Asymmetrical siloxy compounds
    21.
    发明授权
    Asymmetrical siloxy compounds 失效
    不对称甲硅烷基化合物

    公开(公告)号:US06184306B2

    公开(公告)日:2001-02-06

    申请号:US09532717

    申请日:2000-03-22

    IPC分类号: C08C1922

    CPC分类号: C07F7/1804

    摘要: The present invention relates to asymmetrical siloxy compounds of the formula wherein R1, R2 and R3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; and n is an integer of from 1 to 8.

    摘要翻译: 本发明涉及式R 1,R 2和R 3的不对称甲硅烷氧基化合物独立地选自具有1至8个碳原子的烷氧基; R4选自具有1至15个碳原子的亚烷基和具有6至10个碳原子的亚芳基和烷基取代的亚芳基; n为1〜8的整数。

    Process for preparing composite, composition and article thereof
    23.
    发明授权
    Process for preparing composite, composition and article thereof 失效
    制备复合材料,组合物及其制品的方法

    公开(公告)号:US06753375B2

    公开(公告)日:2004-06-22

    申请号:US09897316

    申请日:2001-07-02

    IPC分类号: C08J300

    摘要: This invention relates to preparation of a rubber composition by pre-mixing at least one functionalized carbon black with an organic solvent solution or aqueous emulsion of at least one host elastomer. Functionalized carbon blacks for the purposes of this invention preferably contain a functional moiety on their surface to aid in promoting covalent bonds between the functionalized carbon black and said host polymer. The invention also contemplates the use of such rubber composition, or blend of such rubber composition with at least one additional elastomer and/or rubber compounding ingredient, as a component of an article of manufacture. Such article of manufacture may be, for example, a tire. Such article may also be an industrial product such as, for example, a hose or belt such as a conveyor belt or power transmission belt.

    摘要翻译: 本发明涉及通过将至少一种官能化炭黑与至少一种主体弹性体的有机溶剂溶液或水性乳液预混合来制备橡胶组合物。 用于本发明目的的官能化炭黑优选在其表面上含有官能部分以有助于促进官能化炭黑和所述主体聚合物之间的共价键。 本发明还考虑使用这种橡胶组合物或这种橡胶组合物与至少一种另外的弹性体和/或橡胶配混成分的共混物作为制品的组分。 这种制造品可以是例如轮胎。 这种制品也可以是工业产品,例如软管或皮带,例如输送带或动力传动带。

    Electropolymerization modified carbon black and articles including tires having at least one component containing such modified carbon black
    24.
    发明授权
    Electropolymerization modified carbon black and articles including tires having at least one component containing such modified carbon black 失效
    电聚合改性炭黑和包含具有至少一种含有这种改性炭黑的组分的轮胎的制品

    公开(公告)号:US06894103B2

    公开(公告)日:2005-05-17

    申请号:US10301905

    申请日:2002-11-22

    摘要: This invention relates to a carbon black modified by a two step process in which carbon black is initially treated with functional monomers by an electropolymerization process to form a functionalized carbon black having an initial polymer attached to, of grafted to, the carbon black following which(A) at least one diene monomer, or(B) living anionic catalysis prepared polymer, is introduced to the functionalized carbon black to continue the polymerization, starting from a living end of the initially formed polymer, and thereby form an extended diene-based polymer. By the addition of the diene monomer or the live anionic polymer to form the associated extended diene-based polymer, it is contemplated that the modified carbon black is rendered more compatible with diene-based elastomers. Such modified carbon black may be used, for example, as reinforcement for component(s) of various articles of manufacture, including tires. Accordingly, an article of manufacture is provided, such as for example a tire, having at least one component of a rubber composition which contains such modified carbon black.

    摘要翻译: 本发明涉及通过两步法改性的炭黑,其中炭黑最初通过电聚合方法用功能性单体处理,以形成具有连接到炭黑上的初始聚合物的官能化炭黑,随后将 A)将至少一种二烯单体或(B)活性阴离子催化制备的聚合物引入到官能化炭黑中以继续聚合,从最初形成的聚合物的活性端开始,从而形成延伸的二烯基聚合物 。 通过加入二烯单体或活性阴离子聚合物以形成相关的延长的二烯基聚合物,预期改性炭黑与二烯基弹性体更相容。 这种改性炭黑可以用作例如包括轮胎在内的各种制品的组分的增强剂。 因此,提供了具有至少一种含有这种改性炭黑的橡胶组合物组分的例如轮胎的制品。

    Rubber composite containing in situ formed filler reinforcement, article and tire comprising thereof
    26.
    发明授权
    Rubber composite containing in situ formed filler reinforcement, article and tire comprising thereof 失效
    包含原位形成的填料增强剂的橡胶复合材料,其制品和轮胎

    公开(公告)号:US06797762B2

    公开(公告)日:2004-09-28

    申请号:US10050001

    申请日:2002-01-15

    IPC分类号: C08K334

    摘要: This invention relates to a rubber composite made from an elastomer polymerized on the surface of a silanized filler, a rubber composition containing such composite and an article such as for example a tire, which has at least one component comprised of such composition. Such reinforcement is applied by polymerizating a conjugated diene hydrocarbon in the presence of a filler silanized with an alkenyl silane. In particular a silanized reinforcing filler is pre-treated with butyl lithium or peroxide catalyst, preferably with butyl lithium, followed by polymerizing a conjugated diene hydrocarbon in the presence of such treated filler via an anionic or free radical polymerization in an organic solvent. Such pre-formed elastomer composite is also contemplated as well as a rubber composition comprised of a blend of such pre-formed composite and at least one additional elastomer. Such filler may be, for example, precipitated silica, carbon black and/or a modified carbon black. A tire having a component of such composite or rubber composition such as, for example a tread, is also provided.

    摘要翻译: 本发明涉及一种由在硅烷化填料的表面上聚合的弹性体,含有这种复合材料的橡胶组合物制成的橡胶复合材料和具有至少一种由这种组合物构成的组分的制品,例如轮胎。 在通过烯基硅烷硅烷化的填料的存在下,共轭二烯烃聚合来施加这种增强。 特别地,硅烷化增强填料用丁基锂或过氧化物催化剂,优选用丁基锂预处理,然后在有机溶剂中通过阴离子或自由基聚合在这种处理过的填料存在下聚合共轭二烯烃。 还预期了这种预成型的弹性体复合材料以及由这种预成型复合材料和至少一种另外的弹性体的共混物组成的橡胶组合物。 这种填料可以是例如沉淀二氧化硅,炭黑和/或改性炭黑。 还提供了具有这种复合材料或橡胶组合物成分例如胎面的轮胎。

    Rubber composition and tire having tread thereof
    27.
    发明授权
    Rubber composition and tire having tread thereof 失效
    橡胶组合物和具有胎面的轮胎

    公开(公告)号:US06667353B2

    公开(公告)日:2003-12-23

    申请号:US09735220

    申请日:2000-12-12

    IPC分类号: C08K906

    摘要: A rubber composition comprised of an elastomer(s) reinforced with a particulate carbon black composite, and a coupling agent. Said carbon black composite contains integral silica on the surface thereof, wherein said carbon black composite is prepared by co-precipitating carbon black and silica from a dispersion of carbon black in sodium silicate to provide integral silica domains on the outer surface of the carbon black. Said carbon black composite is further functionalized by reacting it with a trialkoxy silane. A tire having a component comprised of such rubber composition, such as, for example, a tire tread is contemplated.

    摘要翻译: 由用颗粒炭黑复合材料增强的弹性体和偶联剂组成的橡胶组合物。 所述炭黑复合物在其表面上含有整体二氧化硅,其中所述炭黑复合材料通过将炭黑和二氧化硅从硅酸钠中的炭黑分散体共沉淀制备,以在炭黑的外表面上提供整体的二氧化硅结构域。 所述炭黑复合物通过与三烷氧基硅烷反应进一步官能化。 考虑了具有由这种橡胶组合物构成的部件的轮胎,例如轮胎胎面。