公开(公告)号：US08084557B2

公开(公告)日：2011-12-27

申请号：US12735014

申请日：2008-12-18

Applicant: Manfred Hecker ,  Markus Schopf ,  Axel Hamann ,  Paulus-Petrus Maria de Lange

Inventor： Manfred Hecker ,  Markus Schopf ,  Axel Hamann ,  Paulus-Petrus Maria de Lange

IPC: C08F2/34 ,  C07C7/09

CPC classification number: C10G50/00 ,  B01D2253/108 ,  B01D2256/24 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C10G2300/1088 ,  C10G2300/1092 ,  C10G2300/308 ,  C10G2400/22 ,  Y10S526/901 ,  C08F2/34 ,  C08F2/002 ,  C08F210/14

Abstract: A continuous gas-phase process for the polymerization of alpha-olefins, in particular ethylene, comprising passing an alpha-olefin monomer stream through an oil filter in order to reduce the amount of oil to less than 8 ppm, and polymerizing the thus purified monomer feed in gas-phase reactor; the reduction of the amount of oil improves the operability of the plant over time.

Abstract translation: 用于α-烯烃，特别是乙烯聚合的连续气相方法，包括使α-烯烃单体流通过油过滤器，以将油的量减少至小于8ppm，并将由此纯化的单体聚合 在气相反应器中进料; 随着时间的推移，油的减少提高了工厂的可操作性。

公开(公告)号：US20100331502A1

公开(公告)日：2010-12-30

申请号：US12735014

申请日：2008-12-18

Applicant: Manfred Hecker ,  Markus Schopf ,  Axel Hamann ,  Paulus-Petrus Maria De Lange

Inventor： Manfred Hecker ,  Markus Schopf ,  Axel Hamann ,  Paulus-Petrus Maria De Lange

IPC: C08F2/34

CPC classification number: C10G50/00 ,  B01D2253/108 ,  B01D2256/24 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C10G2300/1088 ,  C10G2300/1092 ,  C10G2300/308 ,  C10G2400/22 ,  Y10S526/901 ,  C08F2/34 ,  C08F2/002 ,  C08F210/14

Abstract: A continuous gas-phase process for the polymerization of alpha-olefins, in particular ethylene, comprising passing an alpha-olefin monomer stream through an oil filter in order to reduce the amount of oil to less than 8 ppm, and polymerizing the thus purified monomer feed in gas-phase reactor; the reduction of the amount of oil improves the operability of the plant over time.

Abstract translation: 用于α-烯烃，特别是乙烯聚合的连续气相方法，包括使α-烯烃单体流通过油过滤器，以将油的量减少至小于8ppm，并将由此纯化的单体聚合 在气相反应器中进料; 随着时间的推移，油的减少提高了工厂的可操作性。

公开(公告)号：US20090105414A1

公开(公告)日：2009-04-23

申请号：US12226390

申请日：2007-05-04

Applicant: Shahram Mihan ,  Rainer Karer ,  Manfred Hecker

Inventor： Shahram Mihan ,  Rainer Karer ,  Manfred Hecker

IPC: C08F2/06

CPC classification number: C08F210/16 ,  B01J8/1809 ,  B01J19/002 ,  B01J2208/00734 ,  B01J2219/00247 ,  B01J2219/00254 ,  C08F10/00 ,  C08F110/02 ,  C08F2/005 ,  C08F2/44 ,  C08F210/14 ,  C08F210/06 ,  C08F210/08

Abstract: Method for metering polar, antistatically acting process auxiliaries into a polymerization reactor in which the process auxiliaries are present in solution in a nonpolar solvent, wherein the electrical conductivity of the solution is measured and the amount of the process auxiliary metered in is determined from the electrical conductivity.

Abstract translation: 将极性，抗静电作用的加工助剂计量到聚合反应器中的方法，其中工艺助剂存在于非极性溶剂中的溶液中，其中测量溶液的导电性，并且从电气中测定辅助计量的量 电导率。

公开(公告)号：US20090099315A1

公开(公告)日：2009-04-16

申请号：US12085539

申请日：2006-11-14

Applicant: Jennifer Kipke ,  Shahram Mihan ,  Rainer Karer ,  Jorg Auffermann ,  Manfred Hecker ,  Paulus De Lange ,  Harald Schmitz

Inventor： Jennifer Kipke ,  Shahram Mihan ,  Rainer Karer ,  Jorg Auffermann ,  Manfred Hecker ,  Paulus De Lange ,  Harald Schmitz

IPC: C08L23/06

CPC classification number: C08L23/04 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/035 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/06 ,  C08L2666/02

Abstract: A polyethylene composition, in particular suitable for the preparation of films, and a process for preparing the same are described. The polyethylene composition of the invention comprises from 50 to 89% by weight of a first polyethylene component comprising at least one multimodal polyethylene including a plurality of ethylene polymer fractions having distinct molecular weights and comonomer contents, at least one of said plurality of ethylene polymer fractions being prepared by the use of a single site catalyst, and from 50 to 11% by weight of a second polyethylene component comprising a low or medium density polyethylene.

Abstract translation: 描述了特别适用于制备薄膜的聚乙烯组合物及其制备方法。 本发明的聚乙烯组合物包含50至89重量％的第一聚乙烯组分，其包含至少一种多峰聚乙烯，其包含具有不同分子量和共聚单体含量的多种乙烯聚合物级分，所述多种乙烯聚合物级分中的至少一种 通过使用单中心催化剂制备，以及50至11重量％的包含低密度或中密度聚乙烯的第二聚乙烯组分。

公开(公告)号：US20070264171A1

公开(公告)日：2007-11-15

申请号：US11667349

申请日：2005-11-09

Applicant: Eberhard Herrmann ,  Axel Sperber ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus de Lange ,  Jorg Halpap ,  Cyrus Ahmadzade-Youssefi

Inventor： Eberhard Herrmann ,  Axel Sperber ,  Manfred Hecker ,  Rainer Karer ,  Klaus Berhalter ,  Paulus de Lange ,  Jorg Halpap ,  Cyrus Ahmadzade-Youssefi

IPC: C08F2/34

CPC classification number: B01J8/1872 ,  B01J8/0055 ,  B01J8/24 ,  B01J2208/00256 ,  B01J2208/00274 ,  B04C5/081 ,  C08F6/02 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/04 ,  C08F2/34

Abstract: An apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a recycle gas line (2) connected to the reactor for discharging and recirculating the recycle gas stream comprising the unpolymerized olefin and a cyclone (3) located in the recycle gas line for the reduction and precipitation of the solid particles entrained in the recycle gas from the reactor, with the cyclone comprising an upper section (3a) which has an essentially vertical central axis, whose wall extends along a rotationally symmetric body and which is provided with a cyclone inlet (4) arranged eccentrically relative to the central axis, a middle section (3b) which adjoins the upper section (3a) and whose wall extends along a rotationally symmetric body which tapers in a downward direction, a lower section (3c) for discharging the solid particles precipitated from the recycle gas which adjoins the middle section (3b) and whose wall extends along a rotationally symmetric body and a tube (5) extending essentially axially symmetrically down into the upper section and, if appropriate, the middle section for discharging the recycle gas which has been freed of the particles. According to the invention the ratio Hi of the distance hi from the lower end of the tube (5) extending downward into the cyclone to the intersection (6) of an imaginary extension of the wall of the downward-extending tube (5) with the wall of the middle section (3b) to the diameter di of the downward-extending tube (5) is from 3 to 8, in particular from 4 to 7.

Abstract translation: 用于烯烃聚合的装置，特别是乙烯，包括气相流化床反应器（1），连接到反应器的再循环气体管线（2），用于排出和再循环包含未聚合烯烃的循环气流和 旋流器（3），其位于循环气体管线中，用于还原和沉淀夹带在来自反应器的再循环气体中的固体颗粒，旋风分离器包括具有基本上垂直的中心轴线的上部分（3a），其上壁延伸 沿着旋转对称体并且设置有相对于中心轴线偏心布置的旋风入口（4），邻近上部（3a）并且其壁沿旋转对称体延伸的中间部分（3b） 用于排出邻近中间部分（3b）并且其壁延伸的再循环气体沉淀的固体颗粒的下部分（3c） 旋转对称体和基本上轴向对称地延伸到上部的管（5）以及适当的中间部分用于排出已经没有颗粒的循环气体。 根据本发明，与从下游进入旋风分离器的管（5）的下端距离h i i的距离h i i的比例H i 向下延伸的管（5）的壁与中间部分（3b）的壁与向下延伸的管（5）的直径d iI i的假想延伸为3至 8，特别是4到7。

公开(公告)号：US06849699B2

公开(公告)日：2005-02-01

申请号：US10658916

申请日：2003-09-11

Applicant: Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

Inventor： Peter Bauer ,  Armin Lange ,  Rainer Karer ,  Philipp Rosendorfer ,  Manfred Hecker ,  Günther Schweier ,  Wolfgang Micklitz ,  Kaspar Evertz ,  Hans-Jacob Feindt

IPC: C08J5/18 ,  C08F2/34 ,  C08F4/02 ,  C08F4/24 ,  C08F4/69 ,  C08F10/02 ,  C08F210/02

CPC classification number: C08F10/02 ,  C08F4/24 ,  C08F2/34

Abstract: A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢   ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢   ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.

Abstract translation: 用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合 在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床 包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物 特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

公开(公告)号：US06180729B2

公开(公告)日：2001-01-30

申请号：US09201084

申请日：1998-11-30

Applicant: Armin Lange ,  Wolfgang Micklitz ,  Rainer Karer ,  Kaspar Evertz ,  Shahram Mihan ,  Hans-Jacob Feindt ,  Manfred Hecker ,  Peter Bauer ,  Philipp Rosendorfer

Inventor： Armin Lange ,  Wolfgang Micklitz ,  Rainer Karer ,  Kaspar Evertz ,  Shahram Mihan ,  Hans-Jacob Feindt ,  Manfred Hecker ,  Peter Bauer ,  Philipp Rosendorfer

IPC: C08F240

CPC classification number: C08F10/00 ,  C08F2/005 ,  C08F210/16 ,  Y02P20/584 ,  C08F2/34 ,  C08F2/40 ,  C08F2/007 ,  C08F2/002 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/18

Abstract: In a continuous gas-phase polymerization process for preparing ethylene and propene homopolymers and copolymers, in which ethylene, propene or a mixture of ethylene or propene and C3-C8-&agr;-monoolefins is polymerized in the polymerization zone of a gas-phase polymerization reactor at from 30 to 125° C. and a pressure of from 1 to 100 bar in the gas phase in a bed of finely divided polymer in the presence of a catalyst, where the reactor gas is circulated to remove the heat of polymerization, polymer deposits in the circulating gas line are prevented by metering a catalyst poison having a boiling point above the maximum temperature within the circulating gas line into this circulating gas line in at most such an amount that it does not significantly impair the productivity of the catalyst in the reactor.

Abstract translation: 在用于制备乙烯和丙烯均聚物和共聚物的连续气相聚合方法中，其中乙烯，丙烯或乙烯或丙烯和C 3 -C 8-α-单烯烃的混合物在气相聚合反应器的聚合区中聚合 在催化剂存在下，在细分散的聚合物床中的气相中，在30至125℃和1至100巴的压力下，其中反应器气体循环以除去聚合热，聚合物沉积物 通过将沸点高于循环气体管线中的最高温度的催化剂毒物计量到该循环气体管线中，至多使其不显着损害反应器中催化剂的生产率的程度来防止循环气体管线 。