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公开(公告)号：US20170137739A1
公开(公告)日：2017-05-18
申请号：US15352784
申请日：2016-11-16
Applicant: TRENT UNIVERSITY
Inventor： Suresh Narine , Laziz Bouzidi , Latchmi Raghunanan
IPC: C10M129/72 , C10M105/04 , C07C69/67 , C10L10/08 , C10L1/19 , C07C69/73 , C10M101/02 , C10M129/76
CPC classification number: C10M129/72 , C07C69/67 , C07C69/675 , C07C69/73 , C10L1/1905 , C10L1/191 , C10L10/08 , C10L2200/0476 , C10L2270/026 , C10M101/02 , C10M105/04 , C10M105/38 , C10M105/40 , C10M105/42 , C10M129/76 , C10M2203/003 , C10M2203/022 , C10M2203/1006 , C10M2205/0285 , C10M2207/282 , C10M2207/283 , C10M2207/2835 , C10M2207/289 , C10M2207/2895 , C10M2207/30 , C10M2207/301 , C10M2209/102 , C10M2209/1023 , C10N2230/02 , C10N2230/64 , C10N2240/02 , C10N2240/04
Abstract: The disclosure generally provides branched diester compounds having exceptional low-temperature and flow properties. The disclosure also provides uses of the branched diester compounds in lubricant compositions, for example, as a base oil, and in other applications where their low-temperature and flow properties can be employed beneficially. The disclosure also provides efficient and green methods for making the branched diester compounds.In certain embodiments, a vegetable oil-based diester (1,6-hexyldioleate) was branched with propanoic acid (C3) using a green synthetic approach involving solvent-free and catalyst-free epoxide ring opening followed by in situ normal esterification. A total of three branched ester derivatives possessing varied numbers of internal protruding branched ester groups and hydroxyl groups were obtained. All of the pure branched derivatives were comprised of mixtures of positional isomers and/or stereoisomers. Differential scanning calorimetry (DSC) showed that regardless of the composition inhomogeneity of each branched derivative, crystallization was suppressed completely in all of the branched compounds, and they all demonstrated glass transitions below −65° C.Without being bound by any theory, it is believed that this unique thermal behavior is attributed to the internal protruding branched moieties and hydroxyl groups, which dramatically slowed down mass transfer starting with the least branched compound (2-branched derivative). The viscosity of the branched compounds was one order of magnitude larger than that of the starting di ester due to the increased branching and increased resistance to flow associated with hydrogen bonding introduced by the OH groups. Overall, these branched diesters demonstrated superior low temperature and flow properties comparable to existing non-sustainable commercial lubricants and analogous biobased materials which makes them suitable alternatives for use in lubricant formulations particularly in high performance industrial gear and bearing lubricants.
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公开(公告)号：US09359571B2
公开(公告)日：2016-06-07
申请号：US14259575
申请日：2014-04-23
Applicant: Trent University
Inventor： Suresh Narine , Shaojun Li , Ali Mahdevari , Laziz Bouzidi , Stephen Augustine DiBiase , Syed Q. A. Rizvi
IPC: C10M105/42 , C10M105/36 , C10M105/40 , C10M105/34 , C07C69/00 , C07C69/66 , C07C69/34
CPC classification number: C10M105/34 , C07C69/00 , C07C69/34 , C07C69/66 , C10M105/36 , C10M105/40 , C10M105/42 , C10M2207/28 , C10M2207/2805 , C10M2207/2815 , C10M2207/2825 , C10M2207/30 , C10M2207/301 , C10N2020/02 , C10N2220/022 , C10N2230/02 , C10N2230/08 , C10N2230/10 , C10N2230/66 , C10N2230/68 , C10N2240/08 , C10N2240/10 , C10N2240/105 , C10N2240/30 , C10N2240/40 , C10N2240/401 , C10N2240/402 , C10N2250/10 , C10N2270/00 , C10N2220/025 , C10N2220/028
Abstract: This invention relates to base ester compounds and complex ester compounds that can be used as a base stock for lubricant applications or a base stock blend component for use in a finished lubricant or for particular applications, and methods of making the same. The base ester compounds and complex esters described herein comprise dimer and/or trimer esters, and their respective branched derivatives.
Abstract translation: 本发明涉及可用作润滑剂应用的基础油料的基酯化合物和复合酯化合物，或用于成品润滑剂或用于特定应用的基础油混合物组分及其制备方法。 本文所述的碱性酯化合物和络合物酯包含二聚体和/或三聚体酯，以及它们各自的支链衍生物。
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公开(公告)号：US20150321992A1
公开(公告)日：2015-11-12
申请号：US14703986
申请日：2015-05-05
Applicant: Trent University
Inventor： Suresh Narine , Shaojun Li , Laziz Bouzidi
IPC: C07C69/73
CPC classification number: C07C69/73 , C07C69/593 , C11C3/00
Abstract: This application relates to triacylglycerol oligomers derived from the metathesis of natural oils. These oligomers are structure controlled dimers and quatrimers, and the effect of saturation, molecular size, and positional isomerization are also described herein.
Abstract translation: 本申请涉及由天然油复分解衍生的三酰基甘油低聚物。 这些低聚物是结构受控的二聚体和四聚体，本文还描述了饱和度，分子大小和位置异构化的影响。
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公开(公告)号：US20140325899A1
公开(公告)日：2014-11-06
申请号：US14209505
申请日：2014-03-13
Applicant: Trent University
Inventor： Suresh Narine , Laziz Bouzidi , Bruce Darling , Mark Baker , Shaojun Li , Ali Mahdevari
IPC: C10L10/14
CPC classification number: C10L10/14 , C07C69/593 , C10L1/1915 , C10L2200/0476
Abstract: This application relates to certain dimers as crystallization depressants for biodiesel fuels, and methods for making the same. Such dimers, due to their particular structure and conformation, disrupt the regular packing of linear saturated fatty acid methyl esters, thereby delaying nucleation and mitigating crystal growth. In some embodiments, the dimer includes (E)-1-(1-(oleoyloxy)-3-(stearoyloxy)propan-2-yl) 18-(1-(oleoyloxy)-3-(stearoyloxy)propan-2-yl)octadec-9-enedioate.
Abstract translation: 本申请涉及作为生物柴油燃料的结晶抑制剂的某些二聚体及其制备方法。 这种二聚体由于其特殊的结构和构象而破坏了线性饱和脂肪酸甲酯的常规包装，从而延缓成核并减缓晶体生长。 在一些实施方案中，二聚体包括（E）-1-（1-（油酰氧基）-3-（硬脂酰氧基）丙-2-基）18-（1-（油酰氧基）-3-（硬脂酰氧基）丙-2-基 ）十八烷-9-壬二酸酯。
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公开(公告)号：US10738251B2
公开(公告)日：2020-08-11
申请号：US15343831
申请日：2016-11-04
Applicant: TRENT UNIVERSITY
Inventor： Suresh Narine , Laziz Bouzidi , Athira Mohanan
Abstract: This present disclosure relates to biodiesel compositions comprising polymeric pour point depressants, and crystallization modifiers, to improve cold flow properties for biodiesel fuels.
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Patent Agency Ranking
公开(公告)号：US09777245B2
公开(公告)日：2017-10-03
申请号：US15005895
申请日：2016-01-25
Applicant: Trent University
Inventor： Suresh Narine , Prasanth Kumar Sasidharan Pillai , Shaojun Li , Laziz Bouzidi , Ali Mahdevari
IPC: C07C51/00 , C11C3/00 , A61K8/85 , C07C67/31 , C08G18/36 , C08L75/04 , C07C67/333 , C08G18/08 , C08G18/76 , C11C1/00 , A61K8/37 , A61Q19/00 , C08G101/00
CPC classification number: C11C3/00 , A61K8/375 , A61K8/85 , A61K2800/10 , A61Q19/00 , C07C67/31 , C07C67/333 , C08G18/14 , C08G18/36 , C08G18/7671 , C08G2101/0008 , C08G2101/0025 , C08G2101/0083 , C08L75/04 , C11C1/005 , C11C3/006 , C07C69/533 , C07C69/675
Abstract: Metathesized triacylglycerol polyols, fractionated polyol variants thereof, and their related physical and thermal properties are disclosed.
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公开(公告)号：US09637698B2
公开(公告)日：2017-05-02
申请号：US14209505
申请日：2014-03-13
Applicant: Trent University
Inventor： Suresh Narine , Laziz Bouzidi , Bruce Darling , Mark Baker , Shaojun Li , Ali Mahdevari
IPC: C10L1/00 , C10L10/14 , C10L1/19 , C07C69/593
CPC classification number: C10L10/14 , C07C69/593 , C10L1/1915 , C10L2200/0476
Abstract: This application relates to certain dimers as crystallization depressants for biodiesel fuels, and methods for making the same. Such dimers, due to their particular structure and conformation, disrupt the regular packing of linear saturated fatty acid methyl esters, thereby delaying nucleation and mitigating crystal growth. In some embodiments, the dimer includes (E)-1-(1-(oleoyloxy)-3-(stearoyloxy)propan-2-yl) 18-(1-(oleoyloxy)-3-(stearoyloxy)propan-2-yl)octadec-9-enedioate.
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公开(公告)号：US09611352B2
公开(公告)日：2017-04-04
申请号：US14854840
申请日：2015-09-15
Applicant: Trent University
Inventor： Suresh Narine , Shaojun Li , Jesmy Jose , Shegufta Shetranjiwalla , Laziz Bouzidi
Abstract: The synthesis of certain polyester diols (PEDs) is disclosed. This application also discloses the purification and polymerization kinetics of lipid based PEDs. Molecular weight and distribution controls were achieved by initial and induced stoichiometric imbalance and optimization of the purification protocol. Thermal degradation and thermal transition behavior of the PEDs were also investigated by TGA and DSC.
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公开(公告)号：US20160257901A1
公开(公告)日：2016-09-08
申请号：US15157449
申请日：2016-05-18
Applicant: Trent University
Inventor： Suresh Narine , Shaojun Li , Ali Mahdevari , Laziz Bouzidi , Stephen Augustine DiBiase , Syed Q.A. Rizvi
IPC: C10M105/34 , C10M105/36
CPC classification number: C10M105/34 , C07C69/00 , C07C69/34 , C07C69/66 , C10M105/36 , C10M105/40 , C10M105/42 , C10M2207/28 , C10M2207/2805 , C10M2207/2815 , C10M2207/2825 , C10M2207/30 , C10M2207/301 , C10N2020/02 , C10N2220/022 , C10N2230/02 , C10N2230/08 , C10N2230/10 , C10N2230/66 , C10N2230/68 , C10N2240/08 , C10N2240/10 , C10N2240/105 , C10N2240/30 , C10N2240/40 , C10N2240/401 , C10N2240/402 , C10N2250/10 , C10N2270/00 , C10N2220/025 , C10N2220/028
Abstract: This invention relates to base ester compounds and complex ester compounds that can be used as a base stock for lubricant applications or a base stock blend component for use in a finished lubricant or for particular applications, and methods of making the same. The base ester compounds and complex esters described herein comprise dimer and/or trimer esters, and their respective branched derivatives.
Abstract translation: 本发明涉及可用作润滑剂应用的基础油料的基酯化合物和复合酯化合物，或用于成品润滑剂或用于特定应用的基础油混合物组分及其制备方法。 本文所述的碱性酯化合物和络合物酯包含二聚体和/或三聚体酯，以及它们各自的支链衍生物。
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30.发明申请BIO-BASED DIISOCYANATE AND CHAIN EXTENDERS IN CRYSTALLINE SEGMENTED THERMOPLASTIC POLYESTER URETHANES 审中-公开生物基二异氰酸酯和链状延伸剂在结晶分层热塑性聚酯酯公开(公告)号：US20160102168A1
公开(公告)日：2016-04-14
申请号：US14854810
申请日：2015-09-15
Applicant: Trent University
Inventor： Suresh Narine , Shaojun Li , Jesmy Jose , Laziz Bouzidi
CPC classification number: C08G18/73 , C08G18/10 , C08G18/3206 , C08G18/4238 , C08G18/664
Abstract: The synthesis of semi-crystalline thermoplastic polyester urethanes is disclosed. The synthesis describes parameters such as controlled concentration, distribution, and types of crystalline hard segment blocks to correlate the effect of hard segment crystallinity to that of the soft segment blocks.
Abstract translation: 公开了半结晶热塑性聚酯聚氨酯的合成。 该合成描述了诸如受控浓度，分布和结晶硬链段的类型之类的参数，以将硬链段结晶度与软链段嵌段的影响相关联。
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