Chlorate-containing stabilizer system with nitrogen-containing synergists for stabilizing halogen-containing polymers
    21.
    发明授权
    Chlorate-containing stabilizer system with nitrogen-containing synergists for stabilizing halogen-containing polymers 失效
    含有氯酸盐的稳定剂体系,含有用于稳定含卤聚合物的含氮增效剂

    公开(公告)号:US07077981B2

    公开(公告)日:2006-07-18

    申请号:US10467947

    申请日:2001-12-12

    IPC分类号: C08K13/02

    摘要: The invention relates to stabilizer systems, containing at least: a) a perchlorate salt; b) at least one or more compounds from the group consisting of carbamides, indole derivatives and enamines of formula (I), wherein n=1 or 2 and X=O or NR1; n=3–6 and X=O; R1=H, C1–C4-alkyl, C2–C6-alkenyl, C6–C10-aryl, C7–C18-alkaryl or C7–C18-aralkyl; R2 (if n=1)=C1–C22-alkyl, C2–C22-alkenyl or aryl, preferably phenyl, optionally substituted with up to 3 hydroxy, C1–C4-alkoxy or C1–C9-alkyl; or R2 (if n=2–6)=linear or branched C1-22-alkylene, optionally interrupted by one or more O or S atoms, wherein R2 (if n=3) can also be a C2–C3-alkyl trisubstituted isocyanurate; if X=NH R2 can also be H. Said stabilizer systems are suitable for stabilizing halogen-containing polymers, more particularly PVC.

    摘要翻译: 本发明涉及稳定剂体系,其至少包含:a)高氯酸盐; b)至少一种或多种由式(I)的氨基甲酰胺,吲哚衍生物和烯胺组成的组,其中n = 1或2,X = O或NR 1; n = 3-6,X = O; R 1 = H,C 1 -C 4 - 烷基,C 2 -C 6 - 烷基,C 1 -C 4烷基,C 1 -C 4烷基, 亚烷基,C 6 -C 10 - 芳基,C 7 -C 18 - 烷芳基或C 1 -C 6 - C 7 -C 18 - 芳烷基; R 2(如果n = 1)= C 1 -C 22 - 烷基,C 2 -C 任选被至多3个羟基,C 1 -C 4 - 烷氧基或C 1 -C 6烷基取代的亚烷基或芳基,优选苯基 -C 9 - 烷基; 或R 2(如果n = 2-6)=直链或支链C 1-22 - 亚烷基,任选地被一个或多个O或S原子间隔,其中R' (如果n = 3)也可以是C 2 -C 3 - 烷基三取代的异氰脲酸酯; 如果X = NHR 2也可以是H.所述稳定剂体系适用于稳定含卤聚合物,更特别是PVC。

    1,3-Disubstituted 6-aminouracils for stabilizing halogenated polymers
    22.
    发明授权
    1,3-Disubstituted 6-aminouracils for stabilizing halogenated polymers 失效
    用于稳定卤化聚合物的1,3-二取代的6-氨基尿嘧啶

    公开(公告)号:US06274654B1

    公开(公告)日:2001-08-14

    申请号:US09338172

    申请日:1999-06-22

    IPC分类号: C08K534

    CPC分类号: C08K5/3462 C08L57/08

    摘要: A description is given of compositions comprising a chlorine-containing polymer and at least one compound of the general formula I where Y is S or O, and R1 and R2 independently of one another are unsubstituted or C1-C4-alkyl-, C1-C4-alkoxy- and/or hydroxyl-substituted phenyl, phenyl-C1-C4-alkyl which is unsubstituted or substituted on the phenyl ring by C1-C4-alkyl, C1-C5-alkoxy and/or hydroxyl, or are C3-C6-alkenyl, C5-C8-cycloalkyl, or C2-C10-alkyl interrupted by at least 1 oxygen atom, or, if R1 and R2 are different from one another, one of the two radicals can be C2-C12-alkyl and the other can be C2-C12-alkyl or one of the above radicals, or, if R1 and R2 are identical, both can also be C5-C12-alkyl, and, if Y is sulfur, R1 and R2 cannot be octyl.

    摘要翻译: 描述了包含含氯聚合物和至少一种通式I的化合物的组合物,其中Y是S或O,R 1和R 2彼此独立地是未取代的或C 1 -C 4烷基 - ,C 1 -C 4 - 烷氧基 - 和/或羟基取代的苯基,未被取代或在苯环上被C1-C4-烷基,C1-C5-烷氧基和/或羟基取代的苯基-C1-C4-烷基,或为C3-C6-烯基, C 5 -C 8 - 环烷基或被至少1个氧原子间断的C 2 -C 10烷基,或者如果R 1和R 2彼此不同,则两个基团之一可以是C 2 -C 12烷基,另一个可以是C 2 -C 12 - 烷基或上述基团之一,或者如果R 1和R 2相同,则两者也可以是C 5 -C 12 - 烷基,如果Y是硫,则R 1和R 2不能是辛基。

    Novel adducts
    24.
    发明授权
    Novel adducts 失效
    新加盟

    公开(公告)号:US4245125A

    公开(公告)日:1981-01-13

    申请号:US37599

    申请日:1979-05-10

    摘要: Compounds of the formula IA.multidot.m B (I)whereinA is a compound of the formula II or III ##STR1## m is a rational number between 0.1 and 4.0, and B is H.sub.2 O.sub.2, N.sub.2 H.sub.4 or NH.sub.2 OH, andR.sub.1 is an unsubstituted or substituted aliphatic or aromatic hydrocarbon radical which has 3-30 C atoms and which can be interrupted by oxygen or sulfur atoms,R.sub.2 is hydrogen or C.sub.1 -C.sub.30 alkyl,X is --O-- or --SO.sub.2 -- and, in the case where B is N.sub.2 H.sub.4 or NH.sub.2 OH, also --S-- or --SO--,Y is the direct bond, ##STR2## Q is --CH.sub.2, --CH(OH)--CH.sub.2 -- or --CH(CH.sub.2 --OH)--, and n is 1, 2, 3, 4, 5, 6, 7 or 8.

    摘要翻译: 式I Axm B(I)的化合物,其中A是式II或III的化合物,其中的有机数为0.1至4.0,B为H 2 O 2,N 2 H 4或NH 2 OH,R 1为未取代或取代的 具有3-30个碳原子并且可以被氧或硫原子间隔的脂族或芳族烃基,R2是氢或C1-C30烷基,X是-O-或-SO2-,并且在B是N2H4的情况下 或NH 2 OH,也是-S-或-SO-,Y是直接键,Q是-CH 2,-CH(OH)-CH 2 - 或-CH(CH 2 -OH) - ,n是1,2 ,3,4,5,6,7或8。

    Stabilizer system for the stabilisation of halogenated polymers

    公开(公告)号:US20060235124A1

    公开(公告)日:2006-10-19

    申请号:US10555021

    申请日:2004-04-02

    IPC分类号: C08K5/36

    CPC分类号: C08K5/17 C08K5/41 C08L57/08

    摘要: The invention relates to a mixture of stabilisers for the stabilisation of chlorinated polymers, comprising at least a) a sulphate ester salt and/or a sulphonate salt of formula (I): [R(O)aSO3]1M and b) an alkanolamine of formula (II), where M=alkali, earth alkali, lanthanide (Cer) or aluminium cation, t=metal cation valence of 1, 2 or 3; s=0 or 1, R=C1-C22 a phenyl, C7-C10 phenylalkyl, C7 -C24 alkylphenyl, x=1, 2 or 3: y=1, 2, 3, 4, 5 or 6; n=1-10. R1, R2 independently=H. C1-C22 alkyl, —[—(CHR3a)y—CHR3b—O—]a—H, —[—(CHR3a)y—CHR3b—O-]n-CO—R4, C2-C20 alkenyl, C2-C18 acyl, C4-C8 cycloalkyl, optionally substituted at the B-position by OH, C6-C10 aryl, C7-C10 alkaryl or C7-C10 aralkyl, or when x=1, R1 and R2 together with the N can form a closed 4-10 membered ring of carbon atoms with optionally up to 2 heteroatoms, or when x=2, R1 also=C2-C18 alkylene, optionally substituted at both B-carbon atoms with OH and/or interrupted by 1 or more O atoms and/or 1 or more NR2 groups, or dihydroxysubstituted tetrahydrodicyclopentadienylene, dihydroxysubstituted ethylcyclohexanylene, dihydroyxsubstituted 4,4′-bisphenol-A-dipropylether)ylene, isophoronylene, dimethylcyclohexanylene, dicyclohoxylmethanylene or 3,3′-dimethyldicyclohexylmethanylene and when x=3, R1 also=trihydroxysubstituted (tri-N-propylisocyanurate)triyl, R3a, R3b independently=C1-C22 alkyl, C2-C6 alkenyl) C6-C10 aryl, H or CH2—X—R5, where X═O, S, —O—CO— or —CO—O—; R4═C1-C18 alkyl/alkenyl or phenyl and R5═H, C1-C22 alkyl, C2-C22 alkenyl or C6-C10 aryl.

    Monosubstituted 6-aminouracils for the stabilization of halogenated polymers
    28.
    发明申请
    Monosubstituted 6-aminouracils for the stabilization of halogenated polymers 审中-公开
    用于稳定卤代聚合物的单取代的6-氨基尿嘧啶

    公开(公告)号:US20060148941A1

    公开(公告)日:2006-07-06

    申请号:US10537331

    申请日:2003-11-19

    IPC分类号: C08K5/34

    CPC分类号: C08K5/3462 C08L27/06

    摘要: Compositions comprising a chlorinated polymer and at least one compound of formula (I) where R1 or R2=linear or branched C3-C22 alkyl, unsubstituted or substituted with C1-C4 alkyl/alkoxy and/or hydroxy phenyl, unsubstituted or substituted by C1-C4 alkyl/alkoxy and/or hydroxy phenyl C1-C4 alkyl, linear or branched C3-C18 alkenyl, C3-C8— cycloalkyl, C3-C10 alkyl or C3-C10 hydroxyalkyl or acetoxy/benzoyloxy C2-C10 alkyl interrupted by at least one oxygen atom, as stabilisers for halogenated polymers.

    摘要翻译: 包含氯化聚合物和至少一种式(I)化合物的组合物,其中R 1或R 2 =直链或支链C 3 -C 未取代或被C 1 -C 4烷基取代或未取代或被C 1 -C 4烷基取代的烷基, C 1 -C 4烷基/烷氧基和/或羟基苯基C 1 -C 4烷基,直链或支链C

    Cyanoacetylureas for stabilizing halogenated polymers
    29.
    发明授权
    Cyanoacetylureas for stabilizing halogenated polymers 失效
    用于稳定卤化聚合物的氰基乙酰脲

    公开(公告)号:US06211270B1

    公开(公告)日:2001-04-03

    申请号:US09323975

    申请日:1999-06-02

    IPC分类号: C08K521

    CPC分类号: C08K5/315 C08K5/405 C08L27/06

    摘要: A description is given of compositions comprising a chlorine-containing polymer and at least one compound of the general formula I where x is oxygen or sulfur, and R is C2-C22-acyloxyalkyl or C1-C12-alkyl which may be interrupted by 1 to 3 oxygen atoms and/or substituted by 1 to 3 OH groups, or is C3-C8-alkenyl, C7-C10-phenylalkyl, C5-C8-cycloalkyl, C7-C10-alkylphenyl, phenyl or naphthyl, where the aromatic radical in each case may be substituted by —OH, C1-C12-alkyl and/or OC1-C4-alkyl, and R1 is hydrogen or is as defined for R.

    摘要翻译: 给出了包含含氯聚合物和至少一种通式I的化合物的组合物的描述,其中x是氧或硫,R是可被1至3个氧原子间隔的C 2 -C 22 - 酰氧基烷基或C 1 -C 12 - 烷基 或/或被1至3个OH基取代,或为C 3 -C 8 - 烯基,C 7 -C 10 - 苯基烷基,C 5 -C 8 - 环烷基,C 7 -C 10 - 烷基苯基,苯基或萘基,其中每种情况下的芳族基团可以是 被-OH,C 1 -C 12烷基和/或OC 1 -C 4烷基取代,R 1是氢或根据R定义。