少一个脂族多重键的单体的聚合在具有至少40mol％单有机硅氧烷单元的有机聚硅氧烷和自由基引发剂和促进交叉的催化剂存在下进行 连接有机聚硅氧烷。

    Aqueous 1-component silicone composition
    23.
    发明授权
    Aqueous 1-component silicone composition 失效
    水性1-组分硅氧烷组合物

    公开(公告)号：US06699930B1

    公开(公告)日：2004-03-02

    申请号：US09619048

    申请日：2000-07-18

    申请人： Manfred Schmidt ,  Antje Lässig ,  Bernward Deubzer ,  Frank Baumann

    发明人： Manfred Schmidt ,  Antje Lässig ,  Bernward Deubzer ,  Frank Baumann

    IPC分类号： C08L8300

    CPC分类号： C08L83/04 ,  C08G77/16 ,  C08G77/18 ,  C09D183/04 ,  C08L83/00 ,  C08L2666/28

    摘要： An aqueous 1-component composition which forms a resilient silicone network on drying and is obtained by reaction, at a temperature of at least 40° C., of I) a surfactant-stabilized dispersion of a highly crosslinked silicone compound which carries reactive groups which are selected from silanol, hydrocarbon-oxy and silanolate groups with II) a surfactant-stabilized emulsion of optionally precrosslinked silicone oil which carries reactive groups which are selected from silanol, hydrocarbon-oxy and silanolate groups.

    摘要翻译： 在干燥时形成弹性硅酮网络的水性1-组分组合物，其通过在至少40℃的温度下反应获得I）表面活性剂稳定的高度交联的硅氧烷化合物的分散体，其携带反应性基团，其为 选自硅烷醇，烃 - 氧基和硅烷醇酯基团; II）任选预交联的硅油的表面活性剂稳定的乳液，其携带选自硅烷醇，烃 - 氧基和硅烷醇酯基团的反应性基团。

    Polymeric organosilicon compounds, their production and use
    24.
    发明授权
    Polymeric organosilicon compounds, their production and use 失效
    聚合有机硅化合物，其生产和使用

    公开(公告)号：US06258913B1

    公开(公告)日：2001-07-10

    申请号：US09341485

    申请日：1999-08-13

    申请人： Christian Herzig ,  Robert Banfic ,  Reinhard Stallbauer ,  Bernward Deubzer ,  David Heuttner

    发明人： Christian Herzig ,  Robert Banfic ,  Reinhard Stallbauer ,  Bernward Deubzer ,  David Heuttner

    IPC分类号： C08G7708

    CPC分类号： C08G77/50 ,  C08G77/20 ,  C09D183/14 ,  Y10T428/31663 ,  C08L83/00

    摘要： The invention relates to novel polymeric organosilicon compounds comprising hydrocarbon radicals with at least one aliphatic carbon-carbon double bond in a terminal position. To produce these compounds, (A) compounds containing at least one aliphatic carbon-carbon double bond per molecule, in a terminal position, are reacted with (B) oligomeric or polymeric organosilicon compounds containing units of the general formula R1R2SiO1/2 and units of the general formula HRSiO and/or HSiO3/2 and possibly units of the general formula R2SiO, where R is a monovalent, possibly substituted, hydrocarbon radical with between 1 and 18 carbon atoms per radical, which is free of aliphatic carbon-carbon double bonds, and R1 is a monovalent hydrocarbon radical with between 1 and 18 carbon atoms per radical which has at least one aliphatic carbon-carbon double bond in a terminal position, subject to the condition that the sum of the units HRSiO and R1R2SiO1/2 on average is greater than 2.0 if (B) contains no HSiO3/2 units, and the number of R1 radicals per molecule is greater than the number of Si-bonded hydrogen atoms, in the presence of (C) catalysts promoting the addition of Si-bonded hydrogen to aliphatic double-bonds. The ratio of aliphatic double bonds in components (A) and (B) to Si-bonded hydrogen in component (B) is between 1.5 and 10, subject to the condition that the polymeric organosilicon compounds on average contain more than two hydrocarbon radicals with at least one aliphatic carbon-carbon double bond in a terminal position.

    摘要翻译： 本发明涉及包含在最终位置具有至少一个脂族碳 - 碳双键的烃基的新型聚合物有机硅化合物。 为了制备这些化合物，（A）在每个分子中含有至少一个脂族碳 - 碳双键的化合物在末端与（B）含有通式R 1 R 2 SiO 1/2单元的低聚或聚合有机硅化合物反应， 通式HRSiO和/或HSiO3 / 2以及通式R2SiO的可能单元，其中R是每个基团具有1至18个碳原子的单价可能取代的烃基，其不含脂族碳 - 碳双键 并且R 1是每个基团具有1至18个碳原子的单价烃基，其在末端具有至少一个脂族碳 - 碳双键，条件是平均来说单位HRSiO和R 1 R 2 SiO 1/2的总和 如果（B）不含有HSiO3 / 2单元，并且在（C）催化剂的存在下，每分子的R1基团数目大于Si键合的氢原子的数目，则大于2.0，促进添加 硅键键合到脂肪族双键。 组分（B）中组分（A）和（B）中的脂族双键与Si键合的氢的比例为1.5至10，条件是聚合物有机硅化合物平均含有多于两个烃基， 在末端位置具有至少一个脂族碳 - 碳双键。

    Permanent organosilicon compounds, their preparation and use
    26.
    发明授权
    Permanent organosilicon compounds, their preparation and use 失效
    永久性有机硅化合物，其制备和用途

    公开(公告)号：US5998562A

    公开(公告)日：1999-12-07

    申请号：US888934

    申请日：1997-07-07

    申请人： Guenter Mahr ,  Jochen Dauth ,  Bernward Deubzer ,  Monika Ott ,  Petra Gratzl ,  Hans Lautenschlager

    发明人： Guenter Mahr ,  Jochen Dauth ,  Bernward Deubzer ,  Monika Ott ,  Petra Gratzl ,  Hans Lautenschlager

    IPC分类号： C14C11/00 ,  C07F7/10 ,  C07F7/18 ,  C08G77/10 ,  C08G77/26 ,  C08G77/388 ,  C08G77/54 ,  D06M15/643 ,  C08G77/08

    CPC分类号： C08G77/388 ,  C08G77/54 ,  Y10S8/01

    摘要： The present invention relates to triazine-containing organosilicon compounds having units of the formulaA.sub.a R.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I),whereR is identical or different and denotes a hydrogen atom or a monovalent substituted or unsubstituted hydrocarbon radical, having 1 to 26 carbon atoms, preferably 1 to 18 per radical,X is identical or different and is a halogen atom, a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical, having 1 to 18 carbon atoms, preferably 1 to 8 per radical and which may be substituted by an ether oxygen atom,a is 0 or 1, preferably 0.01-0.5b is 0, 1, 2 or 3, preferably 0.5-3.0c is 0, 1, 2 or 3, preferably 0.0-2.0 and the sum a+b+c.ltoreq.4, preferably 0.1-3.5, andA is a radical of the formula ##STR1## where R.sup.2 is an unbranched or branched, optionally substituted alkylene radical, having 1 to 18, preferably 1 to 12, carbon atoms,Y is identical or different and denotes a hydrogen atom or an unbranched or branched alkyl radical, having 1 to 12, preferably 1 to 8, carbon atoms or denotes a radical of the formula --OR.sup.1, where R.sup.1 has the meaning given above, andZ is identical or different and denotes X, --NR.sub.2, --(O)CR or --SR, where X and R have the meanings given above with the proviso that at least one radical A containing at least one halogen atom, preferably a chlorine atom, is present per polymer molecule.

    摘要翻译： 本发明涉及具有式AaRbXcSiO（4-abc）/ 2（I）单元的含三嗪的有机硅化合物，其中R相同或不同，表示氢原子或一价取代或未取代的烃基，其具有1至 26个碳原子，优选1至18个基团，X相同或不同，为卤素原子，氯原子或式-OR1基团，其中R1表示具有1至18个碳原子的烷基，优选1 至8个，并且可被醚氧原子取代，a为0或1，优选为0.01-0.5b为0,1,2或3，优选0.5-3.0c为0,1,2或3，优选为 总和a + b + c 4，优选0.1-3.5，A是下式的基团，其中R 2是无支链或支链的任选取代的亚烷基，其具有1至18，优选1至 12，碳原子，Y相同或不同，表示氢原子或无支链或支链烷基，具有1至12个， 优选为1〜8个碳原子，或表示式-OR1的基团，其中R1具有上述含义，Z相同或不同，表示X，-NR2， - （O）CR或-SR，其中X和 R具有上述含义，条件是每个聚合物分子存在至少一个含有至少一个卤素原子，优选氯原子的基团A.

    Crosslinkable compositions
    28.
    发明授权
    Crosslinkable compositions 失效
    可交联组合物

    公开(公告)号：US5691435A

    公开(公告)日：1997-11-25

    申请号：US782871

    申请日：1997-01-14

    申请人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  Robert Banfic

    发明人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  Robert Banfic

    IPC分类号： C08L83/05 ,  C07F7/08 ,  C08G77/12 ,  C08G77/48 ,  C08K5/5419 ,  C08L83/07 ,  C09D183/04 ,  C09D183/05 ,  C09D183/07 ,  C09J183/07 ,  C08G77/08

    CPC分类号： C08K5/5419 ,  C07F7/0896 ,  C08G77/12 ,  C08G77/485 ,  C09D183/04

    摘要： The present invention provides crosslinkable compositions comprising (A) an organosilicon compound having radicals containing aliphatic carbon-carbon multiple bonds, (B) an organosilicon compound having Si-bonded hydrogen atoms, (C) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bond, and optionally (D) an agent which retards the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperature and to the use of the crosslinkable compositions for producing coatings which repel tacky substances. The present invention also relates to organosilicon compounds having Si-bonded hydrogen atoms, and to a process for their preparation.

    摘要翻译： 本发明提供可交联组合物，其包含（A）具有含有脂族碳 - 碳多重键的基团的有机硅化合物，（B）具有Si键合氢原子的有机硅化合物，（C）促进加入Si键合氢的催化剂 和任选的（D）在室温下将Si键合的氢加成到脂肪族多键上的试剂，以及使用可交联组合物来制造排斥粘性物质的涂层。 本发明还涉及具有Si键合的氢原子的有机硅化合物及其制备方法。

    Organopolysiloxanes containing ester groups
    30.
    发明授权
    Organopolysiloxanes containing ester groups 失效
    含有酯基的有机聚硅氧烷

    公开(公告)号：US5446119A

    公开(公告)日：1995-08-29

    申请号：US279382

    申请日：1994-07-25

    申请人： Christian Herzig ,  Willibald Burger ,  Bernward Deubzer ,  Martina Bloechl

    发明人： Christian Herzig ,  Willibald Burger ,  Bernward Deubzer ,  Martina Bloechl

    IPC分类号： B01J31/02 ,  B01J31/04 ,  C08G63/68 ,  C08G63/695 ,  C08G77/20 ,  C08G77/38 ,  C08G77/42 ,  C08G77/445 ,  C08G77/46 ,  C08G81/00 ,  C08G77/16

    CPC分类号： C08G77/20 ,  C08G77/38 ,  C08G77/46

    摘要： Organopolysiloxanes which contain ester groups and comprise units of the formula ##EQU1## in which R may be an identical or different monovalent, SiC-bonded hydrocarbon radical having 1 to 18 carbon atoms,A may be an identical or different radical of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, c, v, w, s, t,is 0 or an integer, the sum of s and tbeing an integer from 1 to 20,x is 0 or 1,y is 0 or 1, the sum of x and y being 1 or 2,a is 0, 1, 2 or 3, andb is 0, 1 or 2,with the proviso that the sum of a and b is less than or equal to 3 and the organopolysiloxane contains at least one radical A per molecule.

    摘要翻译： 含有酯基并且包含式（I）的单元的有机聚硅氧烷，其中R可以是具有1至18个碳原子的相同或不同的一价SiC键合烃基，A可以是相同或不同的 式中，R1，R2，R3，c，v，w，s，t为0或整数，s和t之和为1〜20的整数，x为0或1 ，y为0或1，x和y之和为1或2，a为0,1,2或3，b为0,1或2，条件是a和b的和小于 或等于3，有机聚硅氧烷每分子含有至少一个基团A.