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公开(公告)号：US08853352B2
公开(公告)日：2014-10-07
申请号：US11961189
申请日：2007-12-20
申请人： Yuan-Yong Yan , Steven Luo
发明人： Yuan-Yong Yan , Steven Luo
摘要： A functionalized polymer includes a directly bonded moiety, which can be located at a terminus of the polymer, defined by the formula —CR1R2NH-Q-M where M is (N═CR1R2) or N-(QN═CR1R2)2 each Q independently is a substituted or unsubstituted, cyclic or acyclic C1-C40 alkyl, aryl, or alkaryl radical, and each R1 and R2 independently is a hydrogen atom or a substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, allyl, aralkyl, alkaryl, or alkynyl group. The polymer can be provided by introducing a polyimine compound into a system that includes carbanionic (living) polymer. Such polymers can be used in the production of compositions that include particulate fillers.
摘要翻译： 官能化聚合物包括直接键合的部分，其可以位于聚合物的末端，由式-CR1R2NH-QM定义，其中M为（N = CR1R2）或N-（QN = CR1R2）2，每个Q独立地为 取代或未取代的环状或非环状C 1 -C 40烷基，芳基或烷芳基，R 1和R 2各自独立地为氢原子或取代或未取代的烷基，烯基，环烷基，环烯基，芳基，烯丙基，芳烷基，烷芳基或 炔基。 聚合物可以通过将聚亚胺化合物引入到包含聚阴离子（活性）聚合物的体系中来提供。 这种聚合物可用于生产包括颗粒填料的组合物。
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公开(公告)号：US08389644B2
公开(公告)日：2013-03-05
申请号：US11877105
申请日：2007-10-23
IPC分类号： C08F4/52 , C08F136/06 , C08F236/06
摘要： A functionalized polymer includes a directly bonded moiety, which can be located at a terminus of the polymer, defined by the formula —NH—NR1R2 where R1 and R2 independently are substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, allyl, aralkyl, alkaryl, or alkynyl groups, or together form a substituted or unsubstituted alkylene, alkenylene, cycloalkylene, cycloalkenylene, or arylene group. The functionalized polymer can be provided by reacting a living polymer with a hydrazone. Such polymers can be used in the production of compositions that include particulate fillers.
摘要翻译： 官能化聚合物包括直接键合的部分，其可以位于由式-NH-NR1R2定义的聚合物的末端，其中R 1和R 2独立地是取代或未取代的烷基，烯基，环烷基，环烯基，芳基，烯丙基，芳烷基 ，烷芳基或炔基，或一起形成取代或未取代的亚烷基，亚烯基，亚环烷基，亚环烯基或亚芳基。 官能化聚合物可以通过使活性聚合物与腙反应来提供。 这种聚合物可用于生产包括颗粒填料的组合物。
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公开(公告)号：US07932316B2
公开(公告)日：2011-04-26
申请号：US11958052
申请日：2007-12-17
申请人： Yuan-Yong Yan , Steven Luo
发明人： Yuan-Yong Yan , Steven Luo
CPC分类号： C08C19/44 , C08K3/013 , C08L15/00 , C08L2205/02 , C08L2666/08
摘要： A composition that includes functionalized polymers and one or more types of particulate filler exhibits both an increased gum Mooney viscosity and a decreased compound Mooney viscosity relative to a comparable composition that includes only one such functionalized polymer. The functionalized polymers include first and second types of functionalities which exhibit a non-covalent interaction that has a bond energy of from about 0.1 to about 20 kJ/mol.
摘要翻译： 包括官能化聚合物和一种或多种类型的颗粒填料的组合物相对于仅包括一种这样的官能化聚合物的可比较组合物显示增加的口香糖粘度和降低的化合物门尼粘度。 官能化聚合物包括具有约0.1至约20kJ / mol的键能的非共价相互作用的第一和第二类功能。
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公开(公告)号：US20080161478A1
公开(公告)日：2008-07-03
申请号：US11958052
申请日：2007-12-17
申请人： Yuan-Yong Yan , Steven Luo
发明人： Yuan-Yong Yan , Steven Luo
IPC分类号： C08K3/00
CPC分类号： C08C19/44 , C08K3/013 , C08L15/00 , C08L2205/02 , C08L2666/08
摘要： A composition that includes functionalized polymers and one or more types of particulate filler exhibits both an increased gum Mooney viscosity and a decreased compound Mooney viscosity relative to a comparable composition that includes only one such functionalized polymer. The functionalized polymers include first and second types of functionalities which exhibit a non-covalent interaction that has a bond energy of from about 0.1 to about 20 kJ/mol.
摘要翻译： 包括官能化聚合物和一种或多种类型的颗粒填料的组合物相对于仅包括一种这样的官能化聚合物的可比较组合物显示增加的口香糖粘度和降低的化合物门尼粘度。 官能化聚合物包括具有约0.1至约20kJ / mol的键能的非共价相互作用的第一和第二类功能。
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公开(公告)号：US20170002105A1
公开(公告)日：2017-01-05
申请号：US15265532
申请日：2016-09-14
申请人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
发明人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
IPC分类号： C08C19/44 , C08K3/04 , C08L9/06 , C08F236/10
CPC分类号： C08C19/44 , B60C1/0016 , C07F7/1804 , C08F12/14 , C08F36/04 , C08F212/14 , C08F236/10 , C08K3/04 , C08K3/045 , C08K3/36 , C08L7/00 , C08L9/06 , C08L15/00 , C08L19/006 , C08L2310/00 , Y02P20/55 , C08F4/48 , C08L2666/08
摘要： Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing α-methylstyrene functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.
摘要翻译： 可以从包含含羟基的α-甲基苯乙烯官能团的聚合物的化合物中获得具有所需性质的硫化剂。 可以通过使用任何或所有合适的引发剂，单体和任选的终止化合物来掺入官能团。 这些聚合物与常规和非常规填料都具有优异的相互作用。
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26.发明授权Hairy polymeric nanoparticles with first and second shell block polymer arms 有权具有第一和第二壳嵌段聚合物臂的多毛聚合物纳米颗粒公开(公告)号：US09062144B2
公开(公告)日：2015-06-23
申请号：US12754367
申请日：2010-04-05
申请人： Xiaorong Wang , Hideki Kitano , James H. Pawlow , Christopher G. Robertson , Yaohong Chen , Yuan-Yong Yan
发明人： Xiaorong Wang , Hideki Kitano , James H. Pawlow , Christopher G. Robertson , Yaohong Chen , Yuan-Yong Yan
IPC分类号： C08L21/00 , C08L7/00 , C08L53/02 , C08F297/04
CPC分类号： C08F279/02 , C08F297/046 , C08L9/06 , C08L21/00 , C08L2205/03 , C08L2207/53 , C08L7/00 , C08L9/00 , C08L53/00 , C08L53/02
摘要： Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.
摘要翻译： 包括用于制备毛发聚合物纳米颗粒的组合物和方法，包括第一和第二壳嵌段聚合物臂至少部分地相分离并且围绕聚合物芯。 一种类型的聚合物臂可以具有比其它类型的聚合物臂更大的极性。 还提供了包含毛状纳米颗粒的橡胶组合物。
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27.发明授权公开(公告)号：US09051455B2
公开(公告)日：2015-06-09
申请号：US13701056
申请日：2011-05-28
申请人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
发明人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
IPC分类号： C08F36/00 , C08L9/06 , C07F7/18 , C08C19/44 , C08F12/14 , C08F36/04 , C08F236/10 , C08K3/04 , C08L15/00 , C08L19/00 , B60C1/00 , C08F212/14 , C08K3/36 , C08L7/00
CPC分类号： C08C19/44 , B60C1/0016 , C07F7/1804 , C08F12/14 , C08F36/04 , C08F212/14 , C08F236/10 , C08K3/04 , C08K3/045 , C08K3/36 , C08L7/00 , C08L9/06 , C08L15/00 , C08L19/006 , C08L2310/00 , Y02P20/55 , C08F4/48 , C08L2666/08
摘要： Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing α-methylstyrene functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.
摘要翻译： 可以从包含含羟基的α-甲基苯乙烯官能团的聚合物的化合物中获得具有所需性质的硫化剂。 可以通过使用任何或所有合适的引发剂，单体和任选的终止化合物来掺入官能团。 这些聚合物与常规和非常规填料都具有优异的相互作用。
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28.发明授权公开(公告)号：US08765888B2
公开(公告)日：2014-07-01
申请号：US13381345
申请日：2010-06-30
申请人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
发明人： Zengquan Qin , Yuan-Yong Yan , Xiao-Dong Pan
摘要： Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing diphenylethylene-type functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.
摘要翻译： 具有所需性质的硫化剂可以从包含含羟基的二苯基乙烯型官能团的聚合物的化合物中获得。 可以通过使用任何或所有合适的引发剂，单体和任选的终止化合物来掺入官能团。 这些聚合物与常规和非常规填料都具有优异的相互作用。
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公开(公告)号：US08642706B2
公开(公告)日：2014-02-04
申请号：US13371338
申请日：2012-02-10
申请人： Yuan-Yong Yan
发明人： Yuan-Yong Yan
CPC分类号： C08L9/06 , C08C19/22 , C08C19/25 , C08C19/44 , C08F2/06 , C08F4/08 , C08F8/30 , C08F8/32 , C08F8/42 , C08F212/08 , C08F236/06 , C08F236/10 , C08K3/013 , C08K3/04 , C08K3/0033 , C08L15/00
摘要： A macromolecule includes a functional group including imine functionality bonded to a polymer chain. Where desired, the functional group also can contain additional (e.g., amine and/or silane) functionality. The material can be provided by reacting a polymer including carbonyl functionality with a compound including a primary amino group. The functional group can interact with particulate filler such as, e.g., carbon black and silica.
摘要翻译： 大分子包括键合到聚合物链上的亚胺官能团的官能团。 如果需要，官能团还可以含有另外的（例如胺和/或硅烷）官能团。 可以通过使包括羰基官能团的聚合物与包含伯氨基的化合物反应来提供该材料。 官能团可以与颗粒填料例如炭黑和二氧化硅相互作用。
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公开(公告)号：US08623955B2
公开(公告)日：2014-01-07
申请号：US13566798
申请日：2012-08-03
申请人： Yuan-Yong Yan , Jason Poulton , Xiaorong Wang , Hao Wang , Michelle A. Cottrell
发明人： Yuan-Yong Yan , Jason Poulton , Xiaorong Wang , Hao Wang , Michelle A. Cottrell
CPC分类号： C08L19/006 , C08C19/44 , C08F291/00 , C08K3/013 , C08L15/00 , C08L51/10
摘要： A macromolecule including a polymer and a polyhedral radical chemically bonded to a terminus of the polymer provides numerous processing and performance advantages. Further functionalization of this macromolecule also is described as being advantageous in certain circumstances. Methods of providing, functionalizing, and utilizing the macro-molecule also are provided.
摘要翻译： 化学键合到聚合物末端的聚合物和多面体基团的大分子提供许多加工和性能优点。 这种高分子的进一步官能化也被描述为在某些情况下是有利的。 还提供了提供，功能化和利用该大分子的方法。
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