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1.发明申请公开(公告)号：US20130189172A1
公开(公告)日：2013-07-25
申请号：US13877075
申请日：2011-11-14
Applicant: Paul Spurk , Nicola Soeger , Elena Mueller , Stephan Malmberg
Inventor： Paul Spurk , Nicola Soeger , Elena Mueller , Stephan Malmberg
CPC classification number: B01D53/9422 , B01D53/9418 , B01D2255/202 , B01D2255/204 , B01D2255/2061 , B01D2255/2065 , B01D2255/207 , B01D2255/20715 , B01D2255/20776 , B01D2255/407 , B01D2255/9022 , B01D2255/9032 , B01D2255/91 , B01J23/002 , B01J23/20 , B01J23/30 , B01J23/63 , B01J23/6484 , B01J23/6527 , B01J23/682 , B01J23/687 , B01J35/0006 , B01J35/04 , B01J37/0244 , B01J37/0248 , B01J2523/00 , F01N3/2066 , F01N2510/0684 , Y02T10/24 , B01J2523/36 , B01J2523/3712 , B01J2523/48 , B01J2523/56
Abstract: The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise selectively catalytically reductive (SCR-active) mixed oxide consisting of cerium oxide, zirconium oxide, rare earth sesquioxide and niobium oxide and optionally tungsten oxide. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, mixed magnesium/aluminum oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.
Abstract translation: 本发明涉及一种用于从柴油发动机废气中除去氮氧化物的催化剂，以及用于降低柴油发动机废气中的氮氧化物水平的方法。 催化剂由长度为L的支撑体和催化活性涂层组成，反过来可以由一个或多个材料区形成。 材料区包括由氧化铈，氧化锆，稀土三氧化物和氧化铌以及任选的氧化钨组成的选择性催化还原（SCR-活性）混合氧化物。 此外，材料区包含至少一种选自氧化钡，氢氧化钡，碳酸钡，氧化锶，氢氧化锶，碳酸锶，氧化镨，氧化镧，氧化镁，混合的镁/铝， 碱金属氧化物，碱金属氢氧化物，碱金属碳酸盐及其混合物。 贵金属可以任选地也存在于催化剂中。
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2.发明授权Method of operating a system comprising a diesel engine and catalyst for exhaust gas purification 有权操作包括用于排气净化的柴油发动机和催化剂的系统的方法公开(公告)号：US07310940B2
公开(公告)日：2007-12-25
申请号：US10558142
申请日：2004-05-18
Applicant: Jürgen Gieshoff , Martin Votsmeir , Stephan Malmberg , Egbert Lox , Thomas Kreuzer
Inventor： Jürgen Gieshoff , Martin Votsmeir , Stephan Malmberg , Egbert Lox , Thomas Kreuzer
IPC: F01N3/00
CPC classification number: F01N11/002 , B01D53/9495 , F01N2430/00 , F01N2430/08 , F01N2550/02 , F02B3/06 , F02D41/0235 , F02D41/024 , F02D2009/0222 , F02D2009/0237 , Y02T10/26 , Y02T10/47
Abstract: The invention relates to a method and an apparatus of operating a drive system comprising an engine and an exhaust gas purification unit containing a catalyst, where the engine emits an exhaust gas having an exhaust gas temperature and the catalyst has a catalytic activity for the purification of the exhaust gas. In the method, an aging-induced decrease in the catalytic activity of the catalyst is compensated at least part of the time by increasing the exhaust gas temperature of the engine.
Abstract translation: 本发明涉及一种操作驱动系统的方法和装置，该驱动系统包括发动机和含有催化剂的排气净化单元，其中发动机排出具有排气温度的废气，并且该催化剂具有用于纯化的催化活性 废气。 在该方法中，通过增加发动机的废气温度，至少部分时间补偿催化剂的催化活性的老化引起的降低。
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3.发明申请公开(公告)号：US20070006570A1
公开(公告)日：2007-01-11
申请号：US10558142
申请日：2004-05-18
Applicant: Jurgen Gieshoff , Martin Votsmeir , Stephan Malmberg , Egbert Lox , Thomas Kreuzer
Inventor： Jurgen Gieshoff , Martin Votsmeir , Stephan Malmberg , Egbert Lox , Thomas Kreuzer
CPC classification number: F01N11/002 , B01D53/9495 , F01N2430/00 , F01N2430/08 , F01N2550/02 , F02B3/06 , F02D41/0235 , F02D41/024 , F02D2009/0222 , F02D2009/0237 , Y02T10/26 , Y02T10/47
Abstract: The invention relates to a method and an apparatus of operating a drive system comprising an engine and an exhaust gas purification unit containing a catalyst, where the engine emits an exhaust gas having an exhaust gas temperature and the catalyst has a catalytic activity for the purification of the exhaust gas. In the method, an aging-induced decrease in the catalytic activity of the catalyst is compensated at least part of the time by increasing the exhaust gas temperature of the engine.
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Patent Agency Ranking
4.发明授权公开(公告)号：US09095816B2
公开(公告)日：2015-08-04
申请号：US13877075
申请日：2011-11-14
Applicant: Paul Spurk , Nicola Soeger , Elena Mueller , Stephan Malmberg
Inventor： Paul Spurk , Nicola Soeger , Elena Mueller , Stephan Malmberg
IPC: B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J23/10 , B01D53/94 , B01J23/20 , B01J23/30 , B01J23/63 , B01J23/648 , B01J23/652 , B01J23/68 , B01J35/00 , B01J35/04 , B01J37/02 , F01N3/20
CPC classification number: B01D53/9422 , B01D53/9418 , B01D2255/202 , B01D2255/204 , B01D2255/2061 , B01D2255/2065 , B01D2255/207 , B01D2255/20715 , B01D2255/20776 , B01D2255/407 , B01D2255/9022 , B01D2255/9032 , B01D2255/91 , B01J23/002 , B01J23/20 , B01J23/30 , B01J23/63 , B01J23/6484 , B01J23/6527 , B01J23/682 , B01J23/687 , B01J35/0006 , B01J35/04 , B01J37/0244 , B01J37/0248 , B01J2523/00 , F01N3/2066 , F01N2510/0684 , Y02T10/24 , B01J2523/36 , B01J2523/3712 , B01J2523/48 , B01J2523/56
Abstract: The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise selectively catalytically reductive (SCR-active) mixed oxide consisting of cerium oxide, zirconium oxide, rare earth sesquioxide and niobium oxide and optionally tungsten oxide. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, mixed magnesium/aluminum oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.
Abstract translation: 本发明涉及一种用于从柴油发动机废气中除去氮氧化物的催化剂，以及用于降低柴油发动机废气中的氮氧化物水平的方法。 催化剂由长度为L的支撑体和催化活性涂层组成，反过来可以由一个或多个材料区形成。 材料区包括由氧化铈，氧化锆，稀土三氧化物和氧化铌以及任选的氧化钨组成的选择性催化还原（SCR-活性）混合氧化物。 此外，材料区包含至少一种选自氧化钡，氢氧化钡，碳酸钡，氧化锶，氢氧化锶，碳酸锶，氧化镨，氧化镧，氧化镁，混合的镁/铝， 碱金属氧化物，碱金属氢氧化物，碱金属碳酸盐及其混合物。 贵金属可以任选地也存在于催化剂中。
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5.发明授权公开(公告)号：US08753596B2
公开(公告)日：2014-06-17
申请号：US13819213
申请日：2011-09-08
Applicant: Paul Spurk , Nicola Soeger , Elena Mueller , Stephan Malmberg
Inventor： Paul Spurk , Nicola Soeger , Elena Mueller , Stephan Malmberg
CPC classification number: B01J29/85 , B01D53/9418 , B01D53/9422 , B01D53/9477 , B01D2251/2067 , B01D2255/1023 , B01D2255/2042 , B01D2255/2047 , B01D2255/2063 , B01D2255/2065 , B01D2255/20715 , B01D2255/20761 , B01D2255/2092 , B01D2255/407 , B01D2255/50 , B01D2255/9022 , B01D2255/9032 , B01D2258/012 , B01J21/04 , B01J21/066 , B01J23/10 , B01J23/63 , B01J23/66 , B01J23/72 , B01J23/8926 , B01J23/894 , B01J23/8946 , B01J29/072 , B01J29/7215 , B01J29/723 , B01J29/83 , B01J35/0006 , B01J37/0215 , B01J37/0244 , B01J37/0246 , B01J37/0248 , B01J37/038 , F01N3/0814 , F01N3/0842 , F01N3/2066 , F01N2370/04 , F01N2510/063 , F01N2510/0682 , F01N2510/0684 , F01N2610/02 , Y02T10/24
Abstract: The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise a copper-containing zeolite or a zeolite-like compound. The materials used include chabazite, SAPO-34, ALPO-34 and zeolite β. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, magnesium/aluminum mixed oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.
Abstract translation: 本发明涉及一种用于从柴油发动机废气中除去氮氧化物的催化剂，以及用于降低柴油发动机废气中的氮氧化物水平的方法。 催化剂由长度为L的支撑体和催化活性涂层组成，反过来可以由一个或多个材料区形成。 材料区域包含含铜沸石或类沸石化合物。 所用的材料包括菱沸石，SAPO-34，ALPO-34和沸石＆bgr。 此外，材料区包含至少一种选自氧化钡，氢氧化钡，碳酸钡，氧化锶，氢氧化锶，碳酸锶，氧化镨，氧化镧，氧化镁，镁/铝混合氧化物， 碱金属氧化物，碱金属氢氧化物，碱金属碳酸盐及其混合物。 贵金属可以任选地也存在于催化剂中。
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6.发明授权Method of operating a catalyst which includes components for storing hydrocarbons 有权操作包含用于储存烃的组分的催化剂的方法公开(公告)号：US07737081B2
公开(公告)日：2010-06-15
申请号：US10556548
申请日：2004-05-12
Applicant: Martin Votsmeier , Frank Schütze , Stephan Malmberg , Jürgen Gieshoff , Egbert Lox , Thomas Kreuzer
Inventor： Martin Votsmeier , Frank Schütze , Stephan Malmberg , Jürgen Gieshoff , Egbert Lox , Thomas Kreuzer
CPC classification number: F01N3/0835 , F01N3/0814 , F01N3/20 , F01N9/005 , F01N11/00 , F01N2370/24 , F01N2430/00 , F01N2430/06 , F01N2430/08 , F01N2430/085 , F01N2550/02 , F01N2550/03 , F02D41/027 , F02D2200/0802 , Y02T10/47 , Y10T436/12
Abstract: This invention relates to a method of operating a catalyst for treating the exhaust gas of an internal combustion engine, the catalyst comprising, in addition to catalytically active noble metals, also storage components for storing hydrocarbons. During engine operating phases at low exhaust-gas temperatures, such a catalyst stores the hydrocarbons contained in the exhaust gas without burning them. When the exhaust-gas temperature rises, these hydrocarbons are desorbed again and then oxidized at the catalytically active noble metals. This process can lead to uncontrolled, vigorous combustion of the hydrocarbons stored on the catalyst and, therefore, damage to the catalyst. According to the invention, this damage is avoided by continuously calculating the respective loading of the storage components with hydrocarbons and repeatedly regenerating the storage components depending on the loading by temporarily raising the exhaust-gas temperature before damage to the catalyst can occur.
Abstract translation: 本发明涉及一种操作用于处理内燃机废气的催化剂的方法，催化剂除了催化活性贵金属外，还包括用于储存烃的储存组分。 在低废气温度的发动机运转阶段，这样的催化剂将不含燃烧物的废气中所含的烃储存在废气中。 当废气温度升高时，这些烃再次解吸，然后在催化活性贵金属处被氧化。 该方法可导致存储在催化剂上的烃的不受控制的剧烈燃烧，因此对催化剂的损害。 根据本发明，通过用碳氢化合物连续地计算储存部件的负荷并且可以在可能发生催化剂的损坏之前通过临时提高排气温度来重新再生存储部件，从而避免了这种损坏。
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7.发明申请Method of operating a catalyst which includes components for storing hydrocarbon 有权操作包含用于储存烃的组分的催化剂的方法公开(公告)号：US20070166827A1
公开(公告)日：2007-07-19
申请号：US10556548
申请日：2004-05-12
Applicant: Martin Votsmeier , Frank Schutze , Stephan Malmberg , Jurgen Gieshoff , Egbert Lox , Thomas Kreuzer
Inventor： Martin Votsmeier , Frank Schutze , Stephan Malmberg , Jurgen Gieshoff , Egbert Lox , Thomas Kreuzer
IPC: G01N35/08
CPC classification number: F01N3/0835 , F01N3/0814 , F01N3/20 , F01N9/005 , F01N11/00 , F01N2370/24 , F01N2430/00 , F01N2430/06 , F01N2430/08 , F01N2430/085 , F01N2550/02 , F01N2550/03 , F02D41/027 , F02D2200/0802 , Y02T10/47 , Y10T436/12
Abstract: This invention relates to a method of operating a catalyst for treating the exhaust gas of an internal combustion engine, the catalyst comprising, in addition to catalytically active noble metals, also storage components for storing hydrocarbons. During engine operating phases at low exhaust-gas temperatures, such a catalyst stores the hydrocarbons contained in the exhaust gas without burning them. When the exhaust-gas temperature rises, these hydrocarbons are desorbed again and then oxidized at the catalytically active noble metals. This process can lead to uncontrolled, vigorous combustion of the hydrocarbons stored on the catalyst and, therefore, damage to the catalyst. According to the invention, this damage is avoided by continuously calculating the respective loading of the storage components with hydrocarbons and repeatedly regenerating the storage components depending on the loading by temporarily raising the exhaust-gas temperature before damage to the catalyst can occur.
Abstract translation: 本发明涉及一种操作用于处理内燃机废气的催化剂的方法，催化剂除了催化活性贵金属外，还包括用于储存烃的储存组分。 在低废气温度的发动机运转阶段，这样的催化剂将不含燃烧物的废气中所含的烃储存在废气中。 当废气温度升高时，这些烃再次解吸，然后在催化活性贵金属处被氧化。 该方法可导致存储在催化剂上的烃的不受控制的剧烈燃烧，因此对催化剂的损害。 根据本发明，通过用碳氢化合物连续地计算储存部件的负荷并且可以在可能发生催化剂的损坏之前通过临时提高排气温度来重新再生存储部件，从而避免了这种损坏。
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8.发明申请公开(公告)号：US20130156668A1
公开(公告)日：2013-06-20
申请号：US13819213
申请日：2011-09-08
Applicant: Paul Spurk , Nicola Soeger , Elena Mueller , Stephan Malmberg
Inventor： Paul Spurk , Nicola Soeger , Elena Mueller , Stephan Malmberg
CPC classification number: B01J29/85 , B01D53/9418 , B01D53/9422 , B01D53/9477 , B01D2251/2067 , B01D2255/1023 , B01D2255/2042 , B01D2255/2047 , B01D2255/2063 , B01D2255/2065 , B01D2255/20715 , B01D2255/20761 , B01D2255/2092 , B01D2255/407 , B01D2255/50 , B01D2255/9022 , B01D2255/9032 , B01D2258/012 , B01J21/04 , B01J21/066 , B01J23/10 , B01J23/63 , B01J23/66 , B01J23/72 , B01J23/8926 , B01J23/894 , B01J23/8946 , B01J29/072 , B01J29/7215 , B01J29/723 , B01J29/83 , B01J35/0006 , B01J37/0215 , B01J37/0244 , B01J37/0246 , B01J37/0248 , B01J37/038 , F01N3/0814 , F01N3/0842 , F01N3/2066 , F01N2370/04 , F01N2510/063 , F01N2510/0682 , F01N2510/0684 , F01N2610/02 , Y02T10/24
Abstract: The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise a copper-containing zeolite or a zeolite-like compound. The materials used include chabazite, SAPO-34, ALPO-34 and zeolite β. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, magnesium/aluminum mixed oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.
Abstract translation: 本发明涉及一种用于从柴油发动机废气中除去氮氧化物的催化剂，以及用于降低柴油发动机废气中的氮氧化物水平的方法。 催化剂由长度为L的支撑体和催化活性涂层组成，反过来可以由一个或多个材料区形成。 材料区域包含含铜沸石或类沸石化合物。 所用的材料包括菱沸石，SAPO-34，ALPO-34和β沸石。 此外，材料区包含至少一种选自氧化钡，氢氧化钡，碳酸钡，氧化锶，氢氧化锶，碳酸锶，氧化镨，氧化镧，氧化镁，镁/铝混合氧化物， 碱金属氧化物，碱金属氢氧化物，碱金属碳酸盐及其混合物。 贵金属可以任选地也存在于催化剂中。
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