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31.发明授权Methods addressing aging in flocculated molecular sieve catalysts for hydrocarbon conversion processes 有权解决用于烃转化过程的絮凝分子筛催化剂中的老化的方法公开(公告)号：US07732537B2
公开(公告)日：2010-06-08
申请号：US12021918
申请日：2008-01-29
CPC分类号： C08F10/00 , B01J29/06 , B01J29/7015 , B01J29/84 , B01J29/85 , B01J37/0045 , B01J2229/40 , B01J2229/42 , C07C1/20 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/06 , C07C11/04 , C08F4/16 , C08F4/12
摘要： One aspect of the invention relates to a method for formulating a molecular sieve catalyst composition, the method comprising the steps of: (a) providing a synthesized molecular sieve having been recovered in the presence of a flocculant; (b) thermally treating the synthesized molecular sieve at a temperature from about 50° C. to about 250° C. and under other conditions sufficient to form a thermally treated synthesized molecular sieve having a first LOI less than 26% and a first micropore surface area; (c) aging the thermally treated synthesized molecular sieve for at least one year; (d) analyzing the aged, thermally treated molecular sieve to determine a second micropore surface area, wherein the second micropore surface area is 3% or less lower than the first micropore surface area; and (e) combining the aged, thermally treated synthesized molecular sieve, a binder, and optionally a matrix material to produce an aged, formulated molecular sieve catalyst composition.
摘要翻译： 本发明的一个方面涉及一种配制分子筛催化剂组合物的方法，该方法包括以下步骤：（a）提供在絮凝剂存在下回收的合成分子筛; （b）在约50℃至约250℃的温度和在足以形成具有第一LOI小于26％的热处理合成分子筛的其它条件下热处理合成的分子筛和第一微孔表面 区; （c）将经热处理的合成分子筛老化至少一年; （d）分析老化的热处理分子筛以确定第二微孔表面积，其中第二微孔表面积比第一微孔表面积低3％或更低; 和（e）将老化的热处理合成分子筛，粘合剂和任选的基质材料组合以制备老化的配制分子筛催化剂组合物。
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公开(公告)号：US07071136B2
公开(公告)日：2006-07-04
申请号：US10442586
申请日：2003-05-21
IPC分类号： B01J29/06
CPC分类号： B01J37/0045 , B01J29/06 , B01J29/85 , C07C1/20 , C07C2529/83 , C07C2529/85 , C10G2400/20 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： This invention is directed to a hardened molecular sieve catalyst composition, a method of making the composition and a method of using the composition. The catalyst composition is made by mixing together molecular sieve, liquid, and an effective hardening amount of a dried molecular sieve catalyst to form a slurry. The slurry is dried, and then calcined to form the hardened molecular sieve catalyst composition. The hardened molecular sieve catalyst is highly attrition resistant.
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公开(公告)号：US07977521B2
公开(公告)日：2011-07-12
申请号：US12136843
申请日：2008-06-11
IPC分类号： C07C1/00
CPC分类号： C10G3/62 , B01J29/90 , B01J2038/005 , C10G3/49 , C10G2300/4006 , C10G2300/4012 , C10G2300/703 , C10G2300/802 , C10G2400/20 , Y10S585/906 , Y10S585/91
摘要： This invention, in one embodiment, is drawn to a process for forming olefin product by contacting an oxygenate with an olefin-forming catalyst under supercritical conditions to form an olefin product. This invention also relates to methods for activating molecular sieve catalyst, regenerating molecular sieve catalyst, and forming and/or disposing a co-catalyst within a molecular sieve catalyst, each under supercritical conditions.
摘要翻译： 在一个实施方案中，本发明涉及通过在超临界条件下使含氧物与形成烯烃的催化剂接触以形成烯烃产物来形成烯烃产物的方法。 本发明还涉及分子筛催化剂的活化方法，再生分子筛催化剂，以及在分子筛催化剂中，在超临界条件下形成和/或配置助催化剂。
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公开(公告)号：US07381853B2
公开(公告)日：2008-06-03
申请号：US11064370
申请日：2005-02-22
申请人： Luc R. M. Martens , John Stephen Godsmark , Marcel J. Janssen , Georges M. K. Mathys , Raphael F. Caers , Hubertus J. Beckers , J. Richard Shutt , Eddy Van Driessche
发明人： Luc R. M. Martens , John Stephen Godsmark , Marcel J. Janssen , Georges M. K. Mathys , Raphael F. Caers , Hubertus J. Beckers , J. Richard Shutt , Eddy Van Driessche
IPC分类号： C10M105/04
CPC分类号： C07C29/16 , C07C1/20 , C07C2/10 , C07C2/12 , C07C2/18 , C07C11/02 , C07C2523/755 , C07C2527/173 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/50 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2529/83 , C07C2529/85 , Y02P30/42 , C07C31/12
摘要： A method of making a higher olefin product from a C4+ fraction separated from the hydrocarbon product produced by an oxygenate to olefin reaction unit. The C4+ fraction primarily contains butenes which may be directed to a higher olefin reaction unit without removing isobutenes, butanes, and/or butadiene. The C4+ fraction is particularly well suited for the production of higher olefins because of its high olefin content, low branching number, and low contaminent levels. The invention is also directed to an olefin product composition that is produced by contacting the C4+ fraction with an oligomerization catalyst. The olefin composition is characterized by a relatively high octene content, and octene with a branching number less than 1.4.
摘要翻译： 从由含氧化合物产生的烃产物与烯烃反应单元分离的C 4 H 4 O + +馏分制备较高级烯烃产物的方法。 C 4 S 4+ + / - >级分主要包含可以引导到较高级烯烃反应单元而不除去异丁烯，丁烷和/或丁二烯的丁烯。 由于其高烯烃含量，低分支数和低污染物水平，C 4 S 4 O + + / O 2馏分特别适用于生产高级烯烃。 本发明还涉及一种烯烃产物组合物，该烯烃产物组合物是通过使低分子化催化剂与C 4+ 4+ 烯烃组合物的特征在于具有相对较高的辛烯含量和分支数小于1.4的辛烯。
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公开(公告)号：US07223714B2
公开(公告)日：2007-05-29
申请号：US10981269
申请日：2004-11-04
IPC分类号： B01J27/182
CPC分类号： B01J8/18 , B01J8/0015 , B01J8/02 , B01J2208/00548 , B01J2208/00752 , B01J2208/00769 , C07C1/20 , C10G3/49 , C10G3/62 , C10G2300/708 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： The invention is directed to methods of transfering catalyst particles into and within reaction systems. The reaction systems are those that use catalysts that comprise molecular sieves, particularly metalloaluminophosphate molecular sieves, especially metalloaluminophosphate molecular sieves which are susceptible to loss of catalytic activity due to contact with water molecules. The transfer methods provide appropriate mechanisms for transporting catalyst into and within a reactor to protect against loss of catalytic activity that can occur due to contact with water molecules.
摘要翻译： 本发明涉及将催化剂颗粒转移到反应体系内和在反应体系内的方法。 反应体系是使用包含分子筛的催化剂，特别是金属铝磷酸盐分子筛，特别是金属铝磷酸盐分子筛，它们由于与水分子接触而易于损失催化活性。 转移方法提供用于将催化剂输送到反应器内部和内部的适当机制，以防止由于与水分子接触而可能发生的催化活性的损失。
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公开(公告)号：US06897180B2
公开(公告)日：2005-05-24
申请号：US10295994
申请日：2002-11-15
CPC分类号： B01J29/85 , B01J2229/24 , B01J2229/30 , B01J2229/38 , B01J2229/42 , C07C1/20 , Y02P30/42 , C07C11/02
摘要： The invention is directed to a method of stabilizing metalloaluminophosphate molecular sieves and catalysts derived therefrom. In particular, the invention is directed to a method of treating such molecular sieves with chemisorbed ammonia, which may be easily desorbed before or during use and after storage. The invention is also directed to formulating the molecular sieve into a catalyst useful in a process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
摘要翻译： 本发明涉及一种稳定金属铝磷酸盐分子筛和由其衍生的催化剂的方法。 特别地，本发明涉及用化学吸附的氨处理这种分子筛的方法，其可以在使用之前或之后在储存之前或之后容易地解吸。 本发明还涉及将分子筛配制成可用于从原料，优选含氧化合物原料生产烯烃，优选乙烯和/或丙烯的方法中的催化剂。
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公开(公告)号：US07754933B2
公开(公告)日：2010-07-13
申请号：US11807450
申请日：2007-05-29
CPC分类号： B01J29/85 , B01J29/90 , B01J38/02 , C07C1/20 , C07C2529/85 , Y02P20/52 , Y02P20/584 , C07C11/02
摘要： This invention is directed to a method of rejuvenating a molecular sieve that has decreased catalytic activity as a result of contact with moisture, and a method of using the rejuvenated catalyst to make an olefin product from methanol feed. The molecular sieve can be rejuvenated by heating at a rate sufficient to increase the catalytic activity of the molecular sieve. The molecular sieve is considered to be rejuvenated when the molecular sieve has a CMCPS that is increased by at least 5% relative to that at a heat rate basis of 40° C./min over a temperature range of from 25° C. to 475° C.
摘要翻译： 本发明涉及一种由于与水分接触而使具有降低的催化活性的分子筛再生的方法，以及使用再生催化剂从甲醇进料制备烯烃产物的方法。 分子筛可以通过以足以增加分子筛的催化活性的速度加热来回复。 当分子筛具有相对于在25℃至475℃的温度范围内以40℃/分钟的热速率升高至少5％的CMCPS时，分子筛被认为是恢复活力的 C。
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公开(公告)号：US09428427B2
公开(公告)日：2016-08-30
申请号：US14233183
申请日：2012-06-14
IPC分类号： C07C2/02 , C07C7/12 , C07C7/00 , C07C7/148 , B01J20/06 , B01J20/08 , B01J20/12 , B01J20/18 , B01J20/20 , B01J21/04 , B01J29/70 , C07C2/12 , C07C51/06 , C07C51/08 , C07C51/47 , C07C53/08 , C07C53/122 , B01J20/10
CPC分类号： C07C7/1485 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/186 , B01J20/20 , B01J21/04 , B01J29/70 , B01J2220/606 , C07C2/12 , C07C7/005 , C07C7/12 , C07C7/148 , C07C7/14866 , C07C51/06 , C07C51/08 , C07C51/47 , C07C53/08 , C07C53/122 , C07C2521/04 , C07C2529/06 , C07C2529/70 , Y02P20/52 , C07C11/02 , C07C11/06
摘要： A process is described, such process comprising i) contacting a hydrocarbon feed with a heterogeneous catalyst under conditions suitable to hydrolyze nitriles present in the feed to form a nitrile hydrolysis product comprising ammonia, carboxylic acid and carboxylate salts or a mixture thereof; and ii) removing the nitrile hydrolysis product from the feed. In an embodiment, the hydrocarbon feed comprises olefins and is intended for use in an olefin oligomerization process.
摘要翻译： 描述了一种方法，该方法包括：i）在适于水解进料中存在的腈的条件下使烃进料与多相催化剂接触以形成含有氨，羧酸和羧酸盐的腈水解产物或其混合物; 和ii）从进料中除去腈水解产物。 在一个实施方案中，烃进料包含烯烃并且用于烯烃低聚方法。
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公开(公告)号：US20140330060A1
公开(公告)日：2014-11-06
申请号：US14233192
申请日：2012-06-14
申请人： Hans K. T. Goris , Geraldine Tosin , Luc R. M. Martens , Machteld M. W. Mertens , Silvio Carrettin
发明人： Hans K. T. Goris , Geraldine Tosin , Luc R. M. Martens , Machteld M. W. Mertens , Silvio Carrettin
CPC分类号： C07C7/12 , B01J20/06 , B01J20/08 , B01J20/12 , B01J20/18 , B01J20/186 , B01J20/20 , B01J20/3408 , B01J20/3483 , B01J2220/606 , C07C2/10 , C07C2/12 , C07C2/18 , C07C7/13 , C07C2523/755 , C07C2527/173 , C07C11/02 , C08F110/14 , C08F2500/02
摘要： In a feed clean-up process at least two adsorbents (2, 4) are installed in front of an oligomerization reactor (3). Olefin feed is sent over one adsorbent (2) and the nitrile poisons are adsorbed so that clean feed will enter the reactor (3). Before the adsorbent (2) will be saturated, the feed (1) is sent to the other, fresh adsorbent (4). At the same time oligomerization product from the reactor (3) is used to desorb nitriles from the spent adsorbent (2).
摘要翻译： 在进料清理过程中，至少两个吸附剂（2,4）安装在低聚反应器（3）的前面。 烯烃进料通过一个吸附剂（2）送出，并且吸附有毒物质，使得清洁的进料将进入反应器（3）。 在吸附剂（2）将饱和之前，将进料（1）送到另一个新鲜的吸附剂（4）。 同时使用来自反应器（3）的低聚产物从废吸附剂（2）中解吸出腈。
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公开(公告)号：US07230151B2
公开(公告)日：2007-06-12
申请号：US10891975
申请日：2004-07-15
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , C07C2529/80 , Y02P30/42 , C07C11/02
摘要： This invention is to a process of making olefin, particularly ethylene and propylene, from an oxygenate feed. The invention uses two or more zeolite catalysts. Examples of zeolite catalysts include a first catalyst containing of ZSM-5, and a second catalyst containing a 10-ring molecular sieve, including but not limited to, ZSM-22, ZSM-23, ZSM35, ZSM-48, and mixtures thereof. The ZSM-5 can be unmodified, phosphorous modified, steam modified having a micropore volume reduced to not less than 50% of that of the unsteamed ZSM-5, or various mixtures thereof.
摘要翻译： 本发明是由含氧化合物进料制备烯烃，特别是乙烯和丙烯的方法。 本发明使用两种或更多种沸石催化剂。 沸石催化剂的实例包括含有ZSM-5的第一催化剂和含有10环分子筛的第二催化剂，包括但不限于ZSM-22，ZSM-23，ZSM35，ZSM-48及其混合物。 ZSM-5可以是未改性的，磷改性的，蒸汽改性的，具有减小到不少于未蒸发的ZSM-5或其各种混合物的50％的微孔体积。
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