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    Complex compounds, process for their preparation, and their use
    6.
    发明授权
    Complex compounds, process for their preparation, and their use 失效
    复合物，其制备方法及其用途

    公开(公告)号：US4425278A

    公开(公告)日：1984-01-10

    申请号：US278763

    申请日：1981-06-29

    申请人： Hermann O. Wirth ,  Hans-Helmut Friedrich

    发明人： Hermann O. Wirth ,  Hans-Helmut Friedrich

    IPC分类号： C08K5/00 ,  C09K3/16 ,  C07F11/00 ,  C07F15/04

    CPC分类号： C09K3/16 ,  C08K5/0091

    摘要： A complex compound of a metal salt or metalloid salt and an ansolvo-acid or proton-acid, of the general formula IM.sub.n.sup.m.X.sub.m.sup.n.pY.qZ (I)in which M is a m-valent cation of a metal or metalloid, a metal-oxy or metal-dioxy cation or a hydrogen atom, X is a n-valent anion of a n-basic inorganic proton-acid or of a n-basic organic acid selected from the group of the aliphatic and cycloaliphatic carboxylic acids with up to 8 C atoms, which can be substituted by halogen and/or hydroxyl groups, the aromatic monocarboxylic, dicarboxylic and tricarboxylic acids, which may be substituted by hydroxyl, halogen and/or nitro groups, the organic oxyacids of phosphorus and sulphur, the organic thioacids of phosphorus, and the mercaptans, the inorganic or organic acid having a pK.sub.a value of at most 15.8 or, if M is a proton, of at most 11, Y is water or a neutral organic molecule which can be bound coodinatively by the cation or the anion, Z is a complex-forming vicinal diol with at least 6 C atoms, p is 0 or a value between 0 and 2, q is a value from 1 to 32, m is an integer from 1 to 6 and, if M is a hydrogen atom, is 1 and n is an integer from 1 to 4, and mixtures of such compounds.

    摘要翻译： 通式I Mnm.Xmn.pY.qZ（I）的金属盐或准金属盐和壬酸或质子酸的络合物，其中M是金属或准金属的m价阳离子， 金属氧化物或金属二氧化物阳离子或氢原子，X是正碱性无机质子酸或正碱性有机酸的n价阴离子，选自脂肪族和脂环族羧酸， 可以被卤素和/或羟基取代的高达8个C原子，可以被羟基，卤素和/或硝基取代的芳族单羧酸，二羧酸和三羧酸，磷和硫的有机含氧， 磷的有机硫代酸和硫醇，pKa值至多为15.8的无机或有机酸，或者如果M是质子，则至多为11，Y是水或中和有机分子，其可以通过 阳离子或阴离子，Z是具有至少6个C原子的络合物形成的邻位二醇，p为0 r值在0和2之间，q是1至32的数值，m是1至6的整数，如果M是氢原子，则为1，n是1至4的整数，并且这些化合物的混合物 。

    Pyrrole stabilizers for chlorine-containing thermoplastics
    7.
    发明授权
    Pyrrole stabilizers for chlorine-containing thermoplastics 失效
    含氯热塑性塑料的吡咯稳定剂

    公开(公告)号：US4369276A

    公开(公告)日：1983-01-18

    申请号：US266872

    申请日：1981-05-26

    申请人： Hermann O. Wirth ,  Jurgen Bussing ,  Hans-Helmut Friedrich

    发明人： Hermann O. Wirth ,  Jurgen Bussing ,  Hans-Helmut Friedrich

    IPC分类号： C09K15/30 ,  C07D207/00 ,  C07D207/32 ,  C07D207/333 ,  C07D207/34 ,  C07D209/52 ,  C08K5/34 ,  C08K5/3415 ,  C08K5/36 ,  C08L27/00 ,  C08L27/04

    CPC分类号： C07D207/333 ,  C07D207/34 ,  C08K5/3415 ,  C08L27/04

    摘要： Chlorine-containing thermoplastics, containing a pyrrole of the formula I ##STR1## in which R.sub.1 is hydrogen, alkyl, cycloalkyl, aryl, alkoxycarbonylmethyl, free or esterified .alpha.-hydroxyalkyl, free or esterified .alpha.-hydroxycycloalkylmethyl, free or esterified .alpha.-hydroxyaralkyl, alkoxymethyl, alkylthiomethyl, aryloxymethyl, arylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, aralkylthiomethyl, alkoxy, alkylthio, cycloalkoxy, cycloalkylthio, aralkoxy, arylalkylthio, aryloxy, arylthic, halogen, mercapto, mercaptomethyl or hydroxyl, R.sub.2 is hydrogen, alkyl, cycloalkyl, aryl, free or esterified .alpha.-hydroxyalkyl, in which the alkyl moiety together with R.sub.1 can be alkylene, or free or esterified .alpha.-hydroxycycloalkylmethyl, free or esterified .alpha.-hydroxyaralkyl, alkoxy, cycloalkoxy, aralkoxy, aryloxy, alkylthio, cycloalkylthio, aralkylthio, arylthio, alkoxymethyl, alkylthiomethyl, aryloxymethyl, arylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, aralkylthiomethyl, hydroxyl, cyano, free carboxyl or carboxyl in the form of a salt or an ester, or acyl, it being possible for acyl together with R.sub.1 to be --CO-alkylene, in which --CO-- is bonded in the 3-position, or R.sub.2 is halogen, mercapto or mercaptomethyl, and R.sub.3 is alkyl, cycloalkyl, aralkyl, aryl, free or esterified hydroxymethyl, alkoxymethyl, alkylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, arylalkylthiomethyl, aryloxymethyl or arylthiomethyl, alkoxy, alkylthio, cycloalkoxy, cycloalkylthio, aralkoxy, aralkylthio, aryloxy, arylthio, halogen, mercapto or mercaptomethyl, or if R.sub.2 is carboxyl in the form of a salt, R.sub.3 is hydrogen and R.sub.1 is as defined, or in which R.sub.3 is hydroxyl and R.sub.1 is hydrogen, alkyl or aryl and R.sub.2 is hydrogen, alkyl, aryl or acyl, or a salt thereof.

    Novel adducts
    9.
    发明授权
    Novel adducts 失效
    新加盟

    公开(公告)号：US4245125A

    公开(公告)日：1981-01-13

    申请号：US37599

    申请日：1979-05-10

    申请人： Hermann O. Wirth ,  Hans-Helmut Friedrich

    发明人： Hermann O. Wirth ,  Hans-Helmut Friedrich

    IPC分类号： A01N59/00 ,  C07C29/00 ,  C07C31/20 ,  C07C31/22 ,  C07C43/11 ,  C07C43/13 ,  C08F2/00 ,  C08F4/00 ,  C11D3/39 ,  C07C43/10 ,  C08F120/18

    CPC分类号： A01N59/00 ,  C07C29/00 ,  C07C31/20 ,  C07C31/22 ,  C07C43/11 ,  C07C43/135 ,  C08F4/00 ,  C11D3/39 ,  C11D3/3945

    摘要： Compounds of the formula IA.multidot.m B (I)whereinA is a compound of the formula II or III ##STR1## m is a rational number between 0.1 and 4.0, and B is H.sub.2 O.sub.2, N.sub.2 H.sub.4 or NH.sub.2 OH, andR.sub.1 is an unsubstituted or substituted aliphatic or aromatic hydrocarbon radical which has 3-30 C atoms and which can be interrupted by oxygen or sulfur atoms,R.sub.2 is hydrogen or C.sub.1 -C.sub.30 alkyl,X is --O-- or --SO.sub.2 -- and, in the case where B is N.sub.2 H.sub.4 or NH.sub.2 OH, also --S-- or --SO--,Y is the direct bond, ##STR2## Q is --CH.sub.2, --CH(OH)--CH.sub.2 -- or --CH(CH.sub.2 --OH)--, and n is 1, 2, 3, 4, 5, 6, 7 or 8.

    摘要翻译： 式I Axm B（I）的化合物，其中A是式II或III的化合物，其中的有机数为0.1至4.0，B为H 2 O 2，N 2 H 4或NH 2 OH，R 1为未取代或取代的 具有3-30个碳原子并且可以被氧或硫原子间隔的脂族或芳族烃基，R2是氢或C1-C30烷基，X是-O-或-SO2-，并且在B是N2H4的情况下 或NH 2 OH，也是-S-或-SO-，Y是直接键，Q是-CH 2，-CH（OH）-CH 2 - 或-CH（CH 2 -OH） - ，n是1,2 ，3，4，5，6，7或8。

    Pyrrole stabilizers for chlorine-containing thermoplastics
    10.
    发明授权
    Pyrrole stabilizers for chlorine-containing thermoplastics 失效

    公开(公告)号：US4290940A

    公开(公告)日：1981-09-22

    申请号：US164194

    申请日：1980-06-30

    申请人： Hermann O. Wirth ,  Jurgen Bussing ,  Hans-Helmut Friedrich

    发明人： Hermann O. Wirth ,  Jurgen Bussing ,  Hans-Helmut Friedrich

    IPC分类号： C09K15/30 ,  C07D207/00 ,  C07D207/32 ,  C07D207/333 ,  C07D207/34 ,  C07D209/52 ,  C08K5/34 ,  C08K5/3415 ,  C08K5/36 ,  C08L27/00 ,  C08L27/04

    CPC分类号： C07D207/333 ,  C07D207/34 ,  C08K5/3415 ,  C08L27/04

    摘要： Chlorine-containing thermoplastics, containing a pyrrole of the formula I ##STR1## in which R.sub.1 is hydrogen, alkyl, cycloalkyl, aryl, alkoxycarbonylmethyl, free or esterified .alpha.-hydroxyalkyl, free or esterified .alpha.-hydroxycycloalkylmethyl, free or esterified .alpha.-hydroxyaralkyl, alkoxymethyl, alkylthiomethyl, aryloxymethyl, arylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, aralkylthiomethyl, alkoxy, alkylthio, cycloalkoxy, cycloalkylthio, aralkoxy, arylalkylthio, aryloxy, arylthio, halogen, mercapto, mercaptomethyl or hydroxyl, R.sub.2 is hydrogen, alkyl, cycloalkyl, aryl, free or esterified .alpha.-hydroxyalkyl, in which the alkyl moiety together with R.sub.1 can be alkylene, or free or esterified .alpha.-hydroxycycloalkylmethyl, free or esterified .alpha.-hydroxyaralkyl, alkoxy, cycloalkoxy, aralkoxy, aryloxy, alkylthio, cycloalkylthio, aralkylthio, arylthio, alkoxymethyl, alkylthiomethyl, aryloxymethyl, arylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, aralkylthiomethyl, hydroxyl, cyano, free carboxyl or carboxyl in the form of a salt or an ester, or acyl, it being possible for acyl together with R.sub.1 to be --CO-alkylene, in which --CO-- is bonded in the 3-position, or R.sub.2 is halogen, mercapto or mercaptomethyl, and R.sub.3 is alkyl, cycloalkyl, aralkyl, aryl, free or esterified hydroxymethyl, alkoxymethyl, alkylthiomethyl, cycloalkoxymethyl, cycloalkylthiomethyl, aralkoxymethyl, arylalkylthiomethyl, aryloxymethyl or arylthiomethyl, alkoxy, alkylthio, cycloalkoxy, cycloalkylthio, aralkoxy, aralkylthio, aryloxy, arylthio, halogen, mercapto or mercaptomethyl, or if R.sub.2 is carboxyl in the form of a salt, R.sub.3 is hydrogen and R.sub.1 is as defined, or in which R.sub.3 is hydroxyl and R.sub.1 is hydrogen, alkyl or aryl and R.sub.2 is hydrogen, alkyl, aryl or acyl, or a salt thereof.