Abstract:
Embodiments are directed to catalyst systems comprising at least one metal ligand complex and to processes for polyolefin polymerization incorporating the catalyst systems. The metal ligand complexes have the following structures: (I)
Abstract:
A process to functionalized organo-metal compounds with silyl-based electrophiles. The process includes combining an organo-metal compound, a silyl-based functionalization agent, and an optional solvent. Functionalized silanes and silyl-terminated polyolefins can be prepared by this process.
Abstract:
Provided is an organic light-emitting diode comprising a substrate, an anode layer, optionally one or more hole injection layers, one or more hole transport layers, optionally one or more electron blocking layers, an emitting layer, optionally one or more hole blocking layers, optionally one or more electron transport layers, an electron injection layer, and a cathode, wherein either the hole injection layer, or the hole transport layer, or both of the hole injection layer and the hole transport layer, or a layer that functions as both a hole injection layer and a hole transport layer, comprises a polymer that comprises one or more triaryl aminium radical cations having the structure (S1) wherein each of R11, R12, R13, R14, R15, R21, R22, R23, R24, R25, R31, R32, R33, R34, and R35 is independently selected from the group consisting of hydrogen, deuterium halogens, amine groups, hydroxyl groups, sulfonate groups, nitro groups, and organic groups, wherein two or more of R11, R12, R13, R14, R15, R21, R22, R23, R24, R25, R31; R32; R33 R34 and R35 are optionally connected to each other to form a ring structure; wherein one or more of R11, R12, R13, R14, R15, R21, R22, R23, R24, R25, R31, R32, R33, R34, and R35 is covalently bound to the polymer, and wherein A″ is an anion.
Abstract:
A polymer which has Mn at least 4,000 and comprises polymerized units of a compound of formula NAr1A2A3, wherein Ar1, Ar2 and Ar3 independently are C6-C40 aromatic substituents; Ar1, Ar2 and Ar3 collectively contain no more than one nitrogen atom and at least one of Ar1, Ar2 and Ar3 contains a vinyl group attached to an aromatic ring.
Abstract:
Disclosed herein is a composition comprising a host material; a fluorescent emitter, wherein the host material and the emitter are different from each other; and a codopant comprising a small molecule that has a polarity that is different from that of the host material; where the codopant modulates an energy gap of the fluorescent emitter to enhance thermally activated delayed fluorescence of the fluorescent emitter in a solid state. Disclosed herein too is a method comprising blending together a solvent, a host material, a fluorescent emitter, and a codopant, wherein the host material and the emitter are different from each other; and wherein the codopant comprising a small molecule that has a polarity that is different from that of the host material; where the codopant modulates an energy gap of the fluorescent emitter to enhance thermally activated delayed fluorescence of the fluorescent emitter in a solid state.
Abstract:
The present disclosure relates to a process for synthesizing multi- or dual-headed compositions having the formula R1MA[R2MA-]NR1 by employing a sterically hindered compound and an organometallic compound in the presence of a transition metal catalyst. The present disclosure further relates to use of the compositions, as well as the process to make the same, in olefin polymerization.
Abstract:
A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.