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公开(公告)号:US20120292501A1
公开(公告)日:2012-11-22
申请号:US13574788
申请日:2011-01-21
IPC分类号: H01J49/12
CPC分类号: H01J49/105 , H01J27/16 , H05H1/2406 , H05H2001/2443
摘要: A mass spectrometer of ionizing a sample by a dielectric barrier discharge under a reduced pressure. An ionization with inconsiderable fragmentation can be carried out highly sensitively by the present invention.
摘要翻译: 一种质谱仪,其通过介电阻挡放电在减压下离子化样品。 通过本发明可以高度敏感地进行具有不可忽视的碎裂的电离。
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公开(公告)号:US20080116372A1
公开(公告)日:2008-05-22
申请号:US11745516
申请日:2007-05-08
IPC分类号: H01J49/42
CPC分类号: H01J49/4225 , H01J49/429
摘要: A linear trap having high ejection efficiency and low ejection energy is realized. In a mass spectrometer in which ion generated by an ion source are introduced to a quadrupole rod structure applied with RF voltage and ejected from the quadrupole rod structure so as to be detected by a detection mechanism, a mass dependent potential is formed in the axial direction of the quadrupole rod structure and ions are ejected mass selectively from the vicinity of a minimum point of the potential, the mass dependent potential being formed by applying electrostatic voltage and RF voltage to an insertion electrode inserted in the quadrupole rods.
摘要翻译: 实现了具有高喷射效率和低喷射能量的线性阱。 在质谱仪中,将由离子源产生的离子引入施加有RF电压的四极杆结构并从四极棒结构喷出以便通过检测机构检测,质量依赖电位在轴向上形成 的四极杆结构和离子从电位的最小点附近选择性地排出,质量依赖电位通过将静电电压和RF电压施加到插入四极棒中的插入电极而形成。
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公开(公告)号:US20080156979A1
公开(公告)日:2008-07-03
申请号:US12010977
申请日:2008-01-31
IPC分类号: B01D59/44
CPC分类号: H01J49/4225 , H01J49/004 , H01J49/4265
摘要: Amass spectrometer includes: an ion source for ionizing a specimen to generate ions, an ion transport portion for transporting the ions, a linear ion trap portion for accumulating the transported ions by a potential formed axially, and a control portion of ejecting the ions within a second m/z range different from a first m/z range, from the linear ion trap portion, and substantially at the same timing as the timing of accumulating the ions within the first m/z range from the transport portion into the linear ion trap portion. The ion transportation portion having a mass selection means for selecting the ions in the first m/z range.
摘要翻译: 阿马斯光谱仪包括:用于电离样品以产生离子的离子源,用于输送离子的离子传输部分,用于通过轴向形成的电势积聚所运送的离子的线性离子捕获部分,以及将离子喷射到 第二m / z范围与第一m / z范围不同于线性离子阱部分,并且基本上与从运输部分到线性离子阱的第一m / z范围内积聚离子的定时基本相同 一部分。 该离子传送部分具有用于选择第一m / z范围内的离子的质量选择装置。
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公开(公告)号:US09302271B2
公开(公告)日:2016-04-05
申请号:US14411217
申请日:2012-07-04
IPC分类号: H01J49/02 , B03C7/02 , G01N27/62 , G01N27/447 , B03C3/017 , B03C3/08 , B03C3/12 , B03C3/41 , B03C3/47 , B03C3/68
CPC分类号: B03C7/02 , B03C3/017 , B03C3/08 , B03C3/12 , B03C3/41 , B03C3/47 , B03C3/68 , G01N27/447 , G01N27/624
摘要: In an ion mobility separation device, there are problems that while arraying of separation electrodes and flow paths is restricted, time required for scanning correction voltages becomes longer and the throughput is reduced when the correction voltages are set in detail. These problems are solved for example by the following means. Namely, an ion mobility separation device characterized in that: at least one of a pair of plate electrodes has a first electrode section having a first conductivity, a second electrode section having a second conductivity, and a third electrode section interposed between the first electrode section and the second electrode section, wherein the third electrode section has a third conductivity smaller than the first conductivity and the second conductivity; the first electrode section, the second electrode section and the third electrode section are aligned in a direction perpendicular to a flow path; and a voltage controller applies different direct-current voltages to the first electrode section and the second electrode section.
摘要翻译: 在离子迁移率分离装置中,存在限制分离电极和流路的排列的问题,当校正电压被详细设定时,扫描校正电压所需的时间变长,吞吐量降低。 这些问题通过以下方式得到解决。 也就是说,一种离子迁移率分离装置,其特征在于:一对平板电极中的至少一个具有具有第一导电性的第一电极部分,具有第二导电性的第二电极部分和介于第一电极部分之间的第三电极部分 和所述第二电极部,其中,所述第三电极部具有小于所述第一导电性和所述第二导电性的第三导电性; 第一电极部分,第二电极部分和第三电极部分在垂直于流路的方向上排列; 并且电压控制器对第一电极部分和第二电极部分施加不同的直流电压。
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公开(公告)号:US20150190815A1
公开(公告)日:2015-07-09
申请号:US14411217
申请日:2012-07-04
IPC分类号: B03C7/02 , G01N27/447
CPC分类号: B03C7/02 , B03C3/017 , B03C3/08 , B03C3/12 , B03C3/41 , B03C3/47 , B03C3/68 , G01N27/447 , G01N27/624
摘要: In an ion mobility separation device, there are problems that while arraying of separation electrodes and flow paths is restricted, time required for scanning correction voltages becomes longer and the throughput is reduced when the correction voltages are set in detail. These problems are solved for example by the following means. Namely, an ion mobility separation device characterized in that: at least one of a pair of plate electrodes has a first electrode section having a first conductivity, a second electrode section having a second conductivity, and a third electrode section interposed between the first electrode section and the second electrode section, wherein the third electrode section has a third conductivity smaller than the first conductivity and the second conductivity; the first electrode section, the second electrode section and the third electrode section are aligned in a direction perpendicular to a flow path; and a voltage controller applies different direct-current voltages to the first electrode section and the second electrode section.
摘要翻译: 在离子迁移率分离装置中,存在限制分离电极和流路的排列的问题,当校正电压被详细设定时,扫描校正电压所需的时间变长,吞吐量降低。 这些问题通过以下方式得到解决。 也就是说,一种离子迁移率分离装置,其特征在于:一对平板电极中的至少一个具有具有第一导电性的第一电极部分,具有第二导电性的第二电极部分和介于第一电极部分之间的第三电极部分 和所述第二电极部,其中,所述第三电极部具有小于所述第一导电性和所述第二导电性的第三导电性; 第一电极部分,第二电极部分和第三电极部分在垂直于流路的方向上排列; 并且电压控制器对第一电极部分和第二电极部分施加不同的直流电压。
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公开(公告)号:US09377445B2
公开(公告)日:2016-06-28
申请号:US14383607
申请日:2012-08-27
申请人: Hiroyuki Satake , Hideki Hasegawa , Yuichiro Hashimoto , Masao Suga , Izumi Waki
发明人: Hiroyuki Satake , Hideki Hasegawa , Yuichiro Hashimoto , Masao Suga , Izumi Waki
CPC分类号: G01N30/7266 , G01N27/62 , G01N30/7233 , H01J49/0409 , H01J49/0445 , H01J49/165
摘要: In order to achieve an ionization method of high robustness with a small carry-over or less crosstalk, an ionization method is disclosed. A method includes the steps of: joining an ionization unit to a tube; sucking the sample from a sample container into a sample holder of the ionization unit to hold the sample; moving the ionization unit holding the sample to near the ionization unit using an ionization unit drive unit; and applying a voltage to the ionization unit using a power supply to ionize the sample by electrostatically spraying the sample from the holding unit.
摘要翻译: 为了实现具有小的遗留或较少串扰的高鲁棒性的电离方法,公开了电离方法。 一种方法包括以下步骤:将电离单元连接到管上; 将样品从样品容器吸入电离单元的样品保持器中以保持样品; 使用电离单元驱动单元将保持样品的电离单元移动到离子化单元附近; 以及使用电源向所述电离单元施加电压以通过从所述保持单元静电喷射所述样品来使样品电离。
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公开(公告)号:US07569814B2
公开(公告)日:2009-08-04
申请号:US12010977
申请日:2008-01-31
IPC分类号: H01J49/00
CPC分类号: H01J49/4225 , H01J49/004 , H01J49/4265
摘要: A mass spectrometer includes: an ion source for ionizing a specimen to generate ions, an ion transport portion for transporting the ions, a linear ion trap portion for accumulating the transported ions by a potential formed axially, and a control portion of ejecting the ions within a second m/z range different from a first m/z range, from the linear ion trap portion, and substantially at the same timing as the timing of accumulating the ions within the first m/z range from the transport portion into the linear ion trap portion. The ion transportation portion having a mass selection means for selecting the ions in the first m/z range.
摘要翻译: 质谱仪包括:离子源,用于离子化样品以产生离子;离子传输部分,用于输送离子;线性离子捕获部分,用于通过轴向形成的电位积聚所运送的离子;以及控制部分, 与线性离子阱部分不同于第一m / z范围的第二m / z范围,并且基本上与从运输部分到线性离子的离子在第一m / z范围内的积累时间基本相同的时刻 陷阱部分。 该离子传送部分具有用于选择第一m / z范围内的离子的质量选择装置。
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公开(公告)号:US07348554B2
公开(公告)日:2008-03-25
申请号:US11146157
申请日:2005-06-07
CPC分类号: H01J49/4225 , H01J49/004 , H01J49/4265
摘要: A mass spectrometer includes: an ion source for ionizing a specimen to generate ions, an ion transport portion for transporting the ions, a linear ion trap portion for accumulating the transported ions by a potential formed axially, and a control portion of ejecting the ions within a second m/z range different from a first m/z range, from the linear ion trap portion, and substantially at the same timing as the timing of accumulating the ions within the first m/z range from the transport portion into the linear ion trap portion. The ion transportation portion having a mass selection means for selecting the ions in the first m/z range.
摘要翻译: 质谱仪包括:离子源,用于离子化样品以产生离子;离子传输部分,用于输送离子;线性离子捕获部分,用于通过轴向形成的电位积聚所运送的离子;以及控制部分, 与线性离子阱部分不同于第一m / z范围的第二m / z范围,并且基本上与从运输部分到线性离子的离子在第一m / z范围内的积累时间基本相同的时刻 陷阱部分。 该离子传送部分具有用于选择第一m / z范围内的离子的质量选择装置。
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公开(公告)号:US20050269504A1
公开(公告)日:2005-12-08
申请号:US11146157
申请日:2005-06-07
CPC分类号: H01J49/4225 , H01J49/004 , H01J49/4265
摘要: A mass spectrometer using a linear ion trap capable of efficiently suppressing the space charge and enabling scanning for a wide m/z range at a high Duty Cycle is provided. The mass spectrometer comprises: an ion source for ionizing a specimen to generate ions, an ion transport portion for transporting the ions, a linear ion trap portion for accumulating the transported ions by a potential formed axially, and a control portion of ejecting the ions within a second m/z range different from a first m/z range from the linear ion trap portion substantially at the same timing as the timing of accumulating the ions within the first m/z range to the linear ion trap portion, in which the control portion conducts control of ejecting the ions mass selectively from the linear ion trap portion by any of voltage application of (1) applying a supplemental AC voltage between at least a pair of linear ion trap rods constituting the linear ion trap portion, (2) applying a supplemental AC voltage to an end lens constituting the linear ion trap portion, and (3) applying a supplemental AC voltage between inserted lenses, the inserted lenses constituting the linear ion trap portion. The ion transportation portion having a mass selection means for selecting the ions in the first m/z range.
摘要翻译: 提供了使用能够有效地抑制空间电荷且能够在高占空比下扫描宽m / z范围的线性离子阱的质谱仪。 该质谱仪包括:用于离子化离子的离子源,用于输送离子的离子传输部分,用于通过轴向形成的电势积聚运送的离子的线性离子捕获部分,以及将离子排出的控制部分 基本上与在线性离子阱部分内将离子累积到第一m / z范围内的时刻相同的定时,与线性离子阱部分的第一m / z范围不同的第二m / z范围,其中控制 通过施加(1)在构成线性离子阱部分的至少一对线性离子阱捕获棒之间施加补充AC电压的任何电压施加(2)施加的线性离子阱部分, 构成线性离子阱部分的端部透镜的补充AC电压,以及(3)在插入的透镜之间施加补充AC电压,构成线性离子阱po的插入透镜 rtion。 该离子传送部分具有用于选择第一m / z范围内的离子的质量选择装置。
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公开(公告)号:US20140151543A1
公开(公告)日:2014-06-05
申请号:US13884755
申请日:2011-11-08
申请人: Hisashi Nagano , Yasutaka Suzuki , Hideo Kashima , Yuichiro Hashimoto , Masuyuki Sugiyama , Masakazu Sugaya , Yasunori Doi , Koichi Terada
发明人: Hisashi Nagano , Yasutaka Suzuki , Hideo Kashima , Yuichiro Hashimoto , Masuyuki Sugiyama , Masakazu Sugaya , Yasunori Doi , Koichi Terada
CPC分类号: H01J49/0422 , G01N1/2211 , G01N1/2214 , G01N33/0057 , G01N2001/028 , H01J49/00 , H01J49/0036 , H01J49/04 , H01J49/0459 , H01J49/0468 , Y02A50/25
摘要: Provided is a technique of analyzing particles in real time while collecting and condensing the particles continuously. Gas and/or particles as a detection target substance that are attached to an authentication target 2 are removed by air flow from a blowing region 5. The removed sample is sucked and is condensed and sampled at a sampling region 10, and ions of the sample are generated at an ion source 21 and are then subjected to mass analysis at a mass analysis region 23. Determination of the obtained mass spectrum is made as to the presence or not of a mass spectrum derived from the detection target substance, and a monitor 27 displays a result thereof. Thereby, the detection target substance attached to the authentication target 2 can be detected continuously in real time, promptly and with a less error rate.
摘要翻译: 提供了一种在连续收集和冷凝颗粒时实时分析颗粒的技术。 作为检测对象物质的作为检测对象物质的气体和/或颗粒被从吹扫区域5的空气流除去。将取出的样品抽吸并在采样区域10被冷凝并取样,并且样品的离子 在离子源21处产生,然后在质量分析区域23进行质量分析。对获得的质谱进行测定,确定是否存在从检测目标物质得到的质谱,以及监测器27 显示其结果。 因此,可以实时,及时且误码率较小的连续检测附着于认证对象2的检测对象物质。
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