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    Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof
    32.
    发明授权
    Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof 失效
    清洁产品，包括通过亚乙烯基烯烃制备的改进的烷基芳基磺酸盐表面活性剂及其制备方法

    公开(公告)号：US06566319B1

    公开(公告)日：2003-05-20

    申请号：US09478906

    申请日：2000-01-07

    申请人： Jeffrey John Scheibel ,  Kevin Lee Kott ,  Thomas Anthony Cripe ,  Daniel Stedman Connor ,  James Charles Theophile Roger Burckett-St. Laurent

    发明人： Jeffrey John Scheibel ,  Kevin Lee Kott ,  Thomas Anthony Cripe ,  Daniel Stedman Connor ,  James Charles Theophile Roger Burckett-St. Laurent

    IPC分类号： C11D1700

    CPC分类号： C07C303/08 ,  C07C303/06 ,  C11D1/22 ,  C11D11/04 ,  C07C309/31

    摘要： Cleaning compositions, especially laundry detergents and the like, comprising (i) modified alkylarylsulfonate surfactants, e.g., modified alkylbenzenesulfonates, which are the product of particular processes and (ii) cleaning adjuncts such as enzymes and bleaches. Processes for making the cleaning products, including processes comprising vinylidene olefin production, alkylation of arenes, sulfonation and domestic cleaning product formulation. VO production is used to introduce particular limited branching into an alpha-olefinic feedstock which, converted to dimer form, has from about 10 to about 16, preferably from about 12 to about 14 carbon atoms. Preferred processes maximize the amount of vinylidene olefin useful for detergent manufacture, and minimize deep internal olefin production. Further, an alkylation step, preferably having an internal isomer selectivity of from 0 to no more than about 40 is used, in which the VO monoalkylates arenes such as benzene, in presence of an alkylation catalyst preferably comprising an at least partially crystalline, porous zeolite-containing solid, the zeolite being at least partially acidic and having intermediate pore size. Preferred alkylation catalysts include at least partially dealuminized acidic mordenites.

    摘要翻译： 清洁组合物，特别是衣物洗涤剂等，其包含（i）改性的烷基芳基磺酸盐表面活性剂，例如改性烷基苯磺酸盐，其是特定方法的产物和（ii）清洁助剂如酶和漂白剂。 用于制造清洁产品的方法，包括包含亚乙烯基烯烃生产，芳烃烷基化，磺化和家用清洁产品配方的方法。 VO生产用于将特定有限的支化物引入α-烯烃原料中，其转化为二聚体形式具有约10至约16个，优选约12至约14个碳原子。 优选的方法使用于洗涤剂制造的亚乙烯基烯烃的量最大化，并使内部烯烃的生产最小化。 此外，使用优选具有0至不大于约40的内部异构体选择性的烷基化步骤，其中在烷基化催化剂存在下，优选包含至少部分结晶的多孔沸石的VO单烷基化物芳烃如苯 所述沸石至少部分为酸性且具有中等孔径。 优选的烷基化催化剂包括至少部分脱铝的酸性丝光沸石。

    Processes for making alkylbenzenesulfonate surfactants and products thereof
    40.
    发明授权
    Processes for making alkylbenzenesulfonate surfactants and products thereof 失效
    制备烷基苯磺酸盐表面活性剂及其制品的方法

    公开(公告)号：US06602840B1

    公开(公告)日：2003-08-05

    申请号：US09478909

    申请日：2000-01-07

    申请人： Jeffrey John Scheibel ,  Kevin Lee Kott ,  Thomas Anthony Cripe ,  James Charles Theophile Roger Burckett-St. Laurent ,  Daniel Stedman Connor

    发明人： Jeffrey John Scheibel ,  Kevin Lee Kott ,  Thomas Anthony Cripe ,  James Charles Theophile Roger Burckett-St. Laurent ,  Daniel Stedman Connor

    IPC分类号： C11D1700

    CPC分类号： C11D11/04 ,  C07C303/06 ,  C07C303/08 ,  C11D1/22 ,  C07C309/31

    摘要： The present invention is in the field of processes for making alkylbenzenesulfonate surfactants. The processes herein include a combination of two essential steps, delinearization and alkylation. The delinearization step selected herein introduces particular types of limited branching into an aliphatic hydrocarbon having ten or more, but no more than about 16, carbon atoms. The hydrocarbon includes olefin having a hydrocarbon chain length suitable for detergent manufacture, e.g., C10-C14, or a corresponding paraffin. The second essential step is an alkylation step having an internal isomer selectivity of from 0 to no more than about 40 in which the hydrocarbon is used to monoalkylate benzene catalytically with an alkylation catalyst. Such alkylation catalysts preferably comprise an at least partially crystalline porous zeolite-containing solid, the zeolite having moderate acidity and intermediate pore size. Preferred alkylation catalysts include certain at least partially dealuminized acidic nonfluoridated mordenites. The processes herein further comprise sulfonating, neutralizing and incorporating the resulting modified alkylbenzenesulfonate surfactants into consumer products. The invention relates also to the products of the processes, including modified surfactants and consumer cleaning products containing them.

    摘要翻译： 本发明涉及制备烷基苯磺酸盐表面活性剂的方法领域。 本文的方法包括两个必要步骤，划线和烷基化的组合。 本文选择的描述步骤将特定类型的有限支化引入具有10个或更多个但不超过约16个碳原子的脂族烃。 烃包括具有适于洗涤剂制造的烃链长度的烯烃，例如C10-C14或相应的石蜡。 第二个关键步骤是烷基化步骤，其内部异构体选择性为0至不超过约40，其中烃用烷基化催化剂催化苯烷基化。 这种烷基化催化剂优选包括至少部分结晶的含多孔沸石的固体，沸石具有适度的酸度和中等孔径。 优选的烷基化催化剂包括某些至少部分脱铝的酸性非氟化丝光沸石。 本文的方法还包括将所得的改性烷基苯磺酸盐表面活性剂磺化，中和并并入消费品中。 本发明还涉及该方法的产品，包括改性表面活性剂和含有它们的消费者清洁产品。