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    ENGINEERING PLASTIC RESIN COMPOSITION CONTAINING GRAFT COPOLYMER
    33.
    发明申请
    ENGINEERING PLASTIC RESIN COMPOSITION CONTAINING GRAFT COPOLYMER 失效
    工程塑料树脂组合物含有GRAFT共聚物

    公开(公告)号：US20110021703A1

    公开(公告)日：2011-01-27

    申请号：US12812521

    申请日：2009-01-14

    Applicant: Manabu Nomura ,  Susumu Kanno ,  Ryo Aburatani ,  Shuji Machida

    Inventor： Manabu Nomura ,  Susumu Kanno ,  Ryo Aburatani ,  Shuji Machida

    IPC: C08G63/46 ,  C08G65/48

    CPC classification number: C08L51/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F110/06 ,  C08F210/02 ,  C08F290/042 ,  C08J3/226 ,  C08J2423/00 ,  C08J2451/00 ,  C08L23/02 ,  C08L67/02 ,  C08L101/02 ,  C08L2314/06 ,  C08F4/65927 ,  C08F220/32 ,  C08F220/12 ,  C08L2666/02 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/15 ,  C08F220/14 ,  C08F220/34 ,  C08F220/20 ,  C08L51/00

    Abstract: Provided is a resin composition containing a resin component prepared by blending a graft copolymer with an engineering plastic, wherein the above graft copolymer is a graft copolymer satisfying (a) to (e) shown below: (a) a graft rate is 1 to 150% by mass, (b) a weight average molecular weight measured by GPC is 500 to 400000, (c) a molecular weight distribution (Mw/Mn) is 1.5 to 4, (d) a main chain is a polymerization chain containing 1 to 100% by mass of a monomer unit having a functional group interacting with the engineering plastic and (e) a side chain is a homopolymerization chain of a single kind selected from α-olefins having 3 to 28 carbon atoms or a copolymerization chain of two or more kinds selected therefrom or a copolymerization chain comprising an α-olefin unit having 3 to 28 carbon atoms and an ethylene unit which accounts for 50% by mass or less, and a mesopentad ratio [mmmm] of the polymerization chain is 30 to 80 mole %.

    Abstract translation: 本发明提供含有通过将接枝共聚物与工程塑料共混而制备的树脂成分的树脂组合物，其中上述接枝共聚物是满足下述（a）〜（e）的接枝共聚物：（a）接枝率为1〜150 （b）通过GPC测定的重均分子量为500〜400000，（c）分子量分布（Mw / Mn）为1.5〜4，（d）主链为含有1〜 100质量％具有与工程塑料相互作用的官能团的单体单元和（e）侧链是选自具有3〜28个碳原子的α-烯烃或两个或多个共聚链的共聚链的单一类型的均聚链 或选自其中的多种或包含碳原子数3〜28的α-烯烃单元和50质量％以下的乙烯单元的共聚合链，聚合链的触键比[mmmm]为30〜80摩尔 ％。

    Branched olefinic macromonomer, olefin graft copolymer, and olefin resin composition
    35.
    发明授权
    Branched olefinic macromonomer, olefin graft copolymer, and olefin resin composition 失效
    支链烯烃大分子单体，烯烃接枝共聚物和烯烃树脂组合物

    公开(公告)号：US06897261B1

    公开(公告)日：2005-05-24

    申请号：US10019293

    申请日：2000-07-18

    Applicant: Shuji Machida ,  Kazuo Sato ,  Tomio Tatsumi ,  Yasuhiro Goto

    Inventor： Shuji Machida ,  Kazuo Sato ,  Tomio Tatsumi ,  Yasuhiro Goto

    IPC: C08F290/04 ,  C08F290/14 ,  C08F297/08

    CPC classification number: C08F290/04 ,  C08F290/042 ,  C08F290/14 ,  C08F290/141

    Abstract: The invention relates to olefin branched macromonomers, olefin graft copolymers and olefin resin compositions having the advantage of good compatibility with polyolefin resins and good moldability and workability. The olefin branched macromonomer satisfies the following (a) and (b): (a) its weight-average molecular weight (Mw) measured through gel permeation chromatography (GPC) falls between 400 and 200000; (b) its vinyl content is at least 70 mol % of all the unsaturated groups in the macromonomer.

    Abstract translation: 本发明涉及烯烃支链大分子单体，烯烃接枝共聚物和烯烃树脂组合物，其具有与聚烯烃树脂的良好相容性和良好的成型性和可加工性。 烯烃支化大分子单体满足以下（a）和（b）：（a）通过凝胶渗透色谱法（GPC）测定的重均分子量（Mw）为400〜200000; （b）其乙烯基含量为大分子单体中所有不饱和基团的至少70摩尔％。

    Aluminum-oxy compound, catalyst component for polymerizing olefin, and method for producing polyolefin
    37.
    发明授权
    Aluminum-oxy compound, catalyst component for polymerizing olefin, and method for producing polyolefin 失效
    铝 - 氧化合物，用于聚合烯烃的催化剂组分和聚烯烃的制备方法

    公开(公告)号：US06737379B1

    公开(公告)日：2004-05-18

    申请号：US09601332

    申请日：2000-08-10

    Applicant: Mitsugu Kanzawa ,  Shuji Machida

    Inventor： Mitsugu Kanzawa ,  Shuji Machida

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C07F5/066 ,  C07F5/068 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/02 ,  C08F110/06 ,  C08F2420/02 ,  C08F4/6028 ,  C08F4/6428 ,  C08F4/65916 ,  C08F2500/18 ,  C08F4/7006

    Abstract: Provided are an aluminium-oxy compound obtained through reaction of an organoaluminium compound with water, which is soluble in hydrocarbon solvents and in which the amount of the organoaluminium compound remaining is at most 10% by weight; a carrier comprising the aluminium-oxy compound and an inorganic compound; and a catalyst component for olefin polymerization comprising the carrier and a transition metal compound. The catalyst component for olefin polymer production comprises the aluminium-oxy compound and gives polyolefins with good polymer morphology.

    Abstract translation: 提供了通过有机铝化合物与水反应获得的铝 - 氧化合物，其可溶于烃溶剂，其中剩余的有机铝化合物的量为至多10重量％ 包含铝 - 氧化合物和无机化合物的载体; 和用于烯烃聚合的催化剂组分，其包含载体和过渡金属化合物。 用于烯烃聚合物生产的催化剂组分包括铝 - 氧化合物，并产生具有良好聚合物形态的聚烯烃。

    Polyethylene, thermoplastic resin composition containing same, and process for preparing polyethylene
    38.
    发明授权
    Polyethylene, thermoplastic resin composition containing same, and process for preparing polyethylene 失效
    聚乙烯，含有它的热塑性树脂组合物，以及制备聚乙烯的方法

    公开(公告)号：US6121402A

    公开(公告)日：2000-09-19

    申请号：US45913

    申请日：1998-03-23

    Applicant: Shuji Machida ,  Haruo Shikuma ,  Ayami Hoshino ,  Yutaka Takakura

    Inventor： Shuji Machida ,  Haruo Shikuma ,  Ayami Hoshino ,  Yutaka Takakura

    IPC: C08F4/62 ,  C08F4/639 ,  C08F4/6392 ,  C08F8/04 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08L23/04 ,  C08L23/06

    CPC classification number: C08L23/06 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08L23/04 ,  C08F2420/02 ,  C08F2420/04 ,  C08F4/63904 ,  C08F4/63912 ,  C08F4/6392

    Abstract: Polyethylenes are disclosed herein which are derived from an ethylene monomer and in which any quaternary carbon atom is not present in a polymeric main chain; and the activation energy (Ea) of melt flow is in the range of 8 to 20 kcal/mol; as well as(1) a Huggins coefficient (k) and an intrinsic viscosity [.eta.] meet the relation of the equationk.gtoreq.0.2+0.0743.times.[.eta.];(2) a molar ratio [CH.sub.3 /CH.sub.2 ] of a methyl group to a methylene group is in a region of 0.005 to 0.1 and meets the equationTm.gtoreq.131-1340[CH.sub.3 /CH.sub.2 ];(3) an Mw and a die swell ratio (DR) meet the equationDR>0.5+0.125.times.log Mw; or(4) in the measurement of a loss elastic modulus, a .beta.-relaxation peak is present in the range of 0 to -100.degree. C.These polyethylenes are different from a usual HDPE, L-LDPE and LDPE, and they are excellent in working properties and permit the control of physical properties such as density, a melting point and crystallinity mainly in the state of a homopolymer.

    Abstract translation: 本文公开的聚乙烯衍生自乙烯单体，其中任何季碳原子不存在于聚合物主链中; 并且熔体流动的活化能（Ea）在8至20kcal / mol的范围内; 以及（1）哈金斯系数（k）和特性粘度η满足方程k> = = 0.2 + 0.0743×η的关系;（2）甲基的摩尔比[CH 3 / CH 2] 亚甲基的基团在0.005至0.1的范围内，并满足方程式T m> = 131-1340 [CH 3 / CH 2];（3）Mw和模头溶胀比（DR）符合方程式> 0.5 + 0.125xlog Mw; 或（4）在测定损耗弹性模量时，β松弛峰存在于0〜-100℃的范围内。这些聚乙烯与通常的HDPE，L-LDPE和LDPE不同，它们是优异的 在工作特性方面，主要是在均聚物的状态下，可以控制物理性质如密度，熔点和结晶度。

    Branched ethylenic macromonomer and its polymer
    39.
    发明授权
    Branched ethylenic macromonomer and its polymer 失效
    分支乙烯大分子单体及其聚合物

    公开(公告)号：US5955557A

    公开(公告)日：1999-09-21

    申请号：US632475

    申请日：1996-04-26

    Applicant: Shuji Machida ,  Masahiro Mitani ,  Masami Watanabe ,  Nobuhiro Yabunouchi

    Inventor： Shuji Machida ,  Masahiro Mitani ,  Masami Watanabe ,  Nobuhiro Yabunouchi

    IPC: C08F4/659 ,  C08F4/6592 ,  C08F8/04 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/02 ,  C08F210/16 ,  C08F10/14

    CPC classification number: C08F10/02 ,  C08F10/00 ,  C08F8/04 ,  C08F110/02 ,  C08F210/02 ,  C08F210/16 ,  C08F4/65912 ,  C08F4/6592 ,  Y10S526/943

    Abstract: A copolymer having the excellent molding and working properties obtainable by using a branched ethylenic macromonomer and a comonomer selected from the group consisting of ethylene, an .alpha.-olefin having 3 to 20 carbon atoms, cyclic olefins and styrenes. The branched ethylenic macromonomer of the present invention is derivable from ethylene singly or derivable from ethylene and another olefin, (a) a molar ratio of a terminal methyl group/a vinyl group in the macromonomer being in the range of 1 to 100, the macromonomer having a branch other than the branch directly derived from the other olefin, (b) a ratio of vinyl groups to the total unsaturated groups in the macromonomer being 70 mol % or more, (c) a weight-average molecular weight of the macromonomer in terms of a polyethylene measured by a GPC being in the range of 100 to 20,000.

    Abstract translation: PCT No.PCT / JP94 / 01792 Sec。 371日期：1996年04月28日 102（e）日期1996年4月28日PCT 1994年10月26日PCT公布。 公开号WO95 / 11931 日期：1993年10月26日具有通过使用支化乙烯性大分子单体和选自乙烯，碳原子数3〜20的α-烯烃，环状烯烃和苯乙烯的共聚单体得到的优异的成型性和工作性的共聚物。 本发明的支链乙烯性大分子单体可单独衍生自乙烯或可衍生自乙烯和另一种烯烃的乙烯基，（a）大分子单体中的末端甲基/乙烯基的摩尔比在1〜100的范围内，大分子单体 具有直接衍生自其它烯烃的分支以外的分支，（b）大分子单体中乙烯基与总不饱和基团的比例为70摩尔％以上，（c）大分子单体的重均分子量 通过GPC测量的聚乙烯的用量在100至20,000的范围内。

    Styrenic block copolymers and process for producing same
    40.
    发明授权
    Styrenic block copolymers and process for producing same 失效
    苯乙烯嵌段共聚物及其制备方法

    公开(公告)号：US5418290A

    公开(公告)日：1995-05-23

    申请号：US312759

    申请日：1994-09-27

    Applicant: Shuji Machida ,  Toshinori Tazaki ,  Noriyuki Tani

    Inventor： Shuji Machida ,  Toshinori Tazaki ,  Noriyuki Tani

    IPC: B32B27/06 ,  C08F297/06 ,  C08L25/06 ,  C08L53/00 ,  C08L53/02 ,  C08L101/00 ,  B32B27/30 ,  C08F4/76 ,  C08F297/04

    CPC classification number: C08F297/06 ,  B32B27/06 ,  C08L25/06 ,  Y10T428/31855

    Abstract: There are disclosed a styrenic block copolymer having a reduced viscosity of 0.01 to 20 dl/g (0.05 g/l in 1,2,4-trichlorobenzene at 135.degree. C.) which comprises highly syndiotactic styrenic-polymer segments and 10.sup.-4 to 10 mol % of heteroatom-containing styrenic polymer segments; a resin composition comprising the above styrenic block copolymer and a thermoplastic resin, an inorganic filler or an organic filler; a multi-layer material comprising at least one layer composed of the above styrenic block copolymer or the above resin composition; and a process for producing the above styrenic block copolymer which comprises polymerizing a styrenic monomer in the presence of a specific catalyst and adding a heteroatom-containing styrenic monomer to successively proceed with copolymerizaiton reaction. The above-disclosed styrenic block copolymer and the resin composition exhibit excellent compatibility and adhesivenesss, and the multi-layer material is expected to find a wide range of applications in automobile parts, electrical and electronic parts as well as film, sheet, etc.

    Abstract translation: 公开了一种苯乙烯嵌段共聚物，其具有0.01至20dl / g（在135℃下的1,2,4-三氯苯中为0.05g / l），其包含高度间同立构的苯乙烯 - 聚合物链段，并且10-4至 10mol％的含杂原子的苯乙烯聚合物链段; 包含上述苯乙烯嵌段共聚物和热塑性树脂，无机填料或有机填料的树脂组合物; 包括由上述苯乙烯嵌段共聚物或上述树脂组合物构成的至少一层的多层材料; 以及制备上述苯乙烯嵌段共聚物的方法，该方法包括在特定催化剂存在下使苯乙烯单体聚合并加入含杂原子的苯乙烯单体以继续进行共聚反应。 上述公开的苯乙烯嵌段共聚物和树脂组合物表现出优异的相容性和粘合性，多层材料预期在汽车部件，电气和电子部件以及薄膜，片材等方面可以广泛应用。

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