公开(公告)号：US06197862B1

公开(公告)日：2001-03-06

申请号：US09029857

申请日：1998-03-16

Applicant: Michio Asano ,  Masamichi Sukegawa ,  Hirokazu Yukawa ,  Tetsuo Shimizu ,  Shoji Kawachi ,  Shingo Tanigawa

Inventor： Michio Asano ,  Masamichi Sukegawa ,  Hirokazu Yukawa ,  Tetsuo Shimizu ,  Shoji Kawachi ,  Shingo Tanigawa

IPC: C08K300

CPC classification number: C08J3/21 ,  C08J3/12 ,  C08J3/205 ,  C08J2327/18

Abstract: Filler-containing polytetrafluoroethylene granular powder, which has a large apparent density, a small average particle size and a sharp particle size distribution and a superior powder flowability, and gives a molded product having a superior tensile strength, elongation and surface roughness, and a process for preparing the same. The granular powder is prepared by granulation of a mixture of a PTFE powder and a filler in water with stirring in the presence of an organic liquid forming liquid-liquid interface with water and a nonionic surfactant.

Abstract translation: 含有填充剂的聚四氟乙烯粒状粉末，其表观密度大，平均粒径小，粒径分布小，粉末流动性优异，得到拉伸强度，伸长率和表面粗糙度优异的成型体， 为准备相同。 在与水和非离子表面活性剂形成液 - 液界面的有机液体的存在下，在搅拌下将PTFE粉末和填料的混合物制粒成粒状粉末。

公开(公告)号：US6156453A

公开(公告)日：2000-12-05

申请号：US930542

申请日：1997-10-01

Applicant: Tetsuo Shimizu ,  Yoshihide Higashihata ,  Takayuki Nakamura

Inventor： Tetsuo Shimizu ,  Yoshihide Higashihata ,  Takayuki Nakamura

IPC: C09K3/18 ,  C08L27/12 ,  C08L27/18 ,  C09D127/12 ,  C09D127/18 ,  H01M4/38 ,  H01M4/62 ,  H01M10/30 ,  H01M10/34 ,  H01M4/607

CPC classification number: H01M4/385 ,  H01M4/62 ,  H01M4/621 ,  H01M4/623 ,  H01M10/345

Abstract: To provide a water-repelling agent for batteries which comprises an aqueous dispersion or organosol containing fine particles having an average particle size of from 0.05 to 1 .mu.m and made of a tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymer and/or a non-fibril-forming tetrafluoroethylene polymer, is obtained without use of a powder of a fluorine-containing resin as it is, can enhance chemical resistance, heat resistance and water repellency particularly more effectively without being fibrillated even if mixed with electrode materials and is excellent in workability, and to provide a battery which is produced by using the water-repelling agent for batteries and is excellent in cycle life and internal pressure characteristics.

Abstract translation: PCT No.PCT / JP96 / 00953 Sec。 371日期：1997年10月1日 102（e）1997年10月1日PCT PCT 1996年4月5日PCT公布。 公开号WO96 / 32751 日本特开1996年10月17日提供一种电池用防水剂，其包含含有平均粒径为0.05〜1μm，由四氟乙烯 - 全氟（烷基乙烯基醚）共聚物构成的细颗粒的水性分散体或有机溶胶， /或非原纤维形成性四氟乙烯聚合物，而不使用含氟树脂的粉末就可以得到，即使与电极材料混合，也可以特别更有效地提高耐化学性，耐热性和拒水性，而不会原纤化 并且具有优异的可加工性，并且提供通过使用电池用防水剂制造并且循环寿命和内部压力特性优异的电池。

公开(公告)号：US5709944A

公开(公告)日：1998-01-20

申请号：US468652

申请日：1995-06-06

Applicant: Masuo Kokumai ,  Yukinaru Nakamura ,  Mitsuru Kishine ,  Tetsuo Kitahaba ,  Hirokazu Yukawa ,  Kazuhide Sawada ,  Sang Bong Han ,  Tetsuo Shimizu ,  Takahisa Aoyama

Inventor： Masuo Kokumai ,  Yukinaru Nakamura ,  Mitsuru Kishine ,  Tetsuo Kitahaba ,  Hirokazu Yukawa ,  Kazuhide Sawada ,  Sang Bong Han ,  Tetsuo Shimizu ,  Takahisa Aoyama

IPC: C08F214/26 ,  C08J3/12 ,  B32B5/16

CPC classification number: C08J3/12 ,  C08F214/262 ,  C08J2327/18 ,  Y10T428/2982

Abstract: Polytetrafluoroethylene molding powder which comprises 0.01 to 1% by weight of a perfluoro(vinyl ether) unit and which has a heat of crystallization of 18.0 to 25.0 J/g. The molding powder provides a molded article which has a flex life of not less than 7 million cycles, a creep resistance (total deformation at 200.degree. C.) of not more than 20%, and a creep resistance (total deformation at 25.degree. C.) of not more than 15%. The polytetrafluoroethylene molding powder which is excellent in both creep resistance and flex fatigue resistance is provided as a molding material for parts which are repeatedly bent such as pump.

公开(公告)号：US5494752A

公开(公告)日：1996-02-27

申请号：US193062

申请日：1994-03-08

Applicant: Tetsuo Shimizu ,  Seitaro Yamaguchi ,  Yoshihisa Yamamoto

Inventor： Tetsuo Shimizu ,  Seitaro Yamaguchi ,  Yoshihisa Yamamoto

IPC: C08F2/00 ,  C08F259/00 ,  C08F259/08 ,  C08J3/12 ,  B32B5/16 ,  C08L83/00

CPC classification number: C08J3/12 ,  C08F259/08 ,  C08J3/126 ,  C08J2327/18 ,  C08J2427/16 ,  Y10S525/902 ,  Y10T428/2998 ,  Y10T428/3154 ,  Y10T428/31544

Abstract: A composite microparticle of fluorine containing resin which is obtained by emulsion polymerization, having a core portion of a perfluoro resin which contains 80 to 100% by weight of TFE and 0 to 15% by weight of other copolymerizable fluorine containing olefin in a monomer composition, is crystalline and has a melting point of not lower than 250 C.; and a shell portion of vinylidene fluoride resin which contains 30 to 100 mole % of vinylidene fluoride and 0 to 70 mole % of other copolymerizable fluorine containing olefin (excluding hexafluoroisobutene), is crystalline and has a melting point of not lower than 70.degree. C.; the composite particle having a multilayer or gradient structure and an averaged particle size of 0.05 to 1.0 .mu.m, which is excellent in blending property with other resins or elastomers, and dispersibility in coating materials.

Abstract translation: PCT No.PCT / JP93 / 00950 Sec。 371日期：1994年3月8日 102（e）1994年3月8日PCT 1993年7月9日PCT公布。 公开号WO94 / 01475 日本1994年1月20日。一种通过乳液聚合得到的含氟树脂的复合微粒，其具有包含80〜100重量％的TFE的核心部分和0〜15重量％的其它可共聚的氟 在单体组合物中含有烯烃是结晶的，熔点不低于250℃; 含有30〜100摩尔％的偏二氟乙烯和0〜70摩尔％的其它可共聚的含氟烯烃（不包括六氟异丁烯）的偏二氟乙烯树脂的壳部分为结晶的，熔点不低于70℃。 ; 复合颗粒具有多层或梯度结构，平均粒径为0.05-1.0μm，与其它树脂或弹性体的共混性能优异，并且在涂料中的分散性。

公开(公告)号：US5160542A

公开(公告)日：1992-11-03

申请号：US580587

申请日：1990-09-11

Applicant: Hiroshi Mihira ,  Tetsuo Shimizu ,  Kazuhiro Hirahara ,  Toshinobu Ishihara ,  Seiki Takaya

Inventor： Hiroshi Mihira ,  Tetsuo Shimizu ,  Kazuhiro Hirahara ,  Toshinobu Ishihara ,  Seiki Takaya

IPC: C23C16/448 ,  C30B25/14

CPC classification number: C23C16/45561 ,  C23C16/448 ,  C23C16/4481 ,  C30B25/14

Abstract: An apparatus for vaporizing and supplying an organometal compound comprising a gas flow path for starting gas which connects a container filled with the organometal compound to a crystal growth chamber heated under reduced pressure through a main valve, a massflow controller for the starting gas and a valve for supplying the starting gas; and a flow path for a carrier gas which connects a carrier gas source to the discharge outlet of the valve for supplying the starting gas through a massflow controller for carrier gas and a heat exchanger. The container, the flow path for the starting gas and the flow path for the carrier gas are arranged in a constant temperature oven.

公开(公告)号：US5158263A

公开(公告)日：1992-10-27

申请号：US784600

申请日：1991-10-30

Applicant: Tetsuo Shimizu ,  Michinori Iwamoto

Inventor： Tetsuo Shimizu ,  Michinori Iwamoto

IPC: F16K31/06

CPC classification number: F16K31/0655 ,  F16K31/0651

Abstract: In a flow rate control valve comprising a fixed core made of a magnetic material provided with a coil arranged on a circumference thereof, a movable core and a valve body made of a magnetic material moved by an attraction by a magnetic force of said fixed core or a release from said magnetic force to open and close a valve seat and a movable member composed of a supporting spring, the fixed core is provided with a flowing conduit passing through an opening formed in a surface opposite to said movable member and the movable member is provided with a passage guiding a fluid, so that the total quantity of fluid can be smoothly flown without staying a part of the fluid.

Abstract translation: 一种流量控制阀，包括由设置有设置在其圆周上的线圈的磁性材料制成的固定芯，可动芯和由通过所述固定芯的磁力引起的吸引力移动的磁性材料制成的阀体， 从所述磁力释放以打开和关闭阀座和由支撑弹簧构成的可动构件，固定芯设置有流过导管，该导管穿过形成在与所述可动构件相对的表面的开口，并且可动构件为 设置有引导流体的通道，使得流体的总量可以平稳地流动而不停留流体的一部分。

公开(公告)号：US5108105A

公开(公告)日：1992-04-28

申请号：US641810

申请日：1991-01-16

Applicant: Tetsuo Shimizu

Inventor： Tetsuo Shimizu

IPC: A63B69/36

CPC classification number: A63B69/36 ,  A63B2220/89

Abstract: A golf practice device comprising a mat with at least two sensors arranged therein in the direction of a swing orbit of a head of a golf club. A swing time substantially from a start of a back swing to a point of an impact with a golf ball is calculated in response to signals output by the sensors, and the result is indicated so that a golfer can observe same and thus achieve a stable swing. It is possible to distinguish an address motion and an actual swing before impact by adapting a special combination of the outputs of the two sensors.

Abstract translation: 一种高尔夫球练习装置，包括具有至少两个传感器的垫，所述传感器布置在高尔夫球杆的头部的摆动轨道的方向上。 根据由传感器输出的信号，计算大体上从后摆开始到高尔夫球的冲击点的摆动时间，并且指示结果，使得高尔夫球手可以观察到相同的状况，从而实现稳定的摆动 。 通过适应两个传感器的输出的特殊组合，可以区分地震运动和冲击前的实际摆动。

公开(公告)号：US4385779A

公开(公告)日：1983-05-31

申请号：US197728

申请日：1980-10-16

Applicant: Toshimitsu Kimura ,  Tetsuo Shimizu

Inventor： Toshimitsu Kimura ,  Tetsuo Shimizu

IPC: B60R19/24 ,  B60R19/02

CPC classification number: B60R19/24

Abstract: A resilient member having preselected properties is disposed on a bolt securing an elastomeric bumper to a vehicle body bumper stay for biasing the elastomeric member against the bumper stay with a force which remains within preselected limits despite expansion and creeping of the elastomeric bumper. The hole in the bumper stay and the hole in the elastomeric bumper through which the bolt is disposed are of different diameters, or one is elongate to allow the bolt and the elastomeric bumper to move in a plane normal to the axis of the bolt.

Abstract translation: 具有预选性质的弹性构件设置在将弹性体缓冲器固定到车体保险杠撑条上的螺栓上，用于使弹性体构件抵靠保险杠撑杆以能够保持在预定极限内的力抵抗弹性体构件，尽管弹性缓冲器膨胀和蠕变。 保险杠支架中的孔和弹性缓冲器中的孔被设置成不同的直径，或者是细长的，以允许螺栓和弹性保险杠在垂直于螺栓的轴线的平面内移动。

公开(公告)号：US09127114B2

公开(公告)日：2015-09-08

申请号：US12445354

申请日：2007-10-12

Applicant: Katsuhiko Imoto ,  Tetsuo Shimizu ,  Tatsuya Morikawa ,  Masayuki Hayashi ,  Tomohiro Iimura ,  Peter Cheshire Hupfield

Inventor： Katsuhiko Imoto ,  Tetsuo Shimizu ,  Tatsuya Morikawa ,  Masayuki Hayashi ,  Tomohiro Iimura ,  Peter Cheshire Hupfield

IPC: C08G18/81 ,  C09D127/18 ,  C09D127/12 ,  C09D127/20 ,  C08G18/62 ,  C08G77/442 ,  C08L83/04 ,  C09D131/02 ,  C08G77/04 ,  C08G77/12 ,  C08K5/5419 ,  C08L27/12 ,  C08L31/02

CPC classification number: C08G18/8108 ,  C08G18/6279 ,  C08G77/045 ,  C08G77/12 ,  C08G77/442 ,  C08K5/5419 ,  C08L27/12 ,  C08L31/02 ,  C08L83/04 ,  C09D127/12 ,  C09D127/18 ,  C09D127/20 ,  C09D131/02 ,  C08L2666/04 ,  C08L2666/14

Abstract: There is provided a curable fluorine-containing polymer composition which is quickly cured at relatively low temperatures by hydrosilylation reaction and provides a coating film which has high hardness, excellent solvent resistance and flexibility. The curable fluorine-containing polymer composition comprises a fluorine-containing polymer comprising a fluorinated ethylenic monomer unit and a non-fluorinated ethylenic monomer unit, in which a part or the whole of the non-fluorinated ethylenic monomer units is a unit represented by the formula: wherein R1 is hydrogen or methyl; R2 is a hydrocarbon group having ethylenic C═C; X is —C(O)NH— or —C(O)—; R3 is —O—, —O[CH(R4)]mO—, —(CH2)mO—, —OC(O)—(CH2)mO— or —(CH2)mOC(O)—(CH2)nO—, where R4 is —H, —OH, —CH2OH or —O—X—R2, a siloxane compound having hydrogen atom bonded to silicon atom, and a catalyst for hydrosilylation reaction.

Abstract translation: 提供一种通过氢化硅烷化反应在相对低的温度下快速固化的可固化含氟聚合物组合物，并提供具有高硬度，优异的耐溶剂性和柔性的涂膜。 可固化含氟聚合物组合物包含含有氟化乙烯性单体单元和非氟化乙烯性单体单元的含氟聚合物，其中一部分或全部未氟化烯属单体单元为式 其中R1是氢或甲基; R2是具有烯属C = C的烃基; X是-C（O）NH-或-C（O） - ; R 3是-O-，-O [CH（R 4）] m O - ， - （CH 2）m O - ， - OC（O） - （CH 2）m O-或 - （CH 2）mOC（O） - （CH 2） 其中R4是-H，-OH，-CH2OH或-O-X-R2，具有与硅原子键合的氢原子的硅氧烷化合物和氢化硅烷化反应的催化剂。

公开(公告)号：US08562893B2

公开(公告)日：2013-10-22

申请号：US13284225

申请日：2011-10-28

Applicant: Masami Natsume ,  Tetsuo Shimizu ,  Tomoo Sagawa

Inventor： Masami Natsume ,  Tetsuo Shimizu ,  Tomoo Sagawa

IPC: B29C45/44

CPC classification number: B29C45/4471 ,  B29L2031/08

Abstract: A molding method for forming an impeller, includes a mold clamping process having a first mold for forming one side of blades, a second mold firmly clamped with the first mold, and a core arranged at the first mold relative to the blades, the mold clamping process clamping the first mold to the second mold in a state where the core is arranged between the first mold and the second mold, an injecting process injecting resin in a cavity obtained by the mold clamping process, and a mold removing process including the steps of releasing at least the first mold from the clamped state obtained by the mold clamping process to generate an opened portion in the first mold after the resin is hardened, rotating the core about a rotational axis toward the opened portion of the first mold, and separating the core from the resin-molded impeller.

Abstract translation: 一种用于形成叶轮的成型方法，包括：模具夹紧工艺，其具有用于形成叶片的一侧的第一模具，与第一模具牢固夹紧的第二模具和相对于叶片在第一模具处布置的芯部，模具夹紧 在芯部布置在第一模具和第二模具之间的状态下，将第一模具夹紧到第二模具中，在通过模具夹紧工艺获得的模腔中注入树脂注入工艺，以及脱模工艺，包括以下步骤： 至少将第一模具从通过合模过程获得的夹紧状态释放，以在树脂硬化之后在第一模具中产生开口部分，使芯围绕旋转轴线朝向第一模具的开口部分旋转， 芯从树脂模制叶轮。