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公开(公告)号：US06423435B1
公开(公告)日：2002-07-23
申请号：US09517527
申请日：2000-03-02
IPC分类号： H01M804
CPC分类号： C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0405 , C01B2203/041 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/0495 , C01B2203/066 , C01B2203/0844 , C01B2203/0883 , C01B2203/1247 , C01B2203/1288 , C01B2203/142 , C01B2203/146 , C01B2203/147 , C01B2203/148 , C01B2203/16 , C01B2203/82 , H01M8/04029 , H01M8/04097 , H01M8/04156 , H01M8/0612 , H01M8/0662 , H01M2300/0082
摘要： A fuel cell system has at least one fuel cell and a hydrogen generating arrangement for feeding the fuel cell anode with a hydrogen-containing product gas from a conversion reaction of a hydrocarbon starting substance or hydrocarbon derivative with of water fed supplied by way of a water feeding system. Water recovery devices are provided for condensing water out of the process gas supplied by the hydrogen generating arrangement, and/or out of the cathode waste gas carried away from the fuel cell cathode, and returning the condensed-out water into the water feeding system.
摘要翻译： 燃料电池系统具有至少一个燃料电池和氢生成装置，用于从烃起始物质或烃衍生物与通过水供给的水的转化反应将含有氢的产物气体供给燃料电池阳极 喂养系统。 提供水回收装置，用于将由氢气发生装置供应的工艺气体中的水和/或从燃料电池阴极携带的阴极废气中的水冷凝，并将冷凝的水返回给水系统。
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22.发明授权Process for operating a water vapor reforming system, a reforming system operable thereby and a fuel cell system operating process 有权用于操作水蒸气重整系统的方法，可操作的重整系统和燃料电池系统操作过程公开(公告)号：US06294149B1
公开(公告)日：2001-09-25
申请号：US09212290
申请日：1998-12-16
IPC分类号： C01B302
CPC分类号： H01M8/0631 , B01B1/005 , B01J8/009 , B01J2208/00327 , B01J2208/00504 , C01B3/323 , C01B3/384 , C01B3/386 , C01B3/501 , C01B2203/0233 , C01B2203/0261 , C01B2203/0405 , C01B2203/041 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/085 , C01B2203/0866 , C01B2203/1223 , C01B2203/1276 , C01B2203/1288 , C01B2203/1604 , H01M8/04007 , H01M8/0612 , H01M2250/20 , Y02P20/128 , Y02T90/32
摘要： The invention relates to a process for operating a system for the water vapor reforming of a hydrocarbon. The system includes a reactor which is suitable for POX operation as well as for a reforming operation, an evaporator, a hydrogen separating stage, and a catalytic burner device. A first part of the catalytic burner device is in thermal contact with the reforming reactor, and a second part of the burner device is in thermal contact with the evaporator. An air/hydrocarbon intermediate feeding pipe for the reactor and a pressure maintaining valve are provided for changing the reactor between the POX operation and the reforming operation. According to the process, during cold start of the system, a heating operation is carried out during which the reactor is first used in the POX operation at a lower pressure and subsequently is used for the reforming operation and simultaneously the pressure is increased to the normal operating pressure. The invention is particularly useful for the water vapor reforming of methanol for obtaining hydrogen for a fuel-cell-operated motor vehicle.
摘要翻译： 本发明涉及一种操作烃类水汽重整系统的方法。 该系统包括适用于POX操作以及重整操作的反应器，蒸发器，氢分离级和催化燃烧器装置。 催化燃烧器装置的第一部分与重整反应器热接触，并且燃烧器装置的第二部分与蒸发器热接触。 提供了用于反应器的空气/烃中间进料管和保压阀，用于在POX操作和重整操作之间改变反应器。 根据该方法，在系统的冷启动期间，进行加压操作，在该加热操作期间，在较低压力下POX操作中首先使用反应器，随后用于重整操作，同时将压力提高到正常 运营压力。 本发明对于用于获得用于燃料电池操作的机动车辆的氢的甲醇的水蒸汽重整特别有用。
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公开(公告)号：US6090499A
公开(公告)日：2000-07-18
申请号：US64762
申请日：1998-04-23
申请人： Rainer Autenrieth , Dietmar Heil
发明人： Rainer Autenrieth , Dietmar Heil
CPC分类号： H01M8/0631 , B01J8/008 , B01J8/0085 , B01J8/02 , B01J8/0278 , C01B3/323 , C01B3/382 , C01B3/48 , B01J2208/00699 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/0833 , C01B2203/0844 , C01B2203/0866 , C01B2203/1011 , C01B2203/1223 , C01B2203/1258 , C01B2203/1288 , C01B2203/142 , C01B2203/82
摘要： A reforming reactor system, suitable in particular for water vapor reforming of methanol, has a reforming reactor in which a reforming catalyst material is situated. A drop catching element is assigned to the inlet side of the reforming reactor, in order to catch drops which may be contained in the gas/vapor mixture, and thus prevent their damaging contact with the catalyst material.
摘要翻译： 特别适用于甲醇的水蒸气重整的重整反应器系统具有其中设置有重整催化剂材料的重整反应器。 为了捕获可能包含在气体/蒸气混合物中的液滴，并且因此防止其与催化剂材料的破坏性接触，将分液捕获元件分配到重整反应器的入口侧。
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公开(公告)号：US20130065147A1
公开(公告)日：2013-03-14
申请号：US13695354
申请日：2011-03-30
申请人： Rainer Autenrieth
发明人： Rainer Autenrieth
IPC分类号： H01M8/04
CPC分类号： H01M8/04619 , H01M8/04626 , H01M8/04955
摘要： A method for operating a fuel cell system for supplying at least one electrical consumer with electric energy is provided. The fuel cell system includes a fuel cell and an accessory for supplying the fuel cell. The efficiency of the fuel cell system is determined and the fuel cell is switched off temporarily when the efficiency of the fuel cell system falls below a switch-limit efficiency.
摘要翻译： 提供了一种用于操作用于向至少一个消费者提供电能的燃料电池系统的方法。 燃料电池系统包括燃料电池和用于供应燃料电池的附件。 当燃料电池系统的效率低于开关限制效率时，确定燃料电池系统的效率并暂时关闭燃料电池。
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公开(公告)号：US07261750B1
公开(公告)日：2007-08-28
申请号：US09715044
申请日：2000-11-20
IPC分类号： C01B3/24
CPC分类号： H01M8/0631 , B01J8/025 , B01J8/0278 , B01J8/0453 , B01J8/0492 , B01J12/007 , B01J19/2485 , B01J2208/00504 , B01J2208/00716 , B01J2219/00157 , C01B3/382 , C01B2203/0244 , C01B2203/142 , C01B2203/1604 , C01B2203/82 , H01M8/0612
摘要： A method for the autothermal reforming of a hydrocarbon, in particular of diesel, includes introducing a combustible mixture of the hydrocarbon to be reformed and an oxygen-containing medium into a first reaction zone of a reformer, A gas-phase reaction is ignited. After an operating temperature required for the autothermal reforming process is reached, water or a water-containing medium is introduced into the first reaction zone, and the water content is increased until the conditions for the reforming process of the hydrocarbon prevail. The reforming process then takes place predominantly in a second reaction zone.
摘要翻译： 烃，特别是柴油的自热重整的方法包括将待重整烃和可燃混合物引入重整器的第一反应区，引发气相反应。 达到自热重整工艺所需的工作温度后，将水或含水介质引入第一反应区，水分含量增加直到烃类重整过程的条件为准。 然后重整过程主要发生在第二反应区中。
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公开(公告)号：US20060166050A1
公开(公告)日：2006-07-27
申请号：US10541212
申请日：2003-12-30
申请人： Rainer Autenrieth
发明人： Rainer Autenrieth
CPC分类号： H01M8/0494 , B60L58/30 , H01M8/04947 , H01M16/006 , H01M2250/20 , Y02T10/92 , Y02T90/32 , Y02T90/34
摘要： A fuel cell system for supplying at least one electric load with electric power includes at least one fuel cell and an energy storage device, and also a switching device for disconnecting and connecting the fuel cell system from and to the at least one load. The switching device has at least two switches, so that the fuel cell and the energy storage device can be disconnected and connected from and to the at least one electric load independently of one another. In addition, a method is provided for operating such a fuel cell system.
摘要翻译： 用于向电力供应至少一个电力负载的燃料电池系统包括至少一个燃料电池和能量存储装置，以及用于从燃料电池系统断开和连接至少一个负载的开关装置。 开关装置具有至少两个开关，使得燃料电池和能量存储装置可以彼此独立地断开并连接到至少一个电负载。 此外，提供了用于操作这种燃料电池系统的方法。
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公开(公告)号：US20050031915A1
公开(公告)日：2005-02-10
申请号：US10734590
申请日：2003-12-15
申请人： Rainer Autenrieth
发明人： Rainer Autenrieth
CPC分类号： H01M8/04388 , H01M8/04089 , H01M8/04201 , H01M8/0494 , H01M8/04947 , H01M8/04955
摘要： In a method for controlling fuel supply to a fuel cell system having at least one fuel cell, the power withdrawal from the fuel cell is performed via a timed switching-on and switching-off of an electric connection between the fuel cell and a consuming device, as a function of the fuel present in the fuel cell. The quantity of fuel is controlled as a function of a pause to switch-on ratio of the timed connection of the fuel cell with the consuming device in such a manner that, based on an actual value of the pause to switch-on ratio, a predefined desired value of the pause to switch-on ratio is set.
摘要翻译： 在用于控制向具有至少一个燃料电池的燃料电池系统的燃料供给的方法中，通过燃料电池和消耗装置之间的电连接的定时接通和断开来执行从燃料电池的停电 ，作为存在于燃料电池中的燃料的函数。 作为燃料电池与消耗装置的定时连接的接通比的暂停的控制，燃料的量以这样的方式被控制：基于暂停到接通比的实际值， 设置暂停到接通比的预定义期望值。
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公开(公告)号：US06432378B1
公开(公告)日：2002-08-13
申请号：US09094672
申请日：1998-06-15
IPC分类号： C01B316
CPC分类号： C01B3/326 , C01B3/323 , C01B2203/1076 , Y02P20/52 , Y02P20/584
摘要： A process for operating a methanol reforming system in which, in the reforming reaction operation, methanol is reformed in a methanol reforming reactor using a methanol reforming catalyst. The reforming reaction operation is interrupted periodically for catalyst reactivation phases during which the methanol reforming catalyst whose catalytic activity decreases in the reforming reaction operation is treated in an activity-regenerating manner. The process may be used in fuel-cell-driven motor vehicles for generating hydrogen for the fuel cells from methanol carried along in the liquid state.
摘要翻译： 一种操作甲醇重整系统的方法，其中在重整反应操作中，使用甲醇重整催化剂在甲醇重整反应器中重整甲醇。 对于催化剂再活化阶段，重整反应操作被周期性地中断，在该阶段，在重整反应操作中催化活性降低的甲醇重整催化剂以活性再生方式处理。 该方法可用于燃料电池驱动的机动车辆中，用于从处于液体状态的甲醇产生用于燃料电池的氢。
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公开(公告)号：US06355367B1
公开(公告)日：2002-03-12
申请号：US09513452
申请日：2000-03-03
IPC分类号： H01M804
CPC分类号： H01M8/0662 , B01J4/02 , B01J7/00 , C01B3/583 , C01B2203/044 , C01B2203/047 , H01M8/0612
摘要： A method and apparatus for applying pressure to at least one reactant for delivery from a storage tank to a gas generating system has at least one pump. An operating medium for applying pressure to the reactants is delivered from the pump to the storage tank via a pipe system. The operating medium itself may also be delivered to a reaction chamber as a reactant of the gas generating system.
摘要翻译： 向至少一种反应物施加压力以从储罐输送到气体发生系统的方法和装置具有至少一个泵。 用于向反应物施加压力的操作介质通过管道系统从泵输送到储罐。 操作介质本身也可以作为气体发生系统的反应物输送到反应室。
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公开(公告)号：US06171992B2
公开(公告)日：2001-01-09
申请号：US09097011
申请日：1998-06-15
IPC分类号： B01J2034
CPC分类号： C01B3/326 , C01B3/323 , C01B2203/1076 , Y02P20/52 , Y10S502/514
摘要： A methanol reforming reactor includes a reforming reaction space into which a methanol reforming catalyst is charged. The methanol reforming catalyst is present at the start of the reforming reaction operation in a pre-aged state in the reforming reaction space. A process for pre-aging the methanol reforming catalyst comprises heating at a temperature of between approximately 240° C. and approximately 350° C. and at a load of between approximately 0.5 m3H2/h and approximately 50 m3H2/h per liter of catalyst material in a methanol/water atmosphere. The reactor may be used in fuel-cell-operated motor vehicles for generating hydrogen for the fuel cells by means of the water vapor reforming of methanol.
摘要翻译： 甲醇重整反应器包括重整反应空间，甲醇重整催化剂装入其中。 甲醇重整催化剂在转化反应空间中的预老化状态下在重整反应操作开始时存在。 用于预熟化甲醇重整催化剂的方法包括在约240℃至约350℃之间的温度和约0.5m 3 H 2 / h至约50m 3 H 2 / h /升催化剂材料之间的温度下加热 在甲醇/水气氛中。 反应器可以用于燃料电池操作的机动车辆中，用于通过甲醇的水蒸汽重整产生用于燃料电池的氢气。
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