摘要:
The present invention relates to a proton-conducting polymer membrane comprising polymers containing phosphonic acid groups which is obtainable by a process comprising the steps A) mixing of vinyl-containing phosphonic acid with one or more aromatic tetraamino compounds with one or more aromatic carboxylic acids, esters thereof, acid halides thereof or anhydrides thereof which contain at least two acid groups per carboxylic acid monomer, and/or mixing of vinyl-containing phosphonic acid with one or more aromatic and/or heteroaromatic diamino carboxylic acids, esters thereof, acid halides thereof or anhydrides thereof, B) heating of the mixture obtainable according to step A) under inert gas at temperatures of up to 350° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) polymerization of the vinyl-containing phosphonic acid present in the sheet-like structure obtainable according to step C).
摘要:
The present invention relates to a novel proton-conducting polymer membrane based on polyazoles which can, because of its excellent chemical and thermal properties, be used in a variety of ways and is particularly useful as polymer electrolyte membrane (PEM) to produce membrane electrode units for PEM fuel cells.
摘要:
The present invention relates to a proton-conducting electrolyte membrane obtainable by a process comprising the steps: A) swelling a polymer film with a liquid comprising a vinyl-containing sulphonic acid and B) polymerising the vinyl-containing sulphonic acid present in liquid introduced in step A). A membrane according to the invention is very versatile on account of its excellent chemical and thermal properties and may be used, in particular, as a polymer electrolyte membrane (PEM) in what are known as PEM fuel cells.
摘要:
The present invention relates to a proton-conducting polymer membrane comprising polyazoles which is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole and/or one or more compounds suitable for forming polyazoles under the action of heat in step B), B) heating of the mixture obtainable according to step A) to temperatures up to 400° C. under inert gas, C) application of a layer to a support using the mixture from step A) and/or B), D) treatment of the membrane formed in step C) until it is self-supporting, wherein the treatment of the membrane is carried out using a hydrolysis liquid comprising oxo acids of phosphorus and/or oxo acids of sulfur.
摘要:
The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.
摘要:
The present invention concerns a proton-conducting electrolyte membrane obtainable by a method comprising the following steps: A) expanding a polymer film with a liquid that contains a vinyl-containing phosphonic acid, and B) polymerisation of the vinyl-containing phosphonic acid present in the liquid introduced in step A). An inventive membrane, thanks to its exceptional chemical and thermal properties, is very versatile in its use and is particularly suitable as a polymer-electrolyte-membrane (PEM) in so-called PEM fuel cells.
摘要:
The present invention relates to an acid-doped polymer membrane based on polyazoles. The acid-doped polymer membrane can be used in a variety of applications because of its excellent mechanical properties and is useful as polymer electrolyte membrane (PEM) in PEM fuel cells. A doped polymer membrane based on polyazoles is obtained by a process comprising the steps of: A) casting a film using a solution of polymers based on polyazoles in a polar, aprotic organic solvent; B) drying the film formed in step A) until it is self-supporting; C) treating the film obtained in step B) with a treatment liquid at a temperature in the range from room temperature to the boiling point of the treatment liquid; D) drying and/or dabbing the film treated according to step C) to remove the treatment liquid from step C); and E) doping the film treated according to step D) with a doping agent.
摘要:
The present invention relates to an asymmetric polymer film, in particular based on polazoles, a method for the production of the same and its use. The polyazole-based asymmetric polymer film according to the invention has a smooth and a rough side and enables, on account of its asymmetric structure, rapid and homogeneous doping with acids to form a proton-conducting membrane. The polyazole-based asymmetric polymer film according to the invention can be used in diverse ways on account of its excellent chemical, thermal and mechanical properties and is particularly suitable for the production of polymer electrolyte membranes (PEM) for so-called PEM fuel cells.
摘要:
The present invention relates to polymer films and a polymer membrane having an improved mechanical property profile produced therefrom, to a process for producing them and to their use.The polymer films, polymer membranes and separation membranes of the invention are produced from selected polymer raw materials and have excellent chemical, thermal. and mechanical properties as are required for use as polymer electrolyte membranes (PEMs) in PEM fuel cells or in apparatuses for the filtration and/or separation of gases and/or liquids or for reverse osmosis.
摘要:
The present invention relates to a proton-conducting polymer electrolyte membrane based on polyvinylphosphonic acid/polyvinylsulfonic acid polymers, which owing to their excellent chemical and thermal properties, can be used for a variety of purposes and is particularly suitable as polymer electrolyte membrane (PEM) in PEM fuel cells.