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1.发明申请Proton conducting electrolyte membrane having reduced methanol permeability and the use thereof in fuel cells 失效具有降低甲醇渗透性的质子导电电解质膜及其在燃料电池中的应用公开(公告)号：US20050118477A1
公开(公告)日：2005-06-02
申请号：US10506387
申请日：2003-03-04
申请人： Joachim Kiefer , Oemer Uensal , Gordon Calundann , James Crivello
发明人： Joachim Kiefer , Oemer Uensal , Gordon Calundann , James Crivello
CPC分类号： H01M8/1023 , C08J5/2231 , C08J2325/08 , H01M8/04197 , H01M8/1011 , H01M8/1025 , H01M8/1039 , H01M8/1044 , H01M8/106 , H01M8/1072 , H01M2300/0082 , Y02E60/523 , Y02P70/56
摘要： The present invention relates to a proton-conducting electrolyte membrane obtainable by a process comprising the steps: A) swelling a polymer film with a liquid comprising a vinyl-containing sulphonic acid and B) polymerising the vinyl-containing sulphonic acid present in liquid introduced in step A). A membrane according to the invention is very versatile on account of its excellent chemical and thermal properties and may be used, in particular, as a polymer electrolyte membrane (PEM) in what are known as PEM fuel cells.
摘要翻译： 本发明涉及可通过包括以下步骤的方法获得的质子传导电解质膜：A）用含有乙烯基磺酸的液体使聚合物膜膨胀，以及B）使存在于液体中的乙烯基磺酸聚合 步骤A）。 根据本发明的膜由于其优异的化学和热性质而是非常通用的，并且可以特别地用作所谓的PEM燃料电池中的聚合物电解质膜（PEM）。
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2.发明授权Proton conducting electrolyte membrane having reduced methanol permeability and the use thereof in fuel cells 失效具有降低甲醇渗透性的质子导电电解质膜及其在燃料电池中的应用公开(公告)号：US07846982B2
公开(公告)日：2010-12-07
申请号：US10506387
申请日：2003-03-04
申请人： Joachim Kiefer , Oemer Uensal , Gordon Calundann , James Crivello
发明人： Joachim Kiefer , Oemer Uensal , Gordon Calundann , James Crivello
CPC分类号： H01M8/1023 , C08J5/2231 , C08J2325/08 , H01M8/04197 , H01M8/1011 , H01M8/1025 , H01M8/1039 , H01M8/1044 , H01M8/106 , H01M8/1072 , H01M2300/0082 , Y02E60/523 , Y02P70/56
摘要： The present invention relates to a proton-conducting electrolyte membrane obtainable by a process comprising the steps: A) swelling a polymer film with a liquid comprising a vinyl-containing sulphonic acid and B) polymerising the vinyl-containing sulphonic acid present in liquid introduced in step A). A membrane according to the invention is very versatile on account of its excellent chemical and thermal properties and may be used, in particular, as a polymer electrolyte membrane (PEM) in what are known as PEM fuel cells.
摘要翻译： 本发明涉及可通过包括以下步骤的方法获得的质子传导电解质膜：A）用含有乙烯基磺酸的液体使聚合物膜膨胀，以及B）使存在于液体中的乙烯基磺酸聚合 步骤A）。 根据本发明的膜由于其优异的化学和热性质而是非常通用的，并且可以特别地用作所谓的PEM燃料电池中的聚合物电解质膜（PEM）。
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3.发明授权Proton-conducting polymer membrane comprising polyazole blends and its use in fuel cells 失效包含聚唑共混物的导电聚合物膜及其在燃料电池中的应用公开(公告)号：US08142917B2
公开(公告)日：2012-03-27
申请号：US12776489
申请日：2010-05-10
申请人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael J. Sansone , Brian Benicewicz , Eui Wong Choe
发明人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael J. Sansone , Brian Benicewicz , Eui Wong Choe
IPC分类号： H01M8/10
CPC分类号： C08J5/2275 , B01D71/62 , C08G73/18 , C08J2379/06 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1034 , H01M8/1037 , H01M8/1039 , H01M8/1041 , H01M8/1048 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： The present invention relates to a proton-conducting polymer membrane which comprises polyazole blends and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, wherein at least one further polymer (polymer B) which is not a polyazole is added to the composition obtainable according to step A) and/or step B) and the weight ratio of polyazole to polymer B is in the range from 0.1 to 50.
摘要翻译： 本发明涉及一种质子传导性聚合物膜，其包含聚唑共混物并且可通过包括以下步骤的方法获得：A）制备包含多磷酸，至少一种聚唑（聚合物A）和/或一种或多种化合物 适用于根据步骤B）在热的作用下形成多唑类; B）将惰性气体下得到的混合物加热至高达400℃的温度; C）使用混合物 从步骤A）和/或B）到支持物，D）处理在步骤C）中形成的膜，直到其自支撑，其中至少一种不是聚唑的另外的聚合物（聚合物B）加入到 根据步骤A）和/或步骤B）可获得的组合物，并且聚唑与聚合物B的重量比在0.1至50的范围内。
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公开(公告)号：US08076379B2
公开(公告)日：2011-12-13
申请号：US10519281
申请日：2003-06-14
CPC分类号： C08J5/2256 , B01D71/62 , B01D71/82 , C08G73/0616 , C08G73/0627 , C08G73/0633 , C08G73/08 , C08G73/18 , C08G73/22 , C08J2379/06 , H01M8/1004 , H01M8/1027 , H01M8/103 , H01M8/1048 , H01M8/1067 , H01M8/1072 , Y02P70/56
摘要： The present invention relates to a novel proton-conducting polymer membrane based on aromatic polyazoles which contain sulfonic acid groups and in which the sulfonic acid groups are covalently bound to the aromatic ring of the polymer and which can, owing to their excellent chemical and thermal properties, be used for a variety of purposes. Such materials are particularly useful for the production of polymer electrolyte membranes (PEMs) in PEM fuel cells.
摘要翻译： 本发明涉及一种基于含有磺酸基的芳香族多唑的新的质子传导聚合物膜，其中磺酸基共价结合到聚合物的芳香环上，并且由于其优异的化学和热性能 ，用于各种用途。 这种材料对于在PEM燃料电池中生产聚合物电解质膜（PEM）特别有用。
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公开(公告)号：US20110288187A1
公开(公告)日：2011-11-24
申请号：US13194294
申请日：2011-07-29
IPC分类号： B01J39/18
CPC分类号： B01D67/0011 , B01D71/62 , B01D2323/08 , B01D2323/26 , C08J5/2256 , C08J2379/06 , H01M8/0293 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1081 , H01M8/1088 , Y02P70/56
摘要： The present invention relates to a novel proton-conducting polymer membrane based on polyazoles which can, because of its excellent chemical and thermal properties, be used in a variety of ways and is particularly useful as polymer electrolyte membrane (PEM) to produce membrane electrode units for PEM fuel cells.
摘要翻译： 本发明涉及一种基于多唑的新型质子导电聚合物膜，由于其优异的化学和热性能可以以多种方式使用，并且特别可用作聚合物电解质膜（PEM）以产生膜电极单元 用于PEM燃料电池。
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公开(公告)号：US07795372B2
公开(公告)日：2010-09-14
申请号：US10525590
申请日：2003-08-14
CPC分类号： B01D71/62 , B01D2323/225 , C08G73/06 , C08G73/0616 , C08G73/0627 , C08G73/0633 , C08G73/0688 , C08G73/0694 , C08G73/18 , C08G73/22 , C08L79/06 , D01F6/74
摘要： The present invention relates to a novel polymer film and also polymer fibers and polymers based on polyazoles, which can, owing to its excellent chemical and thermal properties, be used for a variety of purposes and is particularly useful as film or membrane for gas purification and filtration.
摘要翻译： 本发明涉及一种新颖的聚合物膜，以及聚合物纤维和基于聚唑的聚合物，由于其优异的化学和热性质，可以用于各种目的，并且特别可用作气体净化用膜或膜， 过滤。
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7.发明申请PROTON-CONDUCTING POLYMER MEMBRANE COMPRISING POLYMERS CONTAINING PHOSPHONIC ACID GROUPS AND ITS USE IN FUEL CELLS 审中-公开包含含磷酸聚合物的聚合物的导电聚合物膜及其在燃料电池中的使用公开(公告)号：US20100227252A1
公开(公告)日：2010-09-09
申请号：US12783588
申请日：2010-05-20
申请人： Joachim Kiefer , Oemer Uensal , Gordon Calundann
发明人： Joachim Kiefer , Oemer Uensal , Gordon Calundann
CPC分类号： C08J5/2268 , C08F230/02 , C08F271/02 , C08F275/00 , C08F291/00 , C08G61/122 , C08G73/08 , C08G73/10 , C08G73/18 , C08G73/22 , C08J2379/06 , H01M8/1004 , H01M8/1023 , H01M8/103 , H01M8/1041 , H01M8/1072 , Y02P70/56
摘要： The present invention relates to a proton-conducting polymer membrane comprising polymers containing phosphonic acid groups which is obtainable by a process comprising the steps A) mixing of vinyl-containing phosphonic acid with one or more aromatic tetramino compounds with one or more aromatic carboxylic acids, esters thereof, acid halides thereof or anhydrides thereof which contain at least two acid groups per carboxylic acid monomer, and/or mixing of vinyl-containing phosphonic acid with one or more aromatic and/or heteroaromatic diamino carboxylic acids, esters thereof, acid halides thereof or anhydrides thereof, B) heating of the mixture obtainable according to step A) under inert gas at temperatures of up to 350° C. to form polyazole polymers, C) application of a layer using the mixture from step A) and/or B) to a support, D) polymerization of the vinyl-containing phosphonic acid present in the sheet-like structure obtainable according to step C).
摘要翻译： 本发明涉及包含含有膦酸基团的聚合物的质子传导性聚合物膜，其可以通过包括以下步骤的方法获得：A）将含乙烯基的膦酸与一种或多种芳族四嗪化合物与一种或多种芳族羧酸混合， 其酯，其酰卤或其酸酐，其每个羧酸单体含有至少两个酸基，和/或含乙烯基的膦酸与一种或多种芳族和/或杂芳族二氨基羧酸，其酯，其酰卤的混合 或其酸酐，B）在惰性气体下在高达350℃的温度下加热根据步骤A）获得的混合物，以形成聚唑聚合物，C）使用来自步骤A）和/或B的混合物 ），D）根据步骤C）获得的片状结构中存在的含乙烯基膦酸的聚合。
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公开(公告)号：US20050053820A1
公开(公告)日：2005-03-10
申请号：US10489385
申请日：2002-08-29
IPC分类号： B01D69/10 , B01D67/00 , B01D71/62 , C08G61/12 , C08J5/22 , H01B1/06 , H01B13/00 , H01M8/0293 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1081 , H01M8/1088 , H01M8/10
CPC分类号： B01D67/0011 , B01D71/62 , B01D2323/08 , B01D2323/26 , C08J5/2256 , C08J2379/06 , H01M8/0293 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1081 , H01M8/1088 , Y02P70/56
摘要： The present invention relates to a novel proton-conducting polymer membrane based on polyazoles which can, because of its excellent chemical and thermal properties, be used in a variety of ways and is particularly useful as polymer electrolyte membrane (PEM) to produce membrane electrode units for PEM fuel cells.
摘要翻译： 本发明涉及一种基于多唑的新型质子导电聚合物膜，由于其优异的化学和热性能可以以多种方式使用，并且特别可用作聚合物电解质膜（PEM）以产生膜电极单元 用于PEM燃料电池。
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公开(公告)号：US08013026B2
公开(公告)日：2011-09-06
申请号：US12721088
申请日：2010-03-10
CPC分类号： B01D67/0011 , B01D71/62 , B01D2323/08 , B01D2323/26 , C08J5/2256 , C08J2379/06 , H01M8/0293 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1081 , H01M8/1088 , Y02P70/56
摘要： The present invention relates to a novel proton-conducting polymer membrane based on polyazoles which can, because of its excellent chemical and thermal properties, be used in a variety of ways and is particularly useful as polymer electrolyte membrane (PEM) to produce membrane electrode units for PEM fuel cells.
摘要翻译： 本发明涉及一种基于多唑的新型质子导电聚合物膜，由于其优异的化学和热性能可以以多种方式使用，并且特别可用作聚合物电解质膜（PEM）以产生膜电极单元 用于PEM燃料电池。
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公开(公告)号：US07582210B2
公开(公告)日：2009-09-01
申请号：US11930764
申请日：2007-10-31
CPC分类号： B01D67/0006 , B01D67/0011 , B01D71/62 , B01D2323/08 , B01D2323/26 , B01D2325/04 , C08G73/18 , C08J5/2256 , C08J2379/06 , C09D179/04 , H01M4/8605 , H01M8/0289 , H01M8/1004 , H01M8/103 , H01M8/1048 , H01M8/1067 , H01M8/1072 , H01M8/109 , Y02P70/56
摘要： The present invention relates to a novel proton-conducting polymer membrane based on polyazoles which can, because of its excellent chemical and thermal properties, be used in a variety of ways and is particularly useful as polymer electrolyte membrane (PEM) to produce membrane electrode units for PEM fuel cells.
摘要翻译： 本发明涉及一种基于多唑的新型质子导电聚合物膜，由于其优异的化学和热性能可以以多种方式使用，并且特别可用作聚合物电解质膜（PEM）以产生膜电极单元 用于PEM燃料电池。
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