Abstract:
Selective catalytic reduction filter (SCRF) devices and systems incorporating the same are provided. Systems can include an exhaust gas source, an exhaust gas conduit capable of receiving an exhaust gas stream from the exhaust gas source, and an SCRF device in fluid communication therewith. The SCRF device can include a filter, a selective catalytic reduction (SCR) catalyst disposed on at least portion of the filter, and a NOx storage coating on at least a portion of the filter. The NOx storage coating can include one or more of palladium, barium, or cerium. The NOx storage coating can be biased towards the upstream side of the filter. The NOx storage coating can overlap a portion of the SCR catalyst. The system can further include a water-absorbing alkali oxide. The water-absorbing alkali oxide can be disposed within the SCRF device, the exhaust gas conduit, or in an upstream oxidation catalyst device.
Abstract:
An exhaust gas treatment device includes a housing having a wall. The wall of the housing defines an interior chamber. A substrate is supported by the housing within the interior chamber of the housing. The substrate extends along a longitudinal axis. The substrate includes a flow through structure that allows the flow of exhaust gas to flow through the substrate. The substrate includes a catalytic composition disposed thereon for reacting with the flow of exhaust gas. The substrate includes a cavity, extending along a cavity axis, which is transverse to the longitudinal axis of the substrate. A sensor is attached to the housing. The sensor includes a probe that at least partially extends into the cavity of the substrate, for sensing a gaseous component in the flow of exhaust gas. The cavity mixes the flow of exhaust gas and directs the exhaust gas toward the probe of the sensor.
Abstract:
An integrated sensor-catalyst is disclosed for an after-treatment (AT) system used to filter an exhaust gas flow emitted by an internal combustion engine. The integrated sensor-catalyst includes a sensor element configured to detect a parameter of the exhaust gas flow. The integrated sensor-catalyst also includes a micro-catalyst element configured to filter a pollutant from the exhaust gas flow. Additionally, the integrated sensor-catalyst includes a housing configured to hold the sensor element and the micro-catalyst element and fix the micro-catalyst element relative to the sensor element such that the micro-catalyst element is arranged and maintained in the exhaust gas flow upstream of the sensor element. A vehicle including such an AT system with the integrated sensor-catalyst is also disclosed.
Abstract:
A SCR device includes a substrate having a first portion, and a second portion disposed downstream of the first portion. The first portion of the substrate includes a volume that is between 15% and 25% of a total volume of the substrate. A first selective catalytic reduction compound is disposed on the first portion of the substrate, and includes an iron zeolite (Fe-Zeolite) compound. A second selective catalytic reduction compound is disposed on the second portion of the substrate, and includes a copper (Cu) SAPO-34 compound. The copper SAPO-34 compound includes a catalyst density of less than 2.74 mg copper per cubic centimeter of copper SAPO-34 compound. The copper SAPO-34 compound is applied onto the second portion of the substrate at a compound density of less than 110 g of copper SAPO-34 compound per liter of volume of the second portion of the substrate.
Abstract:
In one exemplary embodiment of the invention, a method of regenerating an exhaust gas particulate filter in a vehicle having an internal combustion engine is provided. The method includes determining a soot accumulation in the particulate filter, determining a soot humidity and temperature correction factor, and adjusting, using the soot humidity and temperature correction factor, the soot accumulation to determine a corrected soot accumulation in the particulate filter. The method further includes performing a regeneration of the particulate filter when at least one of the following occurs: the corrected soot accumulation reaches a predetermined threshold, and the corrected soot accumulation indicates a contorted soot mass to flow resistance relationship.
Abstract:
In one exemplary embodiment of the invention, a method of regenerating an exhaust gas particulate filter in a vehicle having an internal combustion engine is provided. The method includes determining a soot accumulation in the particulate filter, determining a soot humidity and temperature correction factor, and adjusting, using the soot humidity and temperature correction factor, the soot accumulation to determine a corrected soot accumulation in the particulate filter. The method further includes performing a regeneration of the particulate filter when at least one of the following occurs: the corrected soot accumulation reaches a predetermined threshold, and the corrected soot accumulation indicates a contorted soot mass to flow resistance relationship.
Abstract:
A method for estimating the amount of soot accumulated in a particulate filter of a vehicle exhaust gas system is provided. The system may include an engine, an exhaust gas system, having a particulate filter, and a controller configured to execute the present method. The controller may be configured to evaluate an instantaneous volumetric flow rate of an exhaust gas flowing through the exhaust gas system; monitor an exhaust gas pressure drop across the particulate filter; determine a drive state of the vehicle based on the instantaneous volumetric flow rate of exhaust gas and the exhaust gas pressure drop; and execute one of a first control action when the drive state is a steady-state drive state and a second control action when the drive state is a transient-state drive state.
Abstract:
A method and control apparatus is disclosed for operating an internal combustion engine equipped with an after-treatment system including a catalyst. The control is configured to: perform a DeNOx regeneration event; monitor a parameter (1up) representative of an air-to-fuel ratio upstream of the catalyst and a parameter (1down) representative of an air-to-fuel ratio downstream of the catalyst; and perform a dedicated operating phase of the internal combustion engine to achieve an increase of the NOx emissions, if the value of the parameter (1down) representative of an air-to-fuel ratio downstream of the catalyst is lower than the value of the parameter (1up) representative of an air-to-fuel ratio upstream of the catalyst.
Abstract:
Internal combustion engine (ICE) exhaust gas treatment systems include the ICE having one or more cylinders configured to receive a mixture of air and fuel defined by an air to fuel ratio (AFR) for combustion therein, a control module configured to control the AFR, a diesel oxidation catalyst (DOC) configured to receive exhaust gas generated by the ICE and oxidize NOx species within the exhaust gas, and a selective catalytic reduction device (SCR) configured to receive exhaust gas from the DOC. Methods for operating and diagnosing such systems include determining, via the control module, a baseline value of a SCR performance parameter which is unsuitable, changing, via the control module, the AFR to change the DOC outlet NO2:NOx ratio, subsequently assessing a second value of the SCR performance parameter, and implementing a control action based on the second value of the SCR performance parameter.
Abstract:
Described herein is a desulfurization method for desulfurizing a SCR device treating an exhaust gas. The desulfurization method includes injecting a reductant into the exhaust gas upstream from or into the SCR device and increasing a temperature of the exhaust gas.