Photoresist polymeric compound and photoresist resin composition
    31.
    发明授权
    Photoresist polymeric compound and photoresist resin composition 有权
    光阻聚合物和光致抗蚀剂树脂组合物

    公开(公告)号:US06692889B1

    公开(公告)日:2004-02-17

    申请号:US09806857

    申请日:2001-04-05

    Abstract: A polymeric compound of the invention includes at least one monomer unit selected from the following formulae (I), (II), (III) and (IV): (wherein R1 is a hydrogen atom or a methyl group, R2 and R3 are each a hydrogen atom, a hydroxyl group or a —COOR4 group, where R4 is, e.g., a t-butyl group or a 2-tetrahydropyranyl group; R5 and R6 are each a hydrogen atom, a hydroxyl group or an oxo group; R7, R8 and R9 are each a hydrogen atom or a methyl group; R10 and R11 are each a hydrocarbon group having 1 to 8 carbon atoms; R12, R13 and R14 are each a hydrogen atom, a hydroxyl group or a methyl group, where if all of R12 to R14 are each a hydrogen atom or a hydroxyl group, R10 and R11 are not coincidentally methyl groups) [wherein, when the compound includes, for example, a monomer unit of Formula (III), the compound further includes at least one monomer unit selected from among, for example, a monomer unit represented by the following Formula (V): (wherein R15 and R16 are each a hydrogen atom, a hydroxyl group or a carboxyl group; R17 is a hydroxyl group, an oxo group or a carboxyl group; and R1 has the same meaning as defined above)]. This polymeric compound has high etching resistance, as well as satisfactory transparency, alkali-solubility and adhesion, and is therefore useful as a photoresist resin.

    Abstract translation: 本发明的高分子化合物包括至少一种选自下式(I),(II),(III)和(IV)的单体单元:(其中R 1是氢原子或甲基, 2>和R 3各自为氢原子,羟基或-COOR 4基团,其中R 4为例如叔丁基或2-四氢吡喃基; R 5为氢原子, R 6和R 6各自为氢原子,羟基或氧代基; R 7,R 8和R 9各自为氢原子或甲基; R 10和R 8为氢原子, 11>各自为具有1至8个碳原子的烃基; R 12,R 13和R 14各自为氢原子,羟基或甲基,其中如果全部R 12, 至R 14各自为氢原子或羟基,R 10和R 11不是甲基),其中,当该化合物包括例如式(III)的单体单元时, 该化合物还包括至少一种单体单元,其选自例如由下式(V)表示的单体单元:(其中 R 15和R 16各自为氢原子,羟基或羧基; R 17是羟基,氧代基或羧基; 和R 1具有与上述相同的含义]]。 该高分子化合物具有高耐蚀刻性,以及令人满意的透明度,碱溶性和粘附性,因此可用作光致抗蚀剂树脂。

    Adamantane derivatives and processes for the preparation thereof
    32.
    发明授权
    Adamantane derivatives and processes for the preparation thereof 失效
    金刚烷衍生物及其制备方法

    公开(公告)号:US06670499B1

    公开(公告)日:2003-12-30

    申请号:US09869858

    申请日:2001-07-06

    Abstract: Adamantane derivatives in which two (meth)acryloyloxyalkyl groups are bonded with an adamantane ring through ester groups, adamantane derivatives in which two adamantane rings are bonded through an alkylene group and two urethane bonds, which two adamantane rings each have a (meth)acryloyloxy group bonded thereto directly or through a coupling group, and adamantane derivatives each having a structure in which a group containing an adamantane ring hangs on the alkylene group of an alkylene glycol di(meth)acrylate. The compounds are useful as dental materials intermediates therefor, and as intermediates for optical materials such as lenses.

    Abstract translation: 其中两个(甲基)丙烯酰氧基烷基通过酯基与金刚烷环键合的金刚烷衍生物,其中两个金刚烷环通过亚烷基和两个氨基甲酸酯键结合的金刚烷衍生物,这两个金刚烷环各自具有(甲基)丙烯酰氧基 以及金刚烷衍生物各自具有其中含有金刚烷环的基团悬挂在亚烷基二醇二(甲基)丙烯酸酯的亚烷基上的结构。 这些化合物可用作牙科材料的中间体,以及作为光学材料如透镜的中间体。

    Process for producing t-butyl esters of bridged-ring polycarboxylic acids
    33.
    发明授权
    Process for producing t-butyl esters of bridged-ring polycarboxylic acids 失效
    制备桥环多元羧酸的叔丁酯的方法

    公开(公告)号:US06515165B1

    公开(公告)日:2003-02-04

    申请号:US09889882

    申请日:2001-07-24

    Abstract: In a process of the present invention for producing a bridged cyclic polycarboxylic acid t-butyl ester, a bridged cyclic polycarboxylic halide of following Formula (1): (wherein ring Z is a bridged cyclic carbon ring; X is a halogen atom; and m denotes an integer of 2 or more, where ring Z may have a substituent) is allowed to react with t-butyl alcohol or its alkali metal salt to thereby yield an ester of following Formula (2): (wherein tBu is a t-butyl group; and ring Z and m have the same meanings as defined above.) This process can commercially efficiently produce a bridged cyclic polycarboxylic acid t-butyl ester. The compound of Formula (1) can be prepared by allowing a bridged cyclic polycarboxylic acid of following Formula (3): (wherein ring Z is a bridged cyclic carbon ring; and m denotes an integer of 2 or more, where ring Z may have a substituent) to react with a halogenating agent.

    Abstract translation: 在本发明的制备桥联环状多元羧酸叔丁酯的方法中,具有下式(1)的桥连环状多羧酸卤化物(其中环Z是桥连环碳环; X是卤素原子; m 表示2以上的整数,其中环Z可以具有取代基)与叔丁醇或其碱金属盐反应,从而得到下式(2)的酯:(其中tBu是叔丁基 基团;且环Z和m具有与上述相同的含义。)该方法可商业上有效地制备桥连环状多元羧酸叔丁酯。 式(1)的化合物可以通过使下述式(3)的桥连环状多元羧酸(其中环Z为桥连环状碳环; m表示2以上的整数,其中环Z可以具有 取代基)与卤化剂反应。

    Method of making tomogram and apparatus
    39.
    发明授权
    Method of making tomogram and apparatus 失效
    制作TOMOGRAM和装置的方法

    公开(公告)号:US4039837A

    公开(公告)日:1977-08-02

    申请号:US702299

    申请日:1976-07-02

    CPC classification number: A61B6/4476 A61B6/14

    Abstract: Method and apparatus for making a tomogram according to this invention include one elongated support member supporting an X-ray tube and a film device in an opposed relation with each other at both ends thereof and one vertical shaft supporting the elongated support member thereon. Movement of the axis of the shaft along a desired curve results in the movement of an X-ray beam in the state of the X-ray beam intersecting the curve. In the meantime, an angle of rotation around the axis of the shaft is adjusted so as to maintain an angle of intersection of the X-ray beam with the curve at a predetermined angle. A film surface is moved relatively with respect to the X-ray beam so as to allow the beam to scan the film surface. The velocity of movement of the film surface is synchronized with the movement of the shaft. In the invention, the aforementioned movement of the shaft along the curve, the aforementioned angle of rotation of the shaft and the aforementioned movement of the film surface are respectively controlled or adjusted by digital signals.

    Curable resin composition and cured article
    40.
    发明授权
    Curable resin composition and cured article 有权
    可固化树脂组合物和固化制品

    公开(公告)号:US08871890B2

    公开(公告)日:2014-10-28

    申请号:US13813895

    申请日:2011-10-31

    Abstract: Disclosed is a curable resin composition which includes a ladder-type silsesquioxane (A) having an aliphatic carbon-carbon double bond in the molecule; a ladder-type silsesquioxane (B) having a Si—H bond in the molecule; and a hydrosilylation catalyst. The curable resin composition is useful as sealants typically for optical semiconductor elements. Also disclosed is a cured article which is obtained by curing the curable resin composition. The curable resin composition can give such a cured article having properties including resistance to elevated temperatures, flexibility, transparency, resistance to thermal yellowing, and resistance to photoyellowing.

    Abstract translation: 公开了一种固化性树脂组合物,其包含分子中具有脂肪族碳 - 碳双键的梯型倍半硅氧烷(A) 分子中具有Si-H键的梯型倍半硅氧烷(B); 和氢化硅烷化催化剂。 可固化树脂组合物可用作通常用于光学半导体元件的密封剂。 还公开了通过固化可固化树脂组合物获得的固化制品。 固化性树脂组合物可以得到具有耐高温性,柔软性,透明性,耐黄变性,耐光变性等特性的固化物。

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