公开(公告)号：US07157501B2

公开(公告)日：2007-01-02

申请号：US10533870

申请日：2003-10-30

Applicant: Edgar Evert Steenwinkel ,  Marieke Paulyne Renate Spee ,  Johannes Petrus Jozef Verlaan ,  Eelco Titus Carel Vogt

Inventor： Edgar Evert Steenwinkel ,  Marieke Paulyne Renate Spee ,  Johannes Petrus Jozef Verlaan ,  Eelco Titus Carel Vogt

IPC: C07C27/00 ,  C10G65/00 ,  C10G15/00

CPC classification number: B01J35/0006 ,  B01J23/75 ,  B01J29/084 ,  C10G2/33 ,  C10G2/332

Abstract: Fischer-Tropsch process for the conversion of carbon monoxide and hydrogen to C5+ hydrocarbon mixtures in which process use is made of Fischer-Tropsch catalyst particles and fluid catalytic cracking (FCC) catalyst particles. The FCC catalyst can be a fresh FCC catalyst, or an equilibrium catalysts (E-cat).

Abstract translation: 用于将一氧化碳和氢气转化为C 5 C 5 O 5烃混合物的费 - 托方法，其中工艺使用费 - 托催化剂颗粒和流化催化裂化（FCC ）催化剂颗粒。 FCC催化剂可以是新鲜的FCC催化剂或平衡催化剂（E-cat）。

公开(公告)号：US06964934B2

公开(公告)日：2005-11-15

申请号：US10647854

申请日：2003-08-25

Applicant: Mike Brady ,  Erik Jeroen Laheij ,  Paul O'Connor ,  Dennis Stamires

Inventor： Mike Brady ,  Erik Jeroen Laheij ,  Paul O'Connor ,  Dennis Stamires

IPC: B01J29/40 ,  C01B39/36 ,  C01B39/38 ,  C01B39/40 ,  B01J29/06

CPC classification number: B01J29/405 ,  B01J2229/62 ,  C01B39/36 ,  C01B39/38 ,  C01B39/40

Abstract: The present invention relates to a process for the preparation of doped pentasil-type zeolite, which process comprises the steps of: a) preparing an aqueous precursor mixture from a silicon source, an aluminium source, and doped non-zeolitic seeds; and b) thermally treating the precursor mixture to form a doped pentasil-type zeolite. The term “non-zeolitic seeds” includes seeds made from materials selected from the group consisting of (i) X-ray amorphous materials, (ii) milled crystalline materials, such as milled zeolites, that have a relative crystallinity of not more than 75%, and (iii) crystalline materials other than zeolites, such as clays (e,g, bentonite and kaolin) and (low) crystalline aluminas.

Abstract translation: 本发明涉及一种制备掺杂的pentasil型沸石的方法，该方法包括以下步骤：a）从硅源，铝源和掺杂的非沸石种子制备水性前体混合物; 和b）热处理前体混合物以形成掺杂的pentasil型沸石。 术语“非沸石种子”包括由选自以下的材料制成的种子：（i）X射线无定形材料，（ii）研磨的结晶材料，例如研磨的沸石，其相对结晶度不大于75 ％，和（iii）沸石以外的结晶材料，例如粘土（e，g，膨润土和高岭土）和（低）结晶氧化铝。

公开(公告)号：US20110263412A1

公开(公告)日：2011-10-27

申请号：US13172149

申请日：2011-06-29

Applicant: SCOTT MICHAEL BABITZ

Inventor： SCOTT MICHAEL BABITZ

IPC: B01J29/06 ,  B01J37/00

CPC classification number: C10G2/33 ,  B01D53/94 ,  B01J29/06 ,  B01J29/084 ,  B01J35/002 ,  B01J37/0045 ,  B01J2229/42 ,  C01B3/02 ,  C01B2203/1041 ,  C10G1/086 ,  C10G11/05 ,  C10G29/205 ,  C10G35/06 ,  C10G49/02

Abstract: Process for the preparation of a catalyst comprising the steps of (a) preparing a slurry comprising clay, zeolite, and quasi-crystalline boehmite, provided that the slurry does not comprise peptized quasi-crystalline boehmite, (b) adding a monovalent acid to the slurry, (c) adding a silicon source to the slurry, and (d) shaping the slurry to form particles. This process leads to a catalyst with high accessibility and high attrition resistance.

Abstract translation: 制备催化剂的方法包括以下步骤：（a）制备包含粘土，沸石和准结晶勃姆石的浆料，条件是浆料不包含胶溶的准晶勃姆石，（b）向 浆料，（c）向浆料中加入硅源，和（d）使浆料成形以形成颗粒。 该方法导致具有高可接近性和高抗磨性的催化剂。

公开(公告)号：US07993623B2

公开(公告)日：2011-08-09

申请号：US11771826

申请日：2007-06-29

Applicant: Julie Ann Francis ,  Charles Vadovic

Inventor： Julie Ann Francis ,  Charles Vadovic

IPC: B01J20/04

CPC classification number: B01J20/0251 ,  B01J20/0207 ,  B01J20/0222 ,  B01J20/0229 ,  B01J20/0244 ,  B01J20/04 ,  B01J20/041 ,  B01J20/08 ,  B01J20/3021 ,  B01J20/3078 ,  B01J20/3204 ,  B01J20/3236 ,  C10G11/02 ,  C10G11/04 ,  C10G11/18 ,  C10G25/003 ,  C10G2300/205

Abstract: Compositions and methods suitable for removing poisonous metals from hydrocarbons are provided. The compositions comprise hydrotalcite having one or more trapping metals dispersed on the outer surface thereof.

Abstract translation: 提供了适用于从烃中除去有毒金属的组合物和方法。 组合物包含在其外表面上分散有一种或多种捕获金属的水滑石。

公开(公告)号：US07922894B2

公开(公告)日：2011-04-12

申请号：US10730433

申请日：2003-12-08

Applicant: Frans Lodewijk Plantenga ,  Katsuhisa Fujita ,  Satoshi Abe

Inventor： Frans Lodewijk Plantenga ,  Katsuhisa Fujita ,  Satoshi Abe

IPC: C10G45/04 ,  C10G47/02

CPC classification number: B01J35/10 ,  B01J21/04 ,  B01J21/12 ,  B01J23/85 ,  B01J23/883 ,  B01J35/0006 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C10G45/08 ,  C10G49/04

Abstract: The present invention pertains to a process for hydroprocessing a heavy hydrocarbon oil, comprising contacting a heavy hydrocarbon oil in the presence of hydrogen with a mixture of hydroprocessing catalyst I and hydroprocessing catalyst II. The process of the invention combines high contaminant removal with high conversion, low sediment formation, and high process flexibility.

Abstract translation: 本发明涉及一种用于加氢处理重质烃油的方法，包括在氢气存在下使重质烃油与加氢处理催化剂I和加氢处理催化剂II的混合物接触。 本发明的方法结合了高污染物去除，高转化率，低沉积物形成和高过程灵活性。

公开(公告)号：US20100248945A1

公开(公告)日：2010-09-30

申请号：US12743153

申请日：2008-12-04

Applicant: Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Paul Joseph Maria Lebens ,  Frans Lodewijk Plantenga ,  Bob Gerardus Oogjen ,  Henk Jan Tromp ,  Stuart Leon Soled ,  Sabato Miseo

Inventor： Sona Eijsbouts-Spickova ,  Robertus Gerardus Leliveld ,  Paul Joseph Maria Lebens ,  Frans Lodewijk Plantenga ,  Bob Gerardus Oogjen ,  Henk Jan Tromp ,  Stuart Leon Soled ,  Sabato Miseo

IPC: B01J23/883 ,  B01J23/24 ,  B01J21/16 ,  B01J23/20 ,  B01J27/236 ,  B01J27/049 ,  B01J23/755 ,  B01J27/051

CPC classification number: B01J23/8885 ,  B01J21/16 ,  B01J23/85 ,  B01J23/888 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/03 ,  B01J37/20 ,  C10G49/04

Abstract: The invention relates to a process for preparing bulk metal oxide particles comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 μm upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles. It also relates to bulk metal hydroprocessing catalysts obtainable by such method.

Abstract translation: 本发明涉及一种制备本体金属氧化物颗粒的方法，包括以下步骤：在反应混合物中混合（i）分散在液体中的尺寸小于约1μm的可分散纳米颗粒，（ii）至少一种VIII族 非贵金属化合物，（iii）至少一种VIB族金属化合物，和（iv）质子液体; 并在所述纳米颗粒存在下使所述至少一种第VIII族非贵金属化合物和所述至少一种第ⅥB族金属反应。 它还涉及通过这种方法获得的散装金属加氢处理催化剂。

公开(公告)号：US20080308454A1

公开(公告)日：2008-12-18

申请号：US12135377

申请日：2008-06-09

Applicant: Elbert Arjan De Graaf ,  King Yen Yung ,  Raymond Paul Fletcher ,  Erja Paivi Helena Rautiainen

Inventor： Elbert Arjan De Graaf ,  King Yen Yung ,  Raymond Paul Fletcher ,  Erja Paivi Helena Rautiainen

IPC: C10G11/05 ,  B01J29/06

CPC classification number: C10G11/05 ,  B01J23/007 ,  B01J29/40 ,  B01J35/0006 ,  B01J37/0045 ,  B01J2229/42 ,  C10G11/18

Abstract: Novel catalytic compositions for cracking of crude oil fractions are disclosed. The catalytic compositions comprise a basic material and at least one intermediate and/or small pore zeolite, and comprises little to no large pore zeolite.

Abstract translation: 公开了用于裂解原油馏分的新型催化组合物。 催化组合物包含碱性材料和至少一种中间和/或小孔沸石，并且包含很少至没有大孔沸石。

公开(公告)号：US07445936B2

公开(公告)日：2008-11-04

申请号：US11057507

申请日：2005-02-14

Applicant: Paul O'Connor ,  Edwin Mark Berends ,  Martinus Johannes Maria Baas ,  Eelko Brevoord

Inventor： Paul O'Connor ,  Edwin Mark Berends ,  Martinus Johannes Maria Baas ,  Eelko Brevoord

IPC: G01N31/10 ,  B01J8/18

CPC classification number: G01N31/10 ,  C10G11/18

Abstract: The present invention pertains to A cyclic process for testing FCC catalysts with resid feedstock on a small scale wherein in a first cycle: a) the feed to be cracked is heated to a temperature between 50 and 500° C., b) the heated feed is injected into a riser reactor containing the FCC catalyst to be tested having a temperature between 500 and 800° C., the injection time being less than 2 seconds, c) an inert gas is injected into the lower end of said reactor riser together in the vicinity of the feed injection in a volume ratio of inert gas to vaporized feed of about 0.03 and 10, the mixing of feed and inert gas occurring in said riser reactor; d) the feed is contacted with the FCC catalyst under fluidized conditions for a contact time of less than 8 seconds; e) the feed is stripped from the FCC catalyst and the properties of the product are analyzed; and in a second cycle a quench liquid is injected into said riser reactor in an amount of up to about 20 wt. % of said feed so as to reduce the temperature in said riser reactor and minimize undesirable secondary reactions. The invention also comprises the apparatus employed to carry out the process. With the process of the invention the mass transfer and diffusion limitations of commercial FCC units are properly simulated.

Abstract translation: 本发明涉及一种用于以小规模检测具有残留原料的FCC催化剂的循环方法，其中在第一循环中：a）待裂化的进料被加热至50-500℃的温度，b）加热的进料 被注入到含有待测试的FCC催化剂的提升管反应器中，温度在500-800℃之间，注入时间小于2秒，c）将惰性气体一起注入所述反应器提升管的下端 惰性气体与蒸发进料的体积比约为0.03和10的进料注入附近，在所述提升管反应器中发生的进料和惰性气体的混合; d）在流化条件下使进料与FCC催化剂接触，接触时间小于8秒; e）从FCC催化剂中剥离进料，分析产物的性质; 并且在第二循环中，骤冷液体以高达约20重量％的量注入所述提升管反应器。 ％的所述进料，以便降低所述提升管反应器中的温度并使不期望的次级反应最小化。 本发明还包括用于执行该过程的装置。 通过本发明的方法，适当地模拟商业FCC装置的传质和扩散限制。

公开(公告)号：US20080267860A1

公开(公告)日：2008-10-30

申请号：US12023917

申请日：2008-01-31

Applicant: Avelino Corma Canos ,  Fernando Rey Garcia ,  Maria Jose Diaz-Cabanas ,  Jose Luis Jorda Moret ,  Angel Cantin Sanz ,  Manuel Moliner Marin

Inventor： Avelino Corma Canos ,  Fernando Rey Garcia ,  Maria Jose Diaz-Cabanas ,  Jose Luis Jorda Moret ,  Angel Cantin Sanz ,  Manuel Moliner Marin

IPC: C01B39/02 ,  C01B39/00

CPC classification number: C01B37/02 ,  C01B37/005 ,  C01B39/06

Abstract: A crystalline microporous material of zeolitic nature (ITQ-41) having in its calcined form a chemical composition represented by the empirical formula: x(M1/nXO2):yYO2:SiO2 wherein, Y is a chemical element other than Silicon with oxidation status +4; X is a chemical element with oxidation status +3; M is H+ or an inorganic cation with charge n+; n can take any value between 1 to 3; x can take any value comprised between from about 0 to about 0.2; preferably lower than 0.0666, and more preferably lower than 0.05; y can take any value comprised between 0 and 0.2, and wherein, said material is characterized by the presence of four reflections in its powder X-Ray diffraction pattern at 6.9°; 7.4°; 8.3°, and 9.6°2θ angles.

Abstract translation: 沸石性质的结晶微孔材料（ITQ-41），其煅烧形式为经验式表示的化学组成：<？in-line-formula description =“In-line formula”end =“lead”？> x（ M 1 / n XO 2 2）：y Y 2 2：SiO 2 <β在线公式描述= “In-line Formulas”end =“tail”？>其中，Y是氧化状态+4以外的硅以外的化学元素; X是氧化态为+3的化学元素; M是H + H +或具有电荷n +的无机阳离子。 n可以取1到3之间的任何值; x可以取约0至约0.2之间的任何值; 优选低于0.0666，更优选低于0.05; y可以取0至0.2之间的任何值，并且其中所述材料的特征在于在其粉末X射线衍射图中在6.9°存在四次反射; 7.4°; 8.3°和9.6°2θ角。

公开(公告)号：US07442664B2

公开(公告)日：2008-10-28

申请号：US11939413

申请日：2007-11-13

Applicant: Monique Van Der Zon ,  Jan Hendrik Hilgers

Inventor： Monique Van Der Zon ,  Jan Hendrik Hilgers

IPC: B01J29/06

CPC classification number: B01J29/06 ,  B01J29/084 ,  B01J37/0045 ,  B01J2229/42 ,  C10G11/05

Abstract: This invention relates to a process for the preparation of a fluid catalytic cracking catalyst with improved attrition resistance. According to this preparation process, an aqueous slurry comprising a zeolite, day, and poly aluminum chloride is spray-dried and subsequently calcined, the poly aluminum chloride having the formula [Al2(OH)yCl6-y]x, wherein x is at least 1 and y is greater than 2 and smaller than 4.

Abstract translation: 本发明涉及一种制备具有改善的耐磨性的流化催化裂化催化剂的方法。 根据该制备方法，将包含沸石，天和聚氯化铝的含水浆料喷雾干燥并随后煅烧，具有式[Al 2（OH） 其中x至少为1且y大于2且小于4。