Abstract:
Silane-containing polymers are prepared by the polymerization of one or more ethylenically unsaturated monomers in the presence of a silane-containing aldehyde, hemiacetal, or acetal as a regulator, optionally with further regulators as well. The silane-containing regulators produce polymers with superior properties and with improved polymerization parameters as compared to the conventional mercaptosilane regulators.
Abstract:
An process for producing thin silicone by extrusion of a layer of silicone. The silicone layer may be extruded onto a substrate layer. The silicone layer and the substrate layer may be extruded together out of an extrusion die.
Abstract:
Silicone-containing addition polymers having numerous uses are prepared by polymerizing addition polymerizable monomers in the presence of a silicone-containing polyvinyl alcohol, and/or by adding a silicone-containing polyvinyl alcohol to an aqueous addition polymer dispersion prior to spray drying, the silicone-containing polyvinyl alcohol containing at least one polymerizable group.
Abstract:
Functionalized copolymers hydrophobicized with silicones, in the form of aqueous dispersions or water-redispersible powders are prepared by copolymerizing a) from 60 to 99.89% by weight of one or more monomers selected from the group consisting of vinyl esters of optionally branched C1-15 alkylcarboxylic acids, methacrylates and acrylates of C1-15 alcohols, vinylaromatics, olefins, dienes, and vinyl halides, b) from 0.01 to 30% by weight of one or more silicones with from 10 to 1,000 SiO(CnH2n+1)2 repeat units where n is from 1 to 6, and where from 90 to 100% by weight of the silicones b) contain at least one but not more than two polymerizable groups, c) from 0.05 to 5.0% by weight of one or more hydrolyzable silane monomers selected from the group consisting of ethylenically unsaturated hydrolyzable silicon compounds, and hydrolyzable epoxysilanes, aminosilanes and mercaptosilanes, and d) from 0.05 to 5.0% by weight of one or more monomers selected from the group consisting of ethylenically unsaturated epoxy compounds. The copolymers may be used as binders for paints and coatings with high wet abrasion resistance.
Abstract translation:用水分散体或水可再分散粉末形式的硅氧烷疏水化的官能化共聚物通过以下方法制备:a)将60至99.89重量%的一种或多种选自任选支化的C 1-15烷基羧酸的乙烯基酯的单体 ,C1-15醇,乙烯基芳烃,烯烃,二烯和卤乙烯的甲基丙烯酸酯和丙烯酸酯,b)0.01至30重量%的一种或多种具有10至1,000个SiO(C n H 2n + 1)2重复单元的硅氧烷,其中n 为1至6,其中90至100重量%的硅氧烷b)含有至少1个但不多于2个可聚合基团,c)0.05至5.0重量%的一种或多种可水解硅烷单体,其选自 由烯键式不饱和可水解硅化合物组成的组和可水解的环氧硅烷,氨基硅烷和巯基硅烷,和d)0.05-5.0重量%的一种或多种选自乙烯基 lly不饱和环氧化合物。共聚物可用作具有高耐湿磨性的油漆和涂料的粘合剂。
Abstract:
The invention provides functionalized copolymers in the form of their aqueous dispersions or water-redispersible powders, based on a) one or more monomers from the group consisting of vinyl esters of unbranched or branched alkylcarboxylic acids having 1 to 15 carbon atoms, methacrylic esters and acrylic esters of alcohols having 1 to 15 carbon atoms, vinyl aromatics, olefins, dienes, and vinyl halides, b) from 0.05 to 5.0% by weight of one or more hydrolyzable silane monomers from the group consisting of ethylenically unsaturated, hydrolyzable silicon compounds and hydrolyzable silicon compounds from the group consisting of epoxysilanes, aminosilanes, and mercaptosilanes, c) from 0.05 to 5.0% by weight of one or more monomers from the group consisting of ethylenically unsaturated epoxide compounds, d) from 0 to 2.0% by weight of one or more monomers from the group consisting of ethylenically unsaturated 1,3-dicarbonyl compounds, the figures in % by weight being based in each case on the overall weight of the monomers a) used.
Abstract:
A transparent multi-layered film arrangement comprising at least three layers, wherein the film arrangement comprises one layer is made of a biodegradable polylactic acid (PLA) and a polyglycol as plasticizer, said polyglycol having a molecular weight of between 35,000 and 4,000,000, and at least two outer layers, each of said two outer layers being made of PLA.
Abstract:
Protective-colloid-stabilized polymers in the form of their aqueous dispersions or of their water-redispersible powders are based on homo- or copolymers of one or more monomers from the group consisting of vinyl esters of optionally branched alkyl carboxylic acids having from 1 to 15 carbon atoms, (meth)acrylic esters of alcohols having from 1 to 15 carbon atoms, vinylaromatics, olefins, dienes, and vinyl halides, wherein partially hydrolyzed vinyl acetate-ethylene copolymers with an ethylene content of from 1 to 15 mol %, a degree of hydrolysis DH of the vinyl acetate units of 80 mol %
Abstract:
Hydrophilic silicone copolymers are the addition polymerization product of an unsaturated silicone macromer, and unsaturated polyoxyalkylene polyether, and optionally further unsaturated addition polymerizable monomers.
Abstract:
A method for producing a biodegradable plastic film or a composite film, and the film obtained by such method. The film has barrier properties and is made at least of a biodegradable basic plastic material and a second plastic material having barrier properties. The film is useful in particular for packaging sensitive goods.
Abstract:
Silicone-containing addition polymers having numerous uses are prepared by polymerizing addition polymerizable monomers in the presence of a silicone-containing polyvinyl alcohol, and/or by adding a silicone-containing polyvinyl alcohol to an aqueous addition polymer dispersion prior to spray drying, the silicone-containing polyvinyl alcohol containing at least one polymerizable group.