公开(公告)号：US06844398B2

公开(公告)日：2005-01-18

申请号：US10153891

申请日：2002-05-24

申请人： Haruo Shikuma ,  Shuji Machida ,  Motoharu Ishikawa ,  Shinichi Kurokawa

发明人： Haruo Shikuma ,  Shuji Machida ,  Motoharu Ishikawa ,  Shinichi Kurokawa

IPC分类号： C08F210/16 ,  C08J5/18 ,  C08L23/08 ,  C08F23/08 ,  C08F23/16

CPC分类号： C08J5/18 ,  C08F210/16 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/10 ,  C08F2500/26

摘要： An ethylenic copolymer composition including an ethylenic copolymer having Mw/Mn of 1.5 to 4, Mw of 3,000 to 1,000,000, and a resin density of 0.85 to 0.95 g/cm3. The relationship between the half width at the half maximum [W/2] of the Gaussian distribution curve, and the average, n, of short-chain branches in the copolymer satisfies the equation, 0.704+0.147n=W/2=−0.055+0.577n. The ethylenic copolymer composition also includes an ethylenic copolymer having an Mw of 3,000 to 1,000,000 and a resin density of 0.85 to 0.95 g/cm3.

摘要翻译： 包含Mw / Mn为1.5〜4，Mw为3,000〜1,000,000，树脂密度为0.85〜0.95g / cm 3的乙烯系共聚物的乙烯类共聚物组合物。 高分子分布曲线的半值宽度（W / 2）与共聚物中短链支链的平均值之间的关系满足下式：乙烯类共聚物组合物还包括具有 Mw为3,000至1,000,000，树脂密度为0.85至0.95g / cm 3。

公开(公告)号：US06441116B1

公开(公告)日：2002-08-27

申请号：US09419920

申请日：1999-10-18

申请人： Haruo Shikuma ,  Shuji Machida ,  Motoharu Ishikawa ,  Shinichi Kurokawa

发明人： Haruo Shikuma ,  Shuji Machida ,  Motoharu Ishikawa ,  Shinichi Kurokawa

IPC分类号： C08F21016

CPC分类号： C08J5/18 ,  C08F210/16 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/10 ,  C08F2500/26

摘要： A film formed of an ethylenic copolymer having Mw/Mn of 1.5 to 4, Mw of 3,000 to 1,000,000, and a resin density of 0.85 to 0.95 g/cm3. In the copolymer compositional distribution curve, the relationship between the half width at the half maximum [W/2] of the Gaussian distribution curve, and the average, n, of short-chain branches in the copolymer satisfies the equation, 0.704+0.147n≦W/2≦−0.055+0.577n. The tear strength (TS, kgf/cm) of the copolymer satisfies equations, TS≧131.5−155×log[{(B+C+D)/A}+0.1], and 0.1≦(B+C+D)/A≦1 where A is the area surrounding the Gaussian distribution curve and the base line of the compositional distribution curve; B is the area surrounding the compositional distribution curve, the curve obtained through Gaussian distribution approximation, and the base line, B being at an elution temperature higher than 32° C.; C is the area surrounding the essential peak, Gaussian distribution approximation curve, and the base line; and D is the area surrounding the compositional distribution curve and the base line and falling within an elution temperature range between 25 and 32° C. indicating a high branch component.

摘要翻译： 由Mw / Mn为1.5〜4，Mw为3,000〜1,000,000，树脂密度为0.85〜0.95g / cm 3的乙烯系共聚物形成的薄膜。 在共聚物组成分布曲线中，共聚物中的高分子量分布曲线的半值半值宽度（W / 2）与短链支链的平均值之间的关系满足下式：0.704 + 0.147n <= W / 2 <= - 0.055 + 0.577n。 共聚物的撕裂强度（TS，kgf / cm）满足等式，其中A为高斯分布曲线和组成分布曲线基线的面积。 B是围绕组成分布曲线的区域，通过高斯分布近似获得的曲线，基线B的洗脱温度高于32℃; C是围绕主要峰值的区域，高斯分布近似曲线和基线; D是围绕组成分布曲线和基线的区域，并且在25至32℃之间的洗脱温度范围内，表示高分支组分。

公开(公告)号：US5608009A

公开(公告)日：1997-03-04

申请号：US424384

申请日：1995-04-28

申请人： Shuji Machida ,  Haruo Shikuma ,  Toshinori Tazaki ,  Tomio Tatsumi ,  Shinichi Kurokawa

发明人： Shuji Machida ,  Haruo Shikuma ,  Toshinori Tazaki ,  Tomio Tatsumi ,  Shinichi Kurokawa

IPC分类号： C08F8/04 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/16 ,  C08F210/18 ,  C08F255/00 ,  C08F255/02 ,  C08F255/08 ,  C08F279/02

CPC分类号： C08F255/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/18 ,  C08F8/04 ,  C08F210/16

摘要： There are herein disclosed an olefin copolymer which comprises an olefin unit and a diolefin unit and in which a weight-average molecular weight is in the range of 200 to 800,000, the content of the diolefin unit is in the range of 0.002 to 30 mol%, and a ratio TUS/DOU between the total content of unsaturated groups observed in a molecular chain (TUS mol%) and the content of the diolefin unit (DOU mol%) is in the range of 0.001 to 200; an olefin graft copolymer obtained by the graft polymerization of this olefin copolymer and an olefin; a hydrogenated olefin copolymer and olefin graft copolymer thereof; and a process for preparing these copolymers.These olefin copolymers are excellent in molding/working properties and have a good thermal stability, transparency and uniformity. Therefore, they are useful as a high-performance VLDPE, LDPE, L-LDPE and HDPE, and further useful as a novel branched propylene polymer, a thermoplastic elastomer, a compatibilizing agent for other resins, and the like.

摘要翻译： PCT No.PCT / JP93 / 01556 Sec。 371日期：1995年4月28日 102（e）日期1995年4月28日PCT提交1993年10月28日PCT公布。 公开号WO94 / 10216 PCT 日期1994年5月11日本文公开了一种烯烃共聚物，其包含烯烃单元和二烯烃单元，其中重均分子量在200至800,000的范围内，二烯烃单元的含量在0.002 至30摩尔％，在分子链中观察到的不饱和基团的总含量（TUS摩尔％）与二烯烃单元的含量（D摩尔％）之间的比TUS / DOU在0.001〜200的范围内; 通过该烯烃共聚物和烯烃的接枝聚合得到的烯烃接枝共聚物; 氢化烯烃共聚物及其烯烃接枝共聚物; 以及这些共聚物的制备方法。 这些烯烃共聚物的成型/加工性能优异，并且具有良好的热稳定性，透明性和均匀性。 因此，它们可用作高性能VLDPE，LDPE，L-LDPE和HDPE，并且还可用作新型支化丙烯聚合物，热塑性弹性体，其它树脂的相容剂等。

公开(公告)号：US06352767B1

公开(公告)日：2002-03-05

申请号：US09319431

申请日：1999-06-07

申请人： Shinichi Kurokawa

发明人： Shinichi Kurokawa

IPC分类号： B32B1504

CPC分类号： B41M7/0027 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24893 ,  Y10T428/2848

摘要： There is provided a thermal transfer sheet which can impart excellent durability to images formed on bases, and printed objects bearing images with excellent durability. The thermal transfer sheet has a releasable protective laminate prepared by laminating a protective layer composed mainly of solvent-insoluble organic fine particles and a binder resin, and an adhesive layer in that order on at least a portion of one side of a base sheet, and the printed objects are formed by transferring the protective laminate by the thermal transfer sheet so as to cover at least a portion of an image formed on a base by a heat-sensitive sublimation transfer system.

摘要翻译： 提供了一种热转印片材，其可以赋予在基材上形成的图像优异的耐久性，以及承载具有优异耐久性的图像的印刷品。 热转印片具有通过在基片的一侧的至少一部分上依次层叠主要由溶剂不溶性有机微粒和粘合剂树脂构成的保护层和粘合剂层而制备的剥离性保护层叠体， 通过由热转印片转印保护层压体，以便通过热敏升华转印系统覆盖在基底上形成的图像的至少一部分来形成印刷对象。

公开(公告)号：US06290798B1

公开(公告)日：2001-09-18

申请号：US09268783

申请日：1999-03-16

申请人： Jiro Onishi ,  Shinichi Kurokawa ,  Katsuyuki Oshima

发明人： Jiro Onishi ,  Shinichi Kurokawa ,  Katsuyuki Oshima

IPC分类号： B44C1165

CPC分类号： B41M5/38257 ,  B41M3/12 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24802 ,  Y10T428/28

摘要： An object of the present invention is to provide a method for preparing a printed product in which a transfer layer of an intermediate transfer recording medium can be transfer via a transferring adhesive layer having a suitable adhesive property to either one of the transfer layer and a transfer-receiving material, and thus transferred images do not have turbulence. This objects can be achieved by providing, a method for forming a printed product through that a transfer layer bearing an image is transferred on a transfer-receiving material via a transferring adhesive layer, characterized in that the method comprises following steps. The first step is preparing an intermediate transfer recording medium comprising at least a base film and the transfer, and an adhesive layer transfer sheet comprising at least a substrate sheet and the transferring adhesive layer comprising at least an uppermost layer and a basement layer. And the second step is carrying out a first transfer step in which the transferring adhesive layer is transferred on the transfer layer bearing the image in advance, and a second transfer step in which the transfer layer on which the transferring adhesive layer is transferred, transfers on the transfer-receiving material.

摘要翻译： 本发明的目的是提供一种制备印刷产品的方法，其中中间转印记录介质的转印层可以经由具有适当粘合性的转印粘合剂层转印到转印层和转印层之一 接收材料，因此转印图像不会有紊乱。 该目的可以通过提供一种用于形成印刷产品的方法来实现，其中承载图像的转印层通过转印粘合剂层转印到转印接收材料上，其特征在于该方法包括以下步骤。 第一步是制备至少包含基膜和转印物的中间转印记录介质，以及至少包括基片和至少包含最上层和基底层的转印粘合剂层的粘合剂层转印片。 第二步是进行第一转印步骤，其中转印粘合剂层预先转印在承载图像的转印层上，第二转印步骤将转印粘合剂层转印的转印层转印 转印接收材料。

公开(公告)号：US5856048A

公开(公告)日：1999-01-05

申请号：US97765

申请日：1993-07-26

申请人： Shigehiko Tahara ,  Shinichi Kurokawa ,  Norio Takahashi ,  Ryuji Horiguchi ,  Morito Sakai ,  Akira Hayakawa ,  Shinpei Komaki

发明人： Shigehiko Tahara ,  Shinichi Kurokawa ,  Norio Takahashi ,  Ryuji Horiguchi ,  Morito Sakai ,  Akira Hayakawa ,  Shinpei Komaki

IPC分类号： B41M3/14 ,  B42D15/00 ,  G03H1/00 ,  G03H1/02 ,  G03H1/04 ,  G03H1/24 ,  G03H1/26 ,  G06K19/06 ,  G03H1/18

CPC分类号： B42D25/324 ,  B41M3/14 ,  B42D25/328 ,  B42D25/382 ,  B42D25/387 ,  G03H1/0011 ,  G03H1/0236 ,  G03H1/0248 ,  G03H1/0252 ,  G03H1/24 ,  G03H1/26 ,  G06K19/06046 ,  B42D2035/36 ,  B42D25/391 ,  G03H1/0244 ,  G03H1/2249 ,  G03H2001/0016 ,  G03H2001/0415 ,  G03H2001/186 ,  G03H2001/187 ,  G03H2001/2263 ,  G03H2001/2635 ,  G03H2001/264 ,  G03H2210/20 ,  G03H2210/53 ,  G03H2222/31 ,  G03H2250/10 ,  G03H2250/33 ,  G03H2250/34 ,  G03H2250/36 ,  G03H2250/40 ,  G03H2250/44

摘要： The invention is directed to an information-recorded medium with easily selectable and identifiable items of information, which is virtually protected against forgery and has enhanced security against some improper use, and a method for reading such a medium. This information-recorded medium 1 includes a substrate 2 and a layer 3 with information recorded thereon by the printing of infrared absorbing ink, said layer 3 being provided on the surface of the layer 2. The printed layer 3 is provided thereon with a relief hologram-recorded layer 7 through an adhesive layer 4, said hologram-recorded layer 7 being built up of a reflecting layer 5 transparent to the infrared region and a relief hologram-formed layer 6 provided on the surface of the reflecting layer 5. For reading, the hologram-recorded layer 7 is reconstructed by visible light, while the printed layer is reconstructed by infrared light, and the medium 1 is identified on the basis of the thus reconstructed information.

摘要翻译： 本发明涉及一种具有易于选择和可识别的信息项的信息记录介质，其几乎被保护免受伪造并具有针对某些不当使用的增强的安全性以及用于读取这种介质的方法。 该信息记录介质1包括基板2和通过印刷红外线吸收墨水而记录有信息的层3，所述层3设置在层2的表面上。印刷层3在其上设置有浮雕全息图 记录层7通过粘合剂层4，所述全息记录层7由对红外区域透明的反射层5和设置在反射层5的表面上的凸版全息图形成层6构成。为了读取， 通过可见光重构全息图记录层7，同时通过红外光重建印刷层，并且基于如此重建的信息来识别介质1。

公开(公告)号：US06890623B2

公开(公告)日：2005-05-10

申请号：US09909300

申请日：2001-07-19

申请人： Jiro Onishi ,  Shinichi Kurokawa ,  Katsuyuki Oshima

发明人： Jiro Onishi ,  Shinichi Kurokawa ,  Katsuyuki Oshima

IPC分类号： B41M3/12 ,  B41M5/382 ,  B44C1/00 ,  B44C1/165 ,  B44C1/17 ,  B41M5/38

CPC分类号： B41M5/38257 ,  B41M3/12 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24802 ,  Y10T428/28

摘要： A printed product and an accompanying method for forming the product wherein a transfer layer of an intermediate transfer recording medium can be transferred by a multi-layer transferring adhesive layer having a suitable adhesive product to either the transfer layer or a transfer-receiving material without the transferred images becoming turbulent.

摘要翻译： 一种印刷产品和用于形成产品的伴随方法，其中中间转印记录介质的转印层可以通过具有合适粘合剂产品的多层转印粘合剂层转印到转印层或转印接收材料上，而不需要 转移图像变得动荡。

公开(公告)号：US06308630B1

公开(公告)日：2001-10-30

申请号：US09423204

申请日：1999-11-03

申请人： Shinichi Kurokawa ,  Jiro Onishi ,  Katsuyuki Oshima

发明人： Shinichi Kurokawa ,  Jiro Onishi ,  Katsuyuki Oshima

IPC分类号： B41F116

CPC分类号： B41M5/44 ,  B41M3/14 ,  B41M5/38214 ,  B41M5/38257 ,  B41M7/0027 ,  B41M2205/26 ,  G03H1/0244 ,  G03H1/0272 ,  G03H2001/262 ,  G03H2210/55 ,  G03H2240/50 ,  G03H2250/10 ,  G03H2250/12 ,  G03H2250/40 ,  G03H2270/23

摘要： An intermediate transfer recording medium is comprised by providing a transfer portion having a receptor layer on a substrate film. The transfer portion is printed with the image and thereafter transferred on a surface of a transfer-receiving material. In the first aspect of the intermediate transfer recording medium, the transfer portion is provided with plural hologram patterns 21 with a hologram mark 22 allocated to each the hologram pattern. According to the first aspect of the invention, since an image is formed on the receptor layer through positioning process using the hologram mark and then the transfer portion is transferred to the surface of the transfer-receiving material, no joint of a print plate appears in the hologram pattern and accuracy of transfer is remarkably excellent. On the other hand, In the second aspect of the intermediate transfer recording medium, peeling strength required to peel the transfer portion from the substrate film at the time when transferring the transfer portion to the transfer-receiving material is controlled in the range of 10 to 150 gf/inch. According to the second aspect of the invention, any transfer failure such as tail-extension or chip of the transfer portion is not caused.

摘要翻译： 中间转印记录介质通过在基底膜上提供具有受体层的转印部分而构成。 转印部分印刷图像，然后转印在转印接收材料的表面上。 在中间转印记录介质的第一方面，转印部分设置有多个全息图图案21，全息图标记22分配给每个全息图图案。 根据本发明的第一方面，由于通过使用全息标记的定位处理在接收层上形成图像，然后将转印部分转印到转印接收材料的表面，印刷板的接头不会出现在 全息图和转印精度非常好。 另一方面，在中间转印记录介质的第二方面，将转印部分转印到转印接收材料时将转印部分从基材膜剥离所需的剥离强度控制在10至 150 gf / inch。 根据本发明的第二方面，不会导致诸如转印部分的尾部延伸或芯片之类的转印失败。

公开(公告)号：US06489266B1

公开(公告)日：2002-12-03

申请号：US09124168

申请日：1998-07-28

申请人： Shinichi Kurokawa ,  Katsuyuki Oshima

发明人： Shinichi Kurokawa ,  Katsuyuki Oshima

IPC分类号： B41M5035

CPC分类号： B41M5/502 ,  G03H1/02 ,  G03H1/0244 ,  G03H1/0248 ,  G03H1/0252 ,  G03H2250/10 ,  G03H2250/12 ,  G03H2250/36 ,  G03H2250/40 ,  G03H2270/12

摘要： There is provided an image receiving sheet which comprises: a substrate sheet, a reflection layer disposed on at least one surface side of the substrate sheet so as to be laid on at least one area thereof, and a receptor layer disposed on at least one surface side of the substrate sheet, wherein the reflection layer has at least one area provided with a convexo-concave pattern, the area provided with the convexo-concave pattern of the reflection layer being extended within an area provided with the receptor layer. The reflection layer is disposed, as required, either on the same surface side of the substrate sheet as the receptor layer is disposed so as to be interposed between the substrate sheet and the receptor layer or on the opposite side of a transparent substrate sheet to the surface provided with the receptor layer. The convexo-concave pattern may comprise an interference fringe, and may be divided into plural areas. The divided convexo-concave pattern may be composed of a single or plural kinds of pattern. The receptor layer is disposed on only one surface side of the substrate sheet, and the adhesive layer and the release sheet are disposed in this order on the other surface side, as required.

摘要翻译： 提供了一种图像接收片，其包括：基片，设置在基片的至少一个表面侧以便放置在其至少一个区域上的反射层，以及设置在至少一个表面上的接收层 其中所述反射层具有设置有凹凸图案的至少一个区域，所述设置有所述反射层的所述凹凸图案的区域在设置有所述受体层的区域内延伸。 反射层根据需要设置在衬底片的相同的表面侧上，因为接收层被设置成介于衬底片和接收层之间或者在透明衬底片的相对侧上 表面设置有受体层。 凸凹图案可以包括干涉条纹，并且可以被划分为多个区域。 分割的凹凸图案可以由单一或多种图案组成。 接收层仅设置在基板的一个表面侧，并且根据需要，粘合层和剥离片依次设置在另一个表面侧。

公开(公告)号：US06284708B1

公开(公告)日：2001-09-04

申请号：US09506190

申请日：2000-02-17

申请人： Katsuyuki Oshima ,  Shinichi Kurokawa ,  Masayasu Yamazaki

发明人： Katsuyuki Oshima ,  Shinichi Kurokawa ,  Masayasu Yamazaki

IPC分类号： B41M5035

CPC分类号： B41M7/0027 ,  B41M5/38257 ,  B41M2205/10 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/149 ,  Y10T428/1495 ,  Y10T428/15 ,  Y10T428/24802

摘要： The present invention provides an intermediate transfer recording medium which is used to form an image on a transfer-receiving member and a protective layer on the image to thereby impart durability to the image perfectly and which can simply transfer the protective layer to the image with high accuracy and also provides an image forming method. In the intermediate transfer recording medium (1) of the invention, a sheet substrate (4) provided with a resin layer (5) and a transparent sheet (2) provided with a receptor layer (3) are laminated on each other such that the resin layer (5) is peelable from the transparent sheet (2), wherein a portion of the transparent sheet (2) including the receptor layer (3) is provided with half-cut treatment (6). Using the intermediate transfer recording medium (1), a transfer image is formed on the receptor layer (3) and only the image-formed portion is retransferred to the transfer-receiving member to form an image. At this time, because a portion of the transparent sheet (2) is cut at the half-cut portion (6) as the boundary, forming a structure in which the transparent sheet (2) covers the image-formed portion and the transparent sheet functions as a uniform and strong protective layer, necessary durability is imparted perfectly to the image.

摘要翻译： 本发明提供了一种中间转印记录介质，其用于在图像上的转印接收部件和保护层上形成图像，从而赋予图像完整的耐久性，并且可以简单地将保护层转印到图像上 精度，并且还提供了图像形成方法。 在本发明的中间转印记录介质（1）中，将具有树脂层（5）的片基材（4）和设置有受体层（3）的透明片材（2）彼此层压， 树脂层（5）从透明片材（2）剥离，其中包含受体层（3）的透明片材（2）的一部分设置有半切割处理（6）。 使用中间转印记录介质（1），在受体层（3）上形成转印图像，仅将图像形成部分转印到转印接收部件上以形成图像。 此时，由于透明片材（2）的一部分作为边界在半切割部分（6）处被切割，所以形成透明片材（2）覆盖图像形成部分的结构和透明片材 作为均匀而坚固的保护层，对图像完美地赋予必要的耐久性。