Abstract:
The simultaneous control of the two forms of mercury in petroleum reservoirs (elemental and particulate HgS) is accomplished by the use of agents which react with the elemental mercury and bind the particulate HgS to the formation material: a mercury capture agent and a chemical sand control agent. The elemental control agent reacts with and adsorbs the elemental mercury. The chemical sand control agents reduce or eliminate the dislodging of fine particulate mercury from the surface of the formation material. This simultaneous control can be applied for a new well during well completion operations wherein analyses indicate the presence of mercury. This simultaneous control can also be applied to a currently producing well during a work-over when mercury is detected in the gas or crude products.
Abstract:
The invention relates to the treatment of water, including for example treatment in connection with hydrocarbon production operations. Silica in water produces undesirable scaling in processing equipment, which causes excess energy usage and maintenance problems. Electrocoagulation (EC) at relatively high water temperature, followed by any of membrane distillation or forward osmosis (FO), may be combined with a subsequent process of ceramic ultra-filtration (UF filtration) employed to treat water. Water to be treated may be produced water that has been pumped from a subterranean reservoir. The treated water may be employed to generate steam. The treatment units (e.g., EC, forward osmosis, UF filtration, etc) can be configured into one system as an on-site installation or a mobile unit for on-site or off-site water treatment.
Abstract:
A system for applying power into a wellbore. The system can include a casing, a tubing string, a first and second isolator sub, a power source, and an electrical device. The casing has a first cavity running therethrough. The tubing string is disposed within the first cavity without contacting the casing, where the tubing string has a second cavity running therethrough. The first isolator sub is mechanically coupled to the tubing string and positioned between the neutral section and the power-transmitting section of the tubing string. The power source is electrically coupled to the power-transmitting section of the tubing string below the first isolator sub. The second isolator sub is mechanically coupled to the tubing string and positioned between the bottom neutral section and the power-transmitting section of the tubing string. The electrical device is electrically coupled to a bottom end of the power-transmitting section of the tubing string.
Abstract:
The invention provides complexes in which a calixarene-related compound is coordinated to an iridium-containing metal colloid. The complexes can be immobilized on a substrate. The complexes of the invention are useful as tunable and highly robust isolated metal colloids that find use in binding of molecules and catalysis of chemical reactions.
Abstract:
In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant as metal residuals. In the present disclosure, the metals can be recovered in a chemical precipitation step, wherein the supernatant is mixed with at least one of an acid, a sulfide-containing compound, a base, and combinations thereof to precipitate at least 50% of metal ions in at least one of the metal residuals, wherein the precipitation is carried out at a pre-select pH. The precipitate is isolated and recovered, yielding an effluent stream. The precipitate and/or the effluent stream can be further treated to form at least a metal precursor feed which can be used in the co-precipitation reaction. The process generates an effluent to waste treatment containing less than 50 ppm metals.
Abstract:
Controlled fracturing in geologic formations is carried out in a method employing a combination of alternating and impulsive current waveforms, applied in succession to achieve extensive fracturing and disintegration of rock materials for liquid and gas recovery. In a pre-conditioning step, high voltage discharges and optionally with highly ionizable gas injections are applied to a system of borehole electrodes, causing the formation to fracture with disintegration in multiple directions but confined between the locations of electrode pairs of opposite polarity. After pre-conditioning, intense current waveform of pulse energy is then applied to the system of borehole electrodes to create waves of ionization or shock waves with bubbles of heated gas that propagate inside and outside the high conductivity channels, resulting in rock disintegration with attendant large scale multiple fracturing.
Abstract:
We provide a process for regenerating a used acidic ionic liquid catalyst which has been deactivated by conjunct polymers in a reactor, by removing at least 57 wt % of the conjunct polymers originally present in the used acidic ionic liquid catalyst in a separate regeneration reactor, so as to increase the activity of the catalyst. We also provide a regenerated used acidic ionic liquid catalyst having increased activity.
Abstract:
Systems and methods are provided for use in predicting sand production in a geomechanical reservoir system. Computation of the sand production predictions can include solving a system of partial differential equations that model the geomechanical reservoir system. Systems and methods also are provided for use in operating a geomechanical reservoir system based on the sand production prediction for controlling sand production in the geomechanical reservoir system.
Abstract:
A localized inflow tracer (112) may be flushed from a gravel pack (104) surrounding a base pipe (102) of a production well by outwardly venting the inflow tracer. The base pipe (102) may include a non-perforated section (106) disposed adjacent to one or more perforated sections (108). A tracer carrier (110) may be disposed circumferentially about at least a portion of the non-perforated section (106) of the base pipe (102). An inflow tracer (112) may be released from the tracer carrier (110) into production fluid within the gravel pack (104) proximate to the non-perforated section (106) of the base pipe (102) such that the inflow tracer is flushed from the gravel pack (104) into individual ones of the one or more perforated sections (108) of the base pipe (102) and transported with the production fluid. The inflow tracer (112) may be prevented from being flushed directly from the tracer carrier (110) into the base pipe (102) due to a lack of permeability of the non-perforated section of the base pipe (102).
Abstract:
Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.