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    Polymerization liquid, conductive polymer film obtained from polymerization liquid, and solid electrolytic capacitor
    21.
    发明授权
    Polymerization liquid, conductive polymer film obtained from polymerization liquid, and solid electrolytic capacitor 有权
    聚合液，由聚合液得到的导电聚合物膜和固体电解电容器

    公开(公告)号：US09536675B2

    公开(公告)日：2017-01-03

    申请号：US14426106

    申请日：2013-08-28

    申请人： NIPPON CHEMI-CON CORPORATION

    发明人： Kenji Machida ,  Kenji Tamamitsu ,  Ryo Muroi

    IPC分类号： H01G9/145 ,  H01G9/035 ,  H01G9/055 ,  H01M6/04 ,  C08F2/10 ,  C08F2/06 ,  H01G9/028 ,  H01G9/15

    CPC分类号： H01G9/145 ,  C08F2/06 ,  C08F2/10 ,  C08L2666/30 ,  C08L2666/34 ,  H01G9/028 ,  H01G9/035 ,  H01G9/055 ,  H01G9/15 ,  H01M6/04 ,  Y10T29/417

    摘要： Provided is a polymerization liquid for electropolymerization, which uses a solvent that is mainly composed of water, which is greatly increased in the amount of a monomer contained therein, and which is capable of quickly forming a conductive polymer layer having high conductivity and heat resistance, A polymerization liquid for electropolymerization of the present invention contains: a solvent that is composed of 100-80% by mass of water and 0-20% by mass of an organic solvent; at least one monomer having a pi-conjugated double bond; at least one supporting electrolyte; and at least two nonionic surfactants. The at least two nonionic surfactants are composed of at least one acetylenol surfactant and at least one water-soluble nonionic surfactant other than the acetylenol surfactant. Due to the combination of the two nonionic surfactants, the amount of the monomer emulsified with the solvent can be greatly increased.

    摘要翻译： 提供一种电聚合用聚合液，其使用主要由水组成的溶剂，其中所含的单体的量大大增加，并且能够快速形成具有高导电性和耐热性的导电聚合物层， 本发明的电聚合用聚合液含有：由100〜80质量％的水和0〜20质量％的有机溶剂构成的溶剂， 至少一种具有π-共轭双键的单体; 至少一种支持电解质; 和至少两种非离子表面活性剂。 所述至少两种非离子表面活性剂由至少一种炔属醇表面活性剂和至少一种除乙炔醇表面活性剂之外的水溶性非离子表面活性剂组成。 由于两种非离子表面活性剂的组合，可以大大提高用溶剂乳化的单体的量。

    ELECTROCHEMICAL CAPACITOR
    23.
    发明申请
    ELECTROCHEMICAL CAPACITOR 有权
    电化学电容器

    公开(公告)号：US20160196930A1

    公开(公告)日：2016-07-07

    申请号：US14912810

    申请日：2014-08-11

    申请人： NIPPON CHEMI-CON CORPORATION

    发明人： Satoru TSUMEDA ,  Kazuma OKURA ,  Kazunori TAKAKI ,  Shuichi ISHIMOTO

    IPC分类号： H01G11/32 ,  H01G11/52 ,  H01G11/06 ,  H01G11/50

    CPC分类号： H01G11/32 ,  H01G11/06 ,  H01G11/34 ,  H01G11/46 ,  H01G11/50 ,  H01G11/52 ,  Y02E60/13

    摘要： Provided is an electrochemical capacitor which has low DC internal resistance, and which minimizes increase in the DC internal resistance due to a high temperature experience. The electrochemical capacitor is provided with a positive electrode having a positive electrode active material layer containing activated carbon, a negative electrode having a negative electrode active material layer containing a spinel-type lithium titanate, and a separator holding a non-aqueous electrolytic solution containing a lithium salt between the positive electrode active material layer and the negative electrode active material layer, a 100% discharge capacity of lithium titanate being set to within a range of 2.2 to 7.0 times a 100% discharge capacity of activated carbon. During charging and discharging of the electrochemical capacitor, only the area near the surfaces of lithium titanate particles are utilized, lowering the DCIR and improving the stability of the DCIR.

    摘要翻译： 提供了具有低DC内阻的电化学电容器，并且由于高温体验使DC内部电阻的增加最小化。 电化学电容器设置有具有含有活性炭的正极活性物质层的正极，具有含有尖晶石型钛酸锂的负极活性物质层的负极和含有含有钛酸锂的非水电解液的隔膜 在正极活性物质层和负极活性物质层之间的锂盐，100％的钛酸锂的放电容量设定在活性炭的100％放电容量的2.2〜7.0倍的范围内。 在电化学电容器的充放电期间，仅利用钛酸锂颗粒表面附近的区域，降低DCIR并提高DCIR的稳定性。

    ELECTRODE, ELECTRIC DOUBLE-LAYER CAPACITOR USING THE SAME, AND MANUFACTURING METHOD OF THE ELECTRODE
    25.
    发明申请
    ELECTRODE, ELECTRIC DOUBLE-LAYER CAPACITOR USING THE SAME, AND MANUFACTURING METHOD OF THE ELECTRODE 有权
    电极，使用该电极的双层电容器及电极的制造方法

    公开(公告)号：US20150357127A1

    公开(公告)日：2015-12-10

    申请号：US14827420

    申请日：2015-08-17

    申请人： NIPPON CHEMI-CON CORPORATION

    发明人： Daisuke HORII ,  Shuichi ISHIMOTO ,  Satoru TSUMEDA

    IPC分类号： H01G11/60 ,  H01G11/34 ,  H01G11/28 ,  H01G11/86 ,  H01G11/42 ,  H01G11/40

    CPC分类号： H01G11/60 ,  H01G11/24 ,  H01G11/28 ,  H01G11/34 ,  H01G11/36 ,  H01G11/38 ,  H01G11/40 ,  H01G11/42 ,  H01G11/86 ,  Y02E60/13

    摘要： Provided are an electrode formed by mixing carbon powder and a fibrous carbon, wherein influence of a resin-based binder or the like and an conductivity promoting material or the like is eliminated to have low electric resistance and an excellent property of capacitance; an electric double-layer capacitor using the electrodes; and a manufacturing method of the electrode. Provided is a dispersion step in which the carbon powder with a particle size of less than 100 nm and the fibrous carbon are dispersed into a solvent. The dispersion step is to allow jets of the solution to collide with each other or to apply shear stress and centrifugal force to the solution, thereby dispersing the carbon powder and the fibrous carbon. Furthermore, the method comprises the sheet electrode forming step in which the solution subjected to the dispersion step is filtered to obtain the carbon powder/fibrous carbon sheet.

    摘要翻译： 提供了通过混合碳粉和纤维状碳而形成的电极，其中消除了树脂基粘合剂等和导电促进材料等的影响以具有低电阻和优异的电容性质; 使用该电极的双电层电容器; 和电极的制造方法。 提供了将粒径小于100nm的碳粉末和纤维状碳分散在溶剂中的分散工序。 分散步骤是使溶液的喷射液彼此碰撞或者向溶液施加剪切应力和离心力，从而分散碳粉和纤维状碳。 此外，该方法包括片状电极形成步骤，其中将经过分散步骤的溶液过滤以获得碳粉/纤维状碳片。

    DYE-SENSITIZED SOLAR CELL
    26.
    发明申请
    DYE-SENSITIZED SOLAR CELL 审中-公开
    透明的太阳能电池

    公开(公告)号：US20150332858A2

    公开(公告)日：2015-11-19

    申请号：US14410819

    申请日：2013-06-26

    申请人： NIPPON CHEMI-CON CORPORATION

    发明人： Kenji MACHIDA ,  Nozomu KAMIYAMA ,  Shingo TAKEUCHI ,  Kenji TAMAMITSU

    IPC分类号： H01G9/20 ,  H01L51/00

    CPC分类号： H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0036 ,  H01L51/0037 ,  H01M4/608 ,  H01M14/005 ,  Y02E10/542 ,  Y02P70/521

    摘要： Provided is a dye-sensitized solar cell which exhibits excellent heat resistance and high photoelectric conversion efficiency. This dye-sensitized solar cell is provided with: a negative electrode having a semiconductor layer with a pigment as a photosensitizer, an electrolyte layer located on the semiconductor layer of the negative electrode having a paired oxidized species and reduced species, and a positive electrode located on the electrolyte layer having a conductive polymer layer that acts as a catalyst to convert the oxidized species into the reduced species. The conductive polymer layer in the positive electrode contains a polymer derived from at least one monomer selected from the group consisting of 3,4-disubstituted thiophenes; and an anion as a dopant to the polymer generated from at least one organic non-sulfonate compound having an anion with the molecular weight of 200 or more. The thickness of the conductive polymer layer is within the range of 100 to 10000 nm.

    摘要翻译： 本发明提供耐热性优异，光电转换效率高的染料敏化太阳能电池。 这种染料敏化太阳能电池具有：具有半导体层的负极，其具有作为光敏剂的颜料，位于负极的半导体层上的电解质层，具有成对的氧化物质和还原物质，以及位于 在具有导电聚合物层的电解质层上，该导电聚合物层充当将氧化物质转化为还原物质的催化剂。 正极中的导电性高分子层含有来自至少一种选自3,4-二取代噻吩的单体的聚合物， 以及由具有分子量为200以上的阴离子的至少一种有机非磺酸盐化合物生成的聚合物作为聚合物的阴离子。 导电聚合物层的厚度在100至10000nm的范围内。

    ELECTRODE MATERIAL AND MANUFACTURING METHOD THEREOF
    28.
    发明申请
    ELECTRODE MATERIAL AND MANUFACTURING METHOD THEREOF 有权
    电极材料及其制造方法

    公开(公告)号：US20150207144A1

    公开(公告)日：2015-07-23

    申请号：US14670842

    申请日：2015-03-27

    申请人： NIPPON CHEMI-CON CORPORATION

    发明人： Katsuhiko NAOI ,  Wako NAOI ,  Yoshihiro MINATO ,  Satoshi KUBOTA ,  Syuichi ISHIMOTO ,  Kenji TAMAMITSU

    IPC分类号： H01M4/36 ,  H01M4/62 ,  H01M4/04 ,  H01M4/58

    CPC分类号： H01M4/366 ,  B82Y30/00 ,  H01G11/32 ,  H01G11/38 ,  H01G11/86 ,  H01M4/0471 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/0525 ,  Y02E60/13 ,  Y02T10/7022

    摘要： A method for manufacturing composites in which the nanosize of a carbon material and a metal compound can be maintained as the final product is realized to provide a superior electrode material. A treatment of increasing the functional groups possessed by a carbon material is performed in advance. Then, a metal compound precursor is supported on a carbon material by separately performing a treatment of adsorbing one of source materials of the metal compound to the functional groups of the carbon material having increased functional groups and a treatment of reacting the adsorbed source material of the metal compound with the rest of the source materials on the carbon material to produce a metal compound precursor on the carbon material. Finally, a lithium source is introduced and calcined.

    摘要翻译： 实现了可以将碳材料和金属化合物的纳米尺寸保持为最终产品的复合材料的制造方法，以提供优异的电极材料。 预先进行增加碳材料所具有的官能团的处理。 然后，通过分别进行将金属化合物的原料吸附到具有增加的官能团的碳材料的官能团的处理中，将金属化合物前体负载在碳材料上，以及处理使吸附的源材料 金属化合物与其余的源材料在碳材料上以在碳材料上产生金属化合物前体。 最后，引入锂源并煅烧。

    ELECTRODE FOR ELECTRIC DOUBLE LAYER CAPACITOR AND METHOD FOR PRODUCING THE SAME
    30.
    发明申请
    ELECTRODE FOR ELECTRIC DOUBLE LAYER CAPACITOR AND METHOD FOR PRODUCING THE SAME 有权
    电双层电容器用电极及其制造方法

    公开(公告)号：US20130180091A1

    公开(公告)日：2013-07-18

    申请号：US13692788

    申请日：2012-12-03

    申请人： Nippon Chemi-con Corporation

    发明人： Kenji Machida ,  Shunzo Suemastu ,  Kenji Tamamitsu

    IPC分类号： H01G11/36

    CPC分类号： H01G11/36 ,  H01G9/016 ,  H01G9/058 ,  H01G9/155 ,  H01G11/28 ,  H01G11/70 ,  Y02E60/13 ,  Y10T29/417

    摘要： An electrical double-layer capacitor electrode with excellent capacitance characteristics is obtained together with a manufacturing method therefor. Paper-molded sheet of carbon nanotubes is integrated with etched foil constituting a collector, by means of bumps and indentations formed on the surface of etched foil to prepare an electrical double-layer capacitor electrode. Alternatively, carbon nanotubes grown around core catalyst particles on substrate are integrated with etched foil by means of humps and indentations formed on the surface of etched foil to prepare all electrical double-layer capacitor electrode. To manufacture these electrodes, this carbon nanotube sheet or substrate with carbon nanotubes grown thereon is laid over bumps and indentations on the surface of etched foil, and the sheet or substrate and the foil are pressed under 0.01 to 100 t/cm2 of pressure to integrate the carbon nanotubes with the etched foil.

    摘要翻译： 获得具有优异的电容特性的电双层电容器电极及其制造方法。 通过形成在蚀刻箔的表面上的凸起和凹陷，将碳纳米管的纸模成型片与构成集电体的蚀刻箔一体化，以制备双电层电容器电极。 或者，通过在蚀刻箔的表面上形成的凸起和凹陷将蚀刻的箔与蚀刻箔结合在基板上的核心催化剂颗粒周围生长的碳纳米管，以制备所有双电层电容器电极。 为了制造这些电极，将碳纳米管片或其上生长有碳纳米管的基板放置在蚀刻箔的表面上的凸起和凹陷上，并将片或基片和箔压制在0.01至100t / cm 2的压力下以整合 具有蚀刻箔的碳纳米管。