摘要:
A catalyst for purifying exhaust gases of a diesel engine. The catalyst contains two functional layers superimposed on an inert supporting body, whereby the first layer, which is situated directly on the supporting body, has a nitrogen oxide storage function and the second layer, which is in direct contact with the exhaust gas, has a catalytic function. The second functional layer additionally has a hydrocarbon-storage function and its catalytic function is provided by catalytically active noble metals of the platinum group which are deposited in highly dispersed form on finely divided, acidic carrier materials. Nitrogen oxides in the oxygen-rich exhaust gas of a diesel engine can be converted with optimal utilization of the reductive constituents contained in the exhaust gas. For this purpose, no reducing agents going beyond the reductive components (carbon monoxide and hydrocarbons) which are contained as a consequence of incomplete combustion need to be added to the exhaust gas. Nevertheless, rates of conversion in respect of the nitrogen oxides are obtained, averaged over practical driving cycles, which lie distinctly above the rates of conversion of conventional reduction catalysts.
摘要:
A process is provided for operating a three-way catalyst that contains an oxygen storage component, that has a minimum and a maximum filling degree for oxygen and that is located in the exhaust gas line of an internal combustion engine. The air/fuel mixture supplied to the engine is varied in such a way that the filling degree of the oxygen storage component in the catalyst is held within a set-point interval between the minimum and maximum filling degree. According to this process, in order to regulate the air/fuel mixture, migration of the filling degree out of the set-point interval is checked in a test phase in such a way that the filling degree is increased or lowered relative to the instantaneous value (initial value) by short-term enrichment or reduction in richness of the air/fuel mixture supplied to the engine by a certain amount and immediately returned to the initial value by a short-term opposing change in the air/fuel mixture (lean/rich pulse sequence or rich/lean pulse sequence). In the case of a breakthrough of lean or rich exhaust gas through the catalyst during the test phase, the air/fuel mixture is enriched or reduced in richness in order to correct the filling degree, wherein the amount by which the filling degree during the test phase is increased or decreased is such that no breakthrough of lean or rich exhaust gas takes place through the catalyst when the filling degree of the oxygen storage component is within the set-point interval.
摘要:
A powdered catalyst material based on aluminum oxide, which contains at least one basic metal oxide and at least one noble metal from the platinum group of the Periodic Table of Elements in addition to aluminum oxide. The catalyst material is obtainable by loading a support material already stabilized by basic oxides by renewed impregnation with further basic oxides. After drying and calcining this post-impregnated material at temperatures below 800° C., the catalytically active noble metals are also incorporated into the support material by impregnation.
摘要:
The present invention relates to an exhaust gas cleaning catalyst comprising on a honeycomb carrier a catalytic coating. Said honeycomb carrier has an upstream end and a downstream end and a plurality of flow channels are running from the upstream end to the downstream end. The catalytic coating comprises catalytically active precious metal components of which at least one component exhibits a concentration profile along the honeycomb carrier starting with a low concentration at the upstream end which increases along the flow channels up to a maximum value and then decreases again to the downstream end.
摘要:
This invention relates to a method of operating a catalyst for treating the exhaust gas of an internal combustion engine, the catalyst comprising, in addition to catalytically active noble metals, also storage components for storing hydrocarbons. During engine operating phases at low exhaust-gas temperatures, such a catalyst stores the hydrocarbons contained in the exhaust gas without burning them. When the exhaust-gas temperature rises, these hydrocarbons are desorbed again and then oxidized at the catalytically active noble metals. This process can lead to uncontrolled, vigorous combustion of the hydrocarbons stored on the catalyst and, therefore, damage to the catalyst. According to the invention, this damage is avoided by continuously calculating the respective loading of the storage components with hydrocarbons and repeatedly regenerating the storage components depending on the loading by temporarily raising the exhaust-gas temperature before damage to the catalyst can occur.
摘要:
The present invention relates to a catalyst for the purification of exhaust gases from an internal combustion engine, which comprises a catalytically active coating on an inert ceramic or metal honeycomb body, said coating comprising at least one platinum group metal selected from the group consisting of platinum, palladium, rhodium and iridium on a fine, oxidic support material. As an oxidic support material, the catalyst comprises a low-porosity material on the basis of silicon dioxide that comprises aggregates of essentially spherical primary particles having an average particle diameter of between 7 and 60 nm.
摘要:
This invention relates to a method and a corresponding apparatus for coating open-pored bodies with at least one coating suspension. In particular, the coating suspension has solids and solutes in a liquid medium in a quantity in wet state which is to correspond to at least a required target quantity. The coating operation has a variation in the applied wet coating quantity from one body to the other. The method according to the invention is characterized by the steps of: coating the body with an actual quantity of the coating suspension, which is always larger than the required target quantity taking the variation of the coating operation into account, determining the difference between the actual quantity and the required target quantity, and reducing the difference between actual quantity and target quantity by removing still wet coating suspension.
摘要:
The present invention relates to an exhaust gas cleaning catalyst comprising on a honeycomb carrier a catalytic coating. Said honeycomb carrier has an upstream end and a downstream end and a plurality of flow channels are running from the upstream end to the downstream end. The catalytic coating comprises catalytically active precious metal components of which at least one component exhibits a concentration profile along the honeycomb carrier starting with a low concentration at the upstream end which increases along the flow channels up to a maximum value and then decreases again to the downstream end.
摘要:
This invention relates to a method of operating a catalyst for treating the exhaust gas of an internal combustion engine, the catalyst comprising, in addition to catalytically active noble metals, also storage components for storing hydrocarbons. During engine operating phases at low exhaust-gas temperatures, such a catalyst stores the hydrocarbons contained in the exhaust gas without burning them. When the exhaust-gas temperature rises, these hydrocarbons are desorbed again and then oxidized at the catalytically active noble metals. This process can lead to uncontrolled, vigorous combustion of the hydrocarbons stored on the catalyst and, therefore, damage to the catalyst. According to the invention, this damage is avoided by continuously calculating the respective loading of the storage components with hydrocarbons and repeatedly regenerating the storage components depending on the loading by temporarily raising the exhaust-gas temperature before damage to the catalyst can occur.
摘要:
An oxygen storage material based on cerium oxide with at least one other oxide of the metals silicon and zirconium, wherein the cerium oxide and the other oxides are present in the form of a mixed oxide. The material is obtainable in that hydroxidic precursors of the mixed oxide are first prepared in a manner known per se using a wet-chemical route, these precursors are optionally dried at temperatures between 80 and 300° C. and the dried precursors are then treated under a hydrogen-containing atmosphere at a temperature between 600 and 900° C. for a period of 1 to 10 hours. The reductive thermal treatment endows the material with a greatly improved dynamic behavior as compared with conventional calcination in air.