摘要:
The present invention relates to a multi-stage membrane filtration process for reconcentrating the overspray from a one-component, aqueous coating composition containing high molecular weight components having a weight average molecular weight of at least 2000 and at least 5% by weight, based on the total weight of the organic components of the coating composition, of a low molecular weight component having a weight average molecular weight of less than 2000, that has been diluted with spray booth water from spray booths having wet flushing to form a booth/water overspray mixture bya) preconcentrating the booth water/overspray mixture in an ultrafiltration unit to obtain a first retentate containing high molecular weight components and a first permeant containing water and at least a portion of the low molecular weight components,b) treating said first permeant and the third permeant obtained in step c) below in a reverse osmosis unit to obtain a second permeant containing essentially pure water for recycle as booth water and a retentate containing low molecular weight components,c) treating said first and second retentates in a nanofiltration unit to obtain a third permeant containing water and a minor portion of low molecular weight components and a third retentate which largely corresponds in composition and concentration to said one-component, aqueous coating composition.
摘要:
The invention relates to a dispersing device wherein the dispersed material has a variable throughput comprising a jet disperser which comprises at least one inlet for the materials to be dispersed, a chamber with a multiciplicity of openings arranged in rows along the chamber wall, which lead into an outlet chamber, and an outlet for the finally dispersed material, wherein the chamber comprises a displaceably mounted piston which, depending on its position within the chamber, partially or completely shuts off a specific number of the openings for the passage of the flow os dispersed material.
摘要:
The present invention relates to heat and storage stable vinyl polymer polyol secondary dispersions containing A) at least one vinyl polymer resin having functional groups selected from hydroxyl, carboxyl and/or sulfonic acid groups and dispersed in a water/solvent mixture in the presence of a neutralizing agent, and B) at least one amphiphilic polymer built up from a hydrophobic and a hydrophilic segment. The invention also relates to a process for the preparation of the vinyl polymer polyol secondary dispersions by preparing vinyl polymer resin A) by polymerizing a mixture of ethylenically unsaturated monomers a) in the presence of an initiator b) in a water/solvent mixture and adding at least one amphiphilic polymer B), then at least partly neutralizing and dispersing the resulting product, optionally after the addition of a further amount of water.
摘要:
This invention relates to a new one-component stoving composition, which can be baked at low temperatures without the release of volatile compounds and which also has satisfactory stability when stored at room temperature. The invention also relates to the use of the one-component stoving composition.
摘要:
The present invention relates to a process for preparing hydroxy-functional polyurethane carbonates by reacting a) a dihydroxy- or higher hydroxy-functional polymer having a number average molecular weight of 500 to 100,000 and containing aliphatic carbonate groups and optionally ester groups with b) compounds containing at least one primary or secondary amino group and at least one hydroxy group to form urethane groups, wherein components a) and b) are present in amounts which correspond to a molar ratio of carbonate and ester groups of component a) to primary and secondary amino groups of component b) of greater than 1:1 to 20:1. The present invention also relates to the hydroxy-functional polyurethane carbonates obtained by this process and to their use as a binder component in polyurethane compositions, especially coating compositions.
摘要:
The present invention relates to a hydroxy-functional copolymer P, which is present as a dispersion and/or solution in water, and is obtained by successively carrying out process steps A-D: A) initially introducing a hydrophobic polymer containing hydroxyl groups into a reaction vessel, B) introducing an initiator component into that vessel, C) subsequently polymerizing a hydrophobic monomer mixture containing hydroxyl groups in that vessel and D) subsequently polymerizing a hydrophilic monomer mixture containing hydroxyl and acid groups in that vessel. The present invention also relates to a process for the preparation of copolymers P following the procedure previously set forth and to coating compositions containing these copolymers P and one or more crosslinking agents.
摘要:
The present invention relates to a process for the preparation of aliphatic oligocarbonate diols bya) transesterifying dimethyl carbonate with aliphatic diols in the presence of soluble transesterification catalysts in a gas-liquid countercurrent apparatus to form oligocarbonates until the degree of conversion of the initial dimethyl carbonate is more than 80% andb) removing methanol and traces of dimethyl carbonate in an apparatus which generates gas bubbles in the oligocarbonates until the degree of capping of the terminal OH groups with methoxycarbonyl groups is less than 5%.