摘要:
The present invention is directed to a rubber composition comprising: a functionalized elastomer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and a functional group bonded to the backbone chain, the functional group comprising a multidentate ligand capable of complexing with a metal ion; and a metal ion.The invention is further directed to a pneumatic tire comprising the rubber composition.
摘要:
The present invention is directed to a rubber composition comprising: a functionalized elastomer comprising a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and a functional group bonded to the backbone chain, the functional group comprising a multidentate ligand capable of complexing with a metal ion; and an encapsulated metal salt.The invention is further directed to a pneumatic runflat tire comprising a sidewall insert, the insert comprising the rubber composition.
摘要:
The present invention is directed to a method of making a graft copolymer, comprising the steps of: obtaining a first polymer comprising at least one carbon-carbon double bond, the first polymer derived from at least one monomer, the at least one monomer comprising a conjugated diene monomer; polymerizing a second monomer in the presence of a thiocarbonylthio RAFT chain transfer agent to form a polymer comprising a terminal thiocarbonylthio group; cleaving the terminal thiocarbonylthio group to a thiol group to form the second polymer comprising a terminal thiol group; reacting the second polymer with the first polymer to form a graft copolymer, the graft copolymer comprising a backbone derived from the first polymer and sidechains derived from the second polymer.
摘要:
A pneumatic tire having a tread, the tread comprising a rubber composition comprising: a copolymer comprising a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and polymeric sidechains bonded to the backbone chain, the sidechains comprising a polymer capable of exhibiting a lower critical solution temperature (LCST); optionally, at least one additional diene based elastomer; and a filler selected from the group consisting of carbon black and silica.
摘要:
The present invention is directed to a pneumatic tire comprising a component, the component comprising a rubber composition comprising a diene based elastomer and 1 to 100 phr of: A) a twin polymerization reaction product of a silyl ether; or B) a twin polymerization reaction product of a boronic acid ester; or C) a twin polymerization reaction product of a titanium compound derived from tetraethyl orthotitanate and furfuryl alcohol; or D) a twin polymerization reaction product of a tungsten compound; The invention is further directed to the corresponding rubber compositions.
摘要:
The present invention is directed to a vulcanizable rubber composition comprising: a diene based elastomer; and a compound of formula I where Q is an n-valent organic group of 1 or more carbon atoms and optionally one or more of nitrogen, oxygen, sulfur, halogen, silicon, and phosphorus atoms; X is a divalent polymer group capable of exhibiting a lower critical solution temperature; R is independently a hydrogen atom or a monovalent group of formula (II) where Z is a monovalent organic group of 1 or more carbon atoms and optionally one or more of nitrogen, oxygen, sulfur, halogen, silicon, and phosphorus atoms; and n is an integer greater than or equal to 2. The invention is further directed to a rubber composition comprising the reaction product of a diene based elastomer and a compound of formula I, and a pneumatic tire with a tread comprising the rubber composition.
摘要:
The present invention is directed to a tire comprising at least one component comprising (A) a first copolymer rubber comprised of repeat units derived from (1) 10 to 99 weight percent of a conjugated diene monomer which contains from 4 to 8 carbon atoms; (2) 0 to 70 weight percent of a vinyl substituted aromatic monomer; and (3) 1 to 20 weight percent of at least one co-monomer selected from the group consisting of the following general formulas I: wherein R represents a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms; wherein R1 represents a saturated alcohol group containing from 1 to 8 carbon atoms; and (B) a second copolymer rubber comprised of repeat units derived from (1) 10 to 99 weight percent of a conjugated diene monomer which contains from 4 to 8 carbon atoms; (2) 0 to 70 weight percent of a vinyl substituted aromatic monomer; and (3) 1 to 20 weight percent of at least one co-monomer selected from the group consisting of the following general formulas I: wherein R represents a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms; wherein R1 represents a saturated alcohol group containing from 1 to 8 carbon atoms; wherein the first and second copolymer have a difference in glass transition temperatures ranging from 30° C. to 60° C.
摘要:
The present invention is directed to a functionalized elastomer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and a functional group bonded to the backbone chain, the functional group comprising a multidentate ligand capable of complexing with a metal ion.
摘要:
The present invention is directed to a functionalized elastomer comprising: a polymeric backbone chain derived from a monomer comprising at least one conjugated diene monomer and optionally at least one vinyl aromatic monomer; and a functional group bonded to the backbone chain, the functional group comprising a multidentate ligand capable of complexing with a metal ion.