Method for Producing Diaryl Carbonate
    24.
    发明申请
    Method for Producing Diaryl Carbonate 有权
    碳酸二芳基酯的制备方法

    公开(公告)号:US20120316357A1

    公开(公告)日:2012-12-13

    申请号:US13579649

    申请日:2011-02-23

    IPC分类号: C07C68/06

    摘要: The present invention provides a method for continuously producing a diaryl carbonate stably for a long time with high productivity. The method for producing a diaryl carbonate according to the present invention comprises a step (1) of obtaining an alkylaryl carbonate; a step (2) of obtaining a reaction product from the alkylaryl carbonate; a step (3) of separating the diaryl carbonate and a high boiling component from the reaction product; and a step (4) of recycling the high boiling component into the steps (1) and/or (2), wherein the high boiling component recycled in the step (4) includes a particular compound, and the particular compound satisfies a particular condition.

    摘要翻译: 本发明提供一种以高生产率长时间稳定连续生产碳酸二芳基酯的方法。 根据本发明的制备碳酸二芳基酯的方法包括获得碳酸烷基芳基酯的步骤(1) 从碳酸烷基芳基酯获得反应产物的步骤(2); 从反应产物中分离碳酸二芳酯和高沸点组分的步骤(3); 以及将高沸点组分再循环到步骤(1)和/或(2)中的步骤(4),其中在步骤(4)中再循环的高沸点组分包括特定的化合物,特定化合物满足特定条件 。

    Moisture curable oil and fat compositions and processes for preparing the same
    26.
    发明授权
    Moisture curable oil and fat compositions and processes for preparing the same 有权
    水溶性油脂组合物及其制备方法

    公开(公告)号:US08110036B2

    公开(公告)日:2012-02-07

    申请号:US12287100

    申请日:2008-10-06

    IPC分类号: C09D191/00 C08L91/00 C07F7/08

    摘要: A moisture-curable, silane-modified oil is disclosed. The silane-modified oil includes an unsaturated oil having at least one unsaturated aliphatic hydrocarbon chain per molecule of the unsaturated oil, and at least one hydrolysable silyl group grafted to the unsaturated aliphatic hydrocarbon chain. The silane-modified oil has a degree of unsaturation that is substantially similar that of the unsaturated oil. A process for forming the moisture-curable, silane-modified oil according to the disclosure includes reacting the unsaturated oil with an unsaturated hydrolysable silane in the presence of a free radical initiator. Also disclosed is a cured silane-modified oil which includes the reaction product of the silane-modified oil and water. Compositions according to the disclosure have relatively low viscosities (facilitating their application to a substrate) and have relatively high levels of silane grafting (resulting in non-leaching cured compositions with a high gel content).

    摘要翻译: 公开了一种可湿固化的硅烷改性油。 硅烷改性油包括每分子不饱和油具有至少一个不饱和脂族烃链的不饱和油和接枝到不饱和脂族烃链的至少一个可水解甲硅烷基。 硅烷改性油的不饱和度基本上类似于不饱和油。 根据本公开的形成可湿固化的硅烷改性油的方法包括在自由基引发剂存在下使不饱和油与不饱和可水解硅烷反应。 还公开了一种固化的硅烷改性油,其包括硅烷改性油与水的反应产物。 根据本公开的组合物具有相对低的粘度(促进其应用于基材)并且具有相对高水平的硅烷接枝(导致具有高凝胶含量的非浸出固化的组合物)。

    Air activated organotin catalysts for polyurethane synthesis
    29.
    发明授权
    Air activated organotin catalysts for polyurethane synthesis 有权
    用于聚氨酯合成的空气活化有机锡催化剂

    公开(公告)号:US07919423B2

    公开(公告)日:2011-04-05

    申请号:US12698288

    申请日:2010-02-02

    摘要: This invention relates to an organotin-based catalyst system for polyurethane synthesis that is useful in coatings applications. The catalyst has low activity in the absence of oxygen. When a coating mixture comprising the catalyst is sprayed and/or applied to a substrate as a thin film in air, the catalyst is activated. For solvent-based refinish systems comprising hydroxyl and isocyanate species at high solids levels, the catalyst system therefore provides extended viscosity stability, i.e., pot life.

    摘要翻译: 本发明涉及用于聚氨酯合成的有机锡基催化剂体系,其可用于涂料应用。 催化剂在不存在氧的情况下具有低活性。 当包含催化剂的涂料混合物在空气中作为薄膜喷涂和/或施加到基材上时,催化剂被活化。 对于含有高固体含量的羟基和异氰酸酯物质的基于溶剂的修补体系,催化剂体系因此提供了延长的粘度稳定性,即适用期。

    Method for Separating Out and Recovering Dialkyltin Dialkoxide
    30.
    发明申请
    Method for Separating Out and Recovering Dialkyltin Dialkoxide 有权
    分离和还原二烷基锡二氧化二铁的方法

    公开(公告)号:US20100160662A1

    公开(公告)日:2010-06-24

    申请号:US12223984

    申请日:2007-02-22

    IPC分类号: C07F7/22 C07C68/00

    摘要: For an alkyltin alkoxide catalyst composition used in carbonate production, there is a problem that the alkyltin alkoxide catalyst composition is thermally decomposed by being heated in the production process, changing into an undistillable alkyltin alkoxide catalyst composition containing a high boiling deactivated component and an active component. The present invention provides a method for separating out and recovering the active component from the alkyltin alkoxide catalyst composition as a useful dialkyltin dialkoxide. According to the present invention, there is disclosed a method in which such an undistillable alkyltin alkoxide catalyst composition containing a high boiling deactivated component and an active component is reacted with an alcohol and/or a carbonate, so as to obtain a reaction liquid containing a product originating from the active component, and then the reaction liquid is subjected to distillation, so as to separate out and recover a dialkyltin dialkoxide from the product originating from the active component.

    摘要翻译: 对于用于碳酸盐生产的烷基锡醇盐催化剂组合物,存在的问题是烷基锡醇盐催化剂组合物在制备过程中被加热而热分解,变成不含有高沸点失活组分的烷基锡醇盐催化剂组合物和活性组分 。 本发明提供一种从烷基锡醇盐催化剂组合物中分离出并回收活性组分作为有用的二烷基锡二醇盐的方法。 根据本发明,公开了一种方法,其中使含有高沸失活组分和活性组分的这种不挥发的烷基锡醇盐催化剂组合物与醇和/或碳酸酯反应,以获得含有 来自活性组分的产物,然后将反应液体进行蒸馏,以从源自活性组分的产物中分离出并回收二烷基锡二烷氧基化物。