Stable compositions of water-soluble amino-and alkenyl-functional organosiloxanes, process for their preparation and their use
    31.
    发明授权
    Stable compositions of water-soluble amino-and alkenyl-functional organosiloxanes, process for their preparation and their use 有权
    水溶性氨基和烯基官能的有机硅氧烷的稳定组合物,其制备方法及其应用

    公开(公告)号:US06255513B1

    公开(公告)日:2001-07-03

    申请号:US09300448

    申请日:1999-04-28

    IPC分类号: C07F710

    摘要: The present invention relates to a stable composition of water-soluble organosiloxanes obtained by reacting a) a water-soluble amino-functional alkoxysilane with at least one water-insoluble alkenyl-functional alkoxysilane b) by adding water to form a mixture, and c) removing the alcohol formed during step b) from the mixture, where the amino-functional alkoxysilane and the water are used in the reaction at least in amounts such that substantially all of the alkoxy groups of the water-insoluble silane can react and such that when a resulting composition is diluted with water, essentially no alcohol is liberated by hydrolysis, and the composition, during an/or after the reaction, has a pH of from 2 to 6, the pH being preferably adjusted by adding an organic or inorganic, optionally aqueous, acid. In addition, the present invention discloses a process for the preparation of such a composition and also its use.

    摘要翻译: 本发明涉及水溶性有机硅氧烷的稳定组合物,该组合物通过使水溶性氨基官能化烷氧基硅烷与至少一种水不溶性烯基官能烷氧基硅烷b)反应而得到,所述组合物通过加入水以形成混合物,和c)除去醇 在步骤b)中形成的步骤b)中,其中氨基官能的烷氧基硅烷和水在反应中使用至少使得水不溶性硅烷的基本上所有的烷氧基基本上可以反应,并且使得当得到的组合物 用水稀释,基本上没有通过水解释出醇,并且在反应过程中或之后,组合物的pH为2-6,优选通过加入有机或无机的任选含水酸来调节pH 。 此外,本发明公开了一种制备这种组合物的方法及其用途。

    Modified nacreous luster pigments for water paint systems
    33.
    发明授权
    Modified nacreous luster pigments for water paint systems 失效
    用于水漆系统的改性珍珠光泽颜料

    公开(公告)号:US06176918B1

    公开(公告)日:2001-01-23

    申请号:US09077121

    申请日:1998-05-22

    IPC分类号: C09C100

    摘要: Modified pearl luster pigments for waterborn coating systems, based on a platelet-form substrate coated with metal oxides and, located on the topmost metal oxide layer, a top layer consisting of at least two oxides and/or mixed oxides from the group consisting of silicon dioxide, aluminium oxide, cerium oxide, titanium oxide and zirconium oxide, and on a water-based oligomeric silane system. The oligomeric silane system can be described, for example, by the following approximate structure: [HO[Si(A)(OH)z(CH3)1−zO]a[Si(B)(OH)y(CH3)1−yO]b[Si(E)(OH)w(CH3)1−wO]c[Si(D)(OH)v(CH3)1−vO]dH].(HX)e  (IX) where A=aminoalkyl radical derived from the general formula V, B=glycidyl ether alkyl radical derived from the general formula VI, E=acryloxyalkyl or methacryloxyalkyl radical of the general formula VII, D=alkyl radical of the general formula VIII, HX=monobasic acid, where X=inorganic or organic acid radical such as, for example, chloride, nitrate, formate, acetate, v is equal to 0 or 1 and w is equal to 0 or 1 and y is equal to 0 or 1 and z is equal to 0 or 1 and a+b+c+d≧4 and a≦e≦2a, where 0≦a/(b+c+d)≦3, especially for a/(b+c+d) equal to 0 if a=0 and/or c equal to d equal to 0 and b≧1 and also for 0.5≦a/(b+c+d)≦3.

    摘要翻译: 用于防水涂料体系的改性珍珠光泽颜料,基于涂覆有金属氧化物的片状基材,并且位于最上面的金属氧化物层上,由至少两种由硅组成的组的氧化物和/或混合氧化物组成的顶层 二氧化硅,氧化铝,氧化铈,氧化钛和氧化锆,以及水性低聚硅烷体系。 低聚硅烷体系可以例如通过以下近似结构来描述:其中A =衍生自通式V的氨基烷基,B =衍生自通式VI的缩水甘油醚烷基,E =一般的丙烯酰氧基烷基或甲基丙烯酰氧基烷基 式VII,D =通式VIII的烷基,HX =一元酸,其中X =无机或有机酸基,例如氯化物,硝酸盐,甲酸盐,乙酸盐,v等于0或1,w为 等于0或1,y等于0或1,z等于0或1,a + b + c + d> = 4,a <= e <= 2a,其中0 <= a /(b + c + d)<= 3,特别是对于a = 0和/或c等于d等于0且b> = 1而且对于0.5 <= a /( b + c + d)<= 3。