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57 条记录 (耗时 0.034 秒)

    Method of Forming a Carbon-Heteroatom Bond
    31.
    发明申请
    Method of Forming a Carbon-Heteroatom Bond 失效
    形成碳杂原子键的方法

    公开(公告)号：US20070243999A1

    公开(公告)日：2007-10-18

    申请号：US10556849

    申请日：2004-05-12

    申请人： Christelle Mauger ,  Gerard Mignani

    发明人： Christelle Mauger ,  Gerard Mignani

    IPC分类号： B01J21/00

    CPC分类号： C07C249/16 ,  C07C251/86

    摘要： The present invention relates to a method of creating a carbon-heteroatom bond, and preferably a carbon-nitrogen bond, by reacting a leaving group-bearing unsaturated compound and a nucleophilic compound. In particular, the invention relates to the creation of a carbon-nitrogen bond, using a method involving the arylation of nitrogenous organic derivatives; the inventive method consists in creating a carbon-heteroatom bond by reacting a leaving group-bearing unsaturated compound and a nucleophilic compound introducing a heteroatom which can be substituted for the leaving group, thereby creating a carbon-heteroatom bond, in the presence of a palladium-based catalyst, optionally a ligand. The invention is characterized in that the reaction takes place in the presence of an effective quantity of a metal hydroxide or ammonium hydroxide which is associated with an alcohol-type solvent.

    摘要翻译： 本发明涉及通过使含离去基团的不饱和化合物与亲核性化合物反应而产生碳 - 杂原子键，优选碳 - 氮键的方法。 特别地，本发明涉及使用涉及含氮有机衍生物的芳基化的方法产生碳 - 氮键; 本发明的方法包括通过使带有离去基团的不饱和化合物和引入可被取代离去基团的杂原子的亲核化合物反应产生碳 - 杂原子键，从而在钯的存在下产生碳 - 杂原子键 的催化剂，任选的配体。 本发明的特征在于反应在有效量的与醇型溶剂相关的金属氢氧化物或氢氧化铵存在下进行。

    Method for preparing functionalised polyorganosiloxane resins by redistribution in the presence of at least one triflic acid derivative
    32.
    发明申请
    Method for preparing functionalised polyorganosiloxane resins by redistribution in the presence of at least one triflic acid derivative 失效
    通过在至少一种三氟酸衍生物存在下再分配制备官能化聚有机硅氧烷树脂的方法

    公开(公告)号：US20050239987A1

    公开(公告)日：2005-10-27

    申请号：US10509071

    申请日：2003-03-20

    申请人： Fernande Boisson ,  Gerard Mignani

    发明人： Fernande Boisson ,  Gerard Mignani

    IPC分类号： C08G77/08 ,  C08G77/10

    CPC分类号： C08G77/08 ,  C08G77/10

    摘要： The present invention relates to a process for preparing functionalized polyorganosiloxane (POS) resins comprising units M: (R3SiO1/2), Q: (SiO4/2) and M′: (YaR3-aSiO1/2) and optionally D: (R2SiO2/2) and/or D′: (RYSiO2/2) and T: (RSiO3/2) and/or T′: (YSiO3/2), with, in these units: R=C1-C10 alkyl or a C8-C12 aryl and Y a functional group (e.g.: Si—H), by redistribution of POS resins using POSf bearing functional units M′ and/or D′ and/or in the presence of an acid catalyst of the trifluoromethane-sulfonimide (TFSI) type. The present invention also relates to the aforementioned catalyst system.

    摘要翻译： 本发明涉及一种制备官能化聚有机硅氧烷（POS）树脂的方法，其包括单元M：（R 3 SiO 1/2），Q：（SiO 4） / 2）和M'：（Y a a R 3-a SiO 1/2）和任选的D：（R 和/或D'：（RYSiO 2/2/2）和T：（RSiO 3/2/2） 和/或T'：（YSiO 3/2/2），在这些单元中：R = C 1 -C 10 - 通过使用POSf承载官能单元M'将POS树脂重新分配，通过重新分配POS树脂，以及Y为官能团（例如：Si-H） 和/或D'和/或在三氟甲烷 - 磺酰亚胺（TFSI）型的酸催化剂存在下进行。 本发明还涉及上述催化剂体系。

    Method for preparing a regenerated cellulose fibre or yarn
    33.
    发明授权
    Method for preparing a regenerated cellulose fibre or yarn 失效
    制备再生纤维素纤维或纱线的方法

    公开(公告)号：US06555678B1

    公开(公告)日：2003-04-29

    申请号：US09530188

    申请日：2000-09-25

    申请人： Christian Allandrieu ,  Lucile Gambut ,  Philippe Karrer ,  Ties Karstens ,  Gerard Mignani ,  Armin Stein

    发明人： Christian Allandrieu ,  Lucile Gambut ,  Philippe Karrer ,  Ties Karstens ,  Gerard Mignani ,  Armin Stein

    IPC分类号： C08B1600

    CPC分类号： D01F2/24 ,  D01F2/00

    摘要： A method has been developed for making regenerated cellulose yarn. The method includes the steps of spinning a solution derived from cellulose or a cellulose derivative in a molten state through at least one extrusion die, then regenerating the cellulose by treating the resulting yarn, wherein a silylated cellulose derivative is prepared by reaction with a silylating agent; the silylated cellulose is extracted from the synthesis reaction medium; then spun through at least an extrusion die; and the resultant yarn treated with a desilylation agent to regenerate the cellulose and a siloxane. The resulting cellulose yarns or fibers may be used for making woven or knitted textile surfaces or non-woven surfaces. Said yarns or fibers are also useful as reinforcing fibers in elastomeric materials and more particularly, in tires.

    摘要翻译： 已经开发了用于制备再生纤维素纱线的方法。 该方法包括以下步骤：通过至少一个挤出模头将来自纤维素或纤维素衍生物的溶液通过至少一个挤出模头纺丝，然后通过处理所得纱线再生纤维素，其中通过与甲硅烷基化试剂反应制备甲硅烷基化纤维素衍生物 ; 从合成反应介质中提取甲硅烷基化纤维素; 然后通过至少一个挤出模头旋转; 用脱甲基剂处理得到的纱线再生纤维素和硅氧烷。 所得到的纤维素纱线或纤维可用于制造机织或针织织物表面或无纺织物表面。 所述纱线或纤维也可用作弹性体材料中的增强纤维，更具体地，在轮胎中。

    Method for preparing polyorganosiloxanes (POS) with thiol functions, POS obtainable by this method and their use particularly in rubber materials
    34.
    发明授权
    Method for preparing polyorganosiloxanes (POS) with thiol functions, POS obtainable by this method and their use particularly in rubber materials 失效
    制备具有硫醇官能团的聚有机硅氧烷（POS）的方法，该方法可通过该方法得到并且特别用于橡胶材料中

    公开(公告)号：US06372843B1

    公开(公告)日：2002-04-16

    申请号：US09462565

    申请日：2000-04-19

    申请人： Pierre Barruel ,  Yves Bomal ,  Nathalie Guennouni ,  Gerard Mignani ,  Christian Priou

    发明人： Pierre Barruel ,  Yves Bomal ,  Nathalie Guennouni ,  Gerard Mignani ,  Christian Priou

    IPC分类号： C08L8308

    CPC分类号： C08K3/36 ,  C08G77/392 ,  C08L7/00 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L83/08 ,  C08L2205/03 ,  C08L2666/14

    摘要： The present invention relates to a process for preparing multifunctionalized polyorganosiloxanes (POSs) comprising alkoxyl functional siloxyl units and siloxyl units each having an SH functional group, which consists in introducing the SH functional group by the reaction of H2S on a precursor POS of formula: A—(RXSiO)a—(RYSiO)b—B where R is especially a C1-C6 alkyl radical, X is a C1-C15 alkoxyl radical, Y is a C2-C30 hydrocarbon group which includes an ethylenically unsaturated group from which the SH functionality derives, a is a number ranging from 1 to 150, b is a number ranging from 1 to 150, the number a+b ranging from 2 to 300 and A and B are terminal groups which are selected respectively, from, in particular, on the one hand (R)3SiO— radicals taken alone or as mixtures with (R)2XSiO— and/or R(X)2SiO— and/or (X)3SiO— radicals and on the other hand —Si(R)3 radicals taken alone or as mixtures with —SiX(R)2 and/or —Si(X)2R and/or —Si(X)3 radicals.

    摘要翻译： 本发明涉及一种制备多官能化聚有机基硅氧烷（POSs）的方法，该多官能化聚有机硅氧烷（POSs）包含烷氧基官能硅氧烷单元和含有SH官能团的甲硅烷氧基单元，其包括通过H 2 S在式A的前体POS上反应引入SH官能团 - （RXSiO）a-（RYSiO）bB其中R特别是C 1 -C 6烷基，X是C 1 -C 15烷氧基，Y是C 2 -C 30烃基，其包括具有SH官能度的烯属不饱和基团 a为1〜150的数，b为1〜150的数，a + b的数量为2〜300，A，B为分别选择的端子组，特别是 单独（R）3SiO-基单独或与（R）2 XSiO-和/或R（X）2SiO-和/或（X）3SiO-基团的混合物，另一方面-Si（R）3基团取代 单独或作为与-SiX（R）2和/或-Si（X）2R和/或-Si（X）3基团的混合物）。

    Process for the continuous bulk production of acrylic polymers
    37.
    发明授权
    Process for the continuous bulk production of acrylic polymers 失效
    连续批量生产丙烯酸聚合物的方法

    公开(公告)号：US5243097A

    公开(公告)日：1993-09-07

    申请号：US979344

    申请日：1992-11-20

    申请人： Gerard Mignani ,  Didier Morel

    发明人： Gerard Mignani ,  Didier Morel

    IPC分类号： C07C2/86 ,  C07C29/32 ,  C07C33/042 ,  C07C33/048 ,  C07C33/14 ,  C07C35/08 ,  C07C35/17 ,  C07C41/48 ,  C07C43/315 ,  C07C45/67 ,  C07C45/68 ,  C07C49/24

    CPC分类号： C07C403/02 ,  C07C2/861 ,  C07C29/32 ,  C07C33/042 ,  C07C33/048 ,  C07C33/14 ,  C07C35/08 ,  C07C35/17 ,  C07C403/08 ,  C07C41/48 ,  C07C45/673 ,  C07C45/68 ,  C07C49/24 ,  C07C2101/14 ,  C07C2101/16

    摘要： Acetylenic derivatives of general formula ##STR1## in which R.sub.1 denotes a hydrogen atom or a phenyl radical or a radical of general formula ##STR2## in which R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom or a saturated or unsaturated aliphatic radical, substituted if appropriate, or form together a cycloaliphatic radical, R.sub.4 denotes a hydrogen atom or a saturated or unsaturated aliphatic radical, a hydroxy, alkyloxy, methanesulphonyloxy, benzenesulpnonyloxy or p-toluenesulphonyloxy radical, R.sub.5 denotes a hydrogen atom or a saturated aliphatic radical, R.sub.6 denotes a hydrogen atom or a saturated or unsaturated aliphatic radical are made by reaction of an acetylenic derivative of general formulaR.sub.1 --C.tbd.C--H (III)with an allyl derivative of general formula ##STR3## in the presence of a cuprous salt and an anhydrous organic base. The compounds of formula (I) are useful in organic synthesis, in particular in the preparation of the vitamins A and E.

    摘要翻译： 其中R 1表示氢原子或苯基或通式为（II）的基团，其中R 2和R 3可以相同或不同，表示氢原子的通式（ⅩⅧ）（Ⅰ）的乙炔衍生物 羟基，烷氧基，甲磺酰氧基，苯磺酰氧基或对甲苯磺酰氧基，R5表示氢原子或饱和或不饱和脂肪族基团， 氢原子或饱和脂肪族基团，R6表示氢原子或饱和或不饱和脂肪族基团，通过将通式R 1 -C 3 3BOND CH（III）的炔属衍生物与通式为“IMAGE”的烯丙基衍生物 IV）或（VI）化合物在乙酸盐和无水有机碱的存在下反应。 式（I）化合物可用于有机合成，特别是维生素A和E的制备。