摘要:
A gas treatment module and method includes a first gas purifier and a second gas purifier that cooperate to control a concentration of contaminants in an outgoing portion of a gas stream when the concentration of the contaminants in an incoming portion of the gas stream temporarily exceeds a threshold concentration. One example gas treatment module includes an adsorbent media that temporarily retains at least a portion of the contaminants in the gas stream when the concentration is greater than or equal to the threshold concentration. The adsorbent media later releases the retained contaminants, either to an outgoing portion of the gas stream or to a photocatalyst, when the concentration is less than the threshold concentration. One example method of gas treatment includes controlling the concentration of contaminants in the outgoing portion of the gas stream when the concentration of the contaminants in the incoming portion of the gas stream temporarily exceeds the threshold concentration.
摘要:
A gas recovery system comprising a source of gas having a preselected concentration of a desired component (9), at least one application (1) that adds impurities to said gas, and at least one an adsorption system (6) that purifies said gas to produce a purified gas for re-use in application (1), wherein said at least one adsorption system includes at least one adsorbent bed (A) having at least three layers of adsorbents. A recovery process is also disclosed.
摘要:
In a process for separating propylene from a mixture comprising propylene and propane, the mixture is passed through a bed of an adsorbent comprising a porous crystalline material having (i) a diffusion time constant for propylene of at least 0.1 sec−1, when measured at a temperature of 373° K and a propylene partial pressure of 8 kPa, and (ii) a diffusion time constant for propane, when measured at a temperature of 373° K and a propane partial pressure of 8 kPa, less than 0.02 of said diffusion time constant for propylene. The bed preferentially adsorbs propylene from the mixture. The adsorbed propylene is then desorbed from the bed either by lowering the pressure or raising the temperature of the bed.
摘要:
Xenon and/or krypton are recovered from oxygen containing gas, typically derived from liquid oxygen bottoms in a cryogenic air separation plant, by selective adsorption on a Li and Ag exchange zeolite containing 5 to 40% Ag exchange capacity on an equivalents basis, with periodic thermal regeneration of the adsorbent.
摘要:
A gas adsorption composite a high density adsorbent including a high density layer having a first density of at least 0.3 g/cc; and a low density adsorbent having a low density layer having a second density of less than 0.3 g/cc, wherein the high density adsorbent is in substantially contiguous contact with the low density adsorbent and each of the high density adsorbent and the low density adsorbent has an adsorbent surface area of at least 500 m2/g. A pressure swing adsorption process for recovering a product gas from a feed gas, said process including supplying a pressure swing adsorption apparatus comprising a gas adsorption composite, feeding a feed gas into said pressure swing adsorption apparatus during a feed period not exceeding 100 seconds and recovering said product gas from said pressure swing adsorption apparatus.
摘要:
A fluid storage and dispensing system including a vessel containing a low heel carbon sorbent having fluid adsorbed thereon, with the system arranged to effect desorption of the fluid from the sorbent for dispensing of fluid on demand. The low heel carbon sorbent preferably is characterized by at least one of the following characteristics: (i) Heel, measured for gaseous arsine (AsH3) at 20° C. at 20 Torr, of not more than 50 grams AsH3 per liter of bed of the sorbent material; (ii) Heel, measured for gaseous boron trifluoride (BF3) at 20° C. at 20 Torr, of not more than 20 grams boron trifloride per liter of bed of the sorbent material; (iii) Heel, measured for gaseous germanium tetrafluoride (GeF4) at 20° C. at 20 Torr, of not more than 250 grams AsH3 per liter of bed of the sorbent material; (iv) Heel, measured for gaseous arsenic pentafluoride (AsF5) at 20° C. at 20 Torr, of not more than 700 grams AsF5 per liter of bed of the sorbent material; (v) Heel, measured for gaseous trimethyl silane (3MS) at 20° C. at 20 Torr, of not more than 160 grams 3MS per liter of bed of the sorbent material; and (vi) Heel, measured for gaseous ethane (C2H4) at 21° C. at 25 Torr, of not more than 10 grams ethane per liter of bed of the sorbent material.
摘要:
A gas supply system including a gas cabinet defining an enclosure including therein a gas dispensing manifold and one or more adsorbent-based gas storage and dispensing vessels mounted in the enclosure and joined in gas flow communication with the gas dispensing manifold. The enclosure may be maintained under low or negative pressure conditions for enhanced safety in the event of leakage of gas from the gas storage and dispensing vessel(s) in the enclosure. The gas supply system may be coupled to a gas-consuming unit in a semiconductor manufacturing facility, e.g., an ion implanter, an etch chamber, or a chemical vapor deposition reactor.
摘要:
The invention relates to a process for the purification of a gas stream containing one or more gaseous impurities from the group formed by carbon dioxide, water vapor, H2S, alcohols, S02 and C1-C8 saturated or unsaturated, linear, branched or cyclic hydrocarbons. The gas stream is brought into contact with several different porous carbon adsorbents, that is to say active carbons having different properties and characteristics. The gas is air, nitrogen, hydrogen produced by the reforming or cracking of ammonia or the cracking of alcohols or hydrocarbons, natural gas, combustion gas or fermentation gas.
摘要:
A method of producing ammonia water (aqua ammonia) by means of desorbing an ammonia laden sorbent, preferably a zeolite molecular sieve or silica gel into water. The method includes placing an activated sorbent material into a sealed vessel, such as a pressure pot, and exposing it to ammonia gas for a period of time. After loading by exposure to ammonia gas, the loaded sorbent is then placed into an air and water tight container for storage. The pouch can be stored for extended lengths of time prior to use of the contents. When ready for use, the contents of the pouch are dropped into a container of water. In one preferred use of the loaded sorbents, the container of water is a toilet bowl. In another preferred embodiment, the container is a separate disposal pouch, such as a small plastic bag capable of holding an ostomy pouch, sanitary napkin or incontinence pad. After use, the ostomy pouch or other device can be made to dissolve by placing the used pouch in ammonia water at a pH of 10.3 or higher.
摘要:
A fill system and methodology for the manufacture of fluid storage and dispensing vessels containing sorbent material for holding a sorbable fluid, for on-demand dispensing of the fluid in the use of the vessel. The fill system and methodology are directed to minimizing the processing time required to dissipate the heat of sorption incident to the loading of the sorbable fluid onto the sorbent material, so that thermal equilibration time in the manufacture of the vessels is substantially reduced in relation to the use of only ambient convective air cooling for dissipation of the heat of sorption from the fluid-filled vessel.