公开(公告)号：US08534333B2

公开(公告)日：2013-09-17

申请号：US12810774

申请日：2009-02-13

申请人： Takamasa Kitamura ,  Shigeki Ito ,  Kenichi Kitano ,  Takeshi Inohara

发明人： Takamasa Kitamura ,  Shigeki Ito ,  Kenichi Kitano ,  Takeshi Inohara

IPC分类号： B60C11/00

CPC分类号： C08L7/00 ,  B60C1/0016 ,  B60C11/14 ,  B60C2011/0025 ,  C08J9/32 ,  C08J2203/22 ,  C08J2307/00 ,  C08J2309/00 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08K7/22 ,  C08K9/10 ,  C08L9/00 ,  C08L21/00 ,  C08L2666/08

摘要： A tread rubber is made of a rubber composition containing 100 pbw of a diene rubber, 30 to 100 pbw of a reinforcing filler including at least 10 pbw of silica, and 1 to 20 pbw of microcapsules each encapsulating a heat-expandable substance. A sulfur-containing silane coupling agent is mixed in the rubber composition in an amount of 3 to 15 wt. % based on the weight of the silica. A shell material of each microcapsule is made of a thermoplastic resin which essentially contains a nitrile monomer. A vapor pressure of the heat-expandable substance is 1.4 to 3.0 MPa at 150° C. An average diameter of the microcapsules is 20 to 30 μm before vulcanization of the rubber composition. An average diameter of the microcapsules expanded due to the vulcanization is 40 to 80 μm. The tread rubber has a proportion of a cell-occupying area of 5 to 30%.

摘要翻译： 胎面橡胶由含有100pbw的二烯橡胶，30-100pbw的包含至少10pbw的二氧化硅的增强填料和1至20pbw的每个包封热膨胀性物质的微胶囊的橡胶组合物制成。 含硫硅烷偶联剂在橡胶组合物中以3〜15重量％的量混合。 基于二氧化硅的重量％。 每个微胶囊的壳材料由基本上含有腈单体的热塑性树脂制成。 在150℃下，热膨胀性物质的蒸气压为1.4〜3.0MPa。在橡胶组合物硫化之前，微胶囊的平均直径为20〜30μm。 由于硫化而膨胀的微胶囊的平均直径为40-80μm。 胎面橡胶占电池占用面积的比例为5〜30％。

公开(公告)号：US08324286B2

公开(公告)日：2012-12-04

申请号：US12089600

申请日：2006-11-16

申请人： Toshiaki Masuda ,  Ichiro Takahara ,  Kenichi Kitano ,  Katsushi Miki ,  Takeshi Inohara ,  Takeyoshi Fukuda ,  Takayuki Aoki ,  Satoshi Kawanami

发明人： Toshiaki Masuda ,  Ichiro Takahara ,  Kenichi Kitano ,  Katsushi Miki ,  Takeshi Inohara ,  Takeyoshi Fukuda ,  Takayuki Aoki ,  Satoshi Kawanami

IPC分类号： C08J9/228 ,  C08J9/00

CPC分类号： B01J13/14 ,  C08F220/14 ,  C08F220/44 ,  C08F220/48 ,  C08F222/1006 ,  Y10T428/2984

摘要： Heat-expandable microspheres include a shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin, have a maximum expanding ratio not lower than 50 times, and are thermally expanded into hollow particulates having a repeated-compression durability not lower than 75 percent. The method of producing the heat-expandable microspheres includes the steps of dispersing an oily mixture containing a polymerizable component and the blowing agent in an aqueous dispersing medium containing a specific water-soluble compound and polymerizing the polymerizable component contained in the oily mixture.

摘要翻译： 热膨胀性微球包括热塑性树脂的壳和其中包含沸点不高于热塑性树脂的软化点的发泡剂，其最大膨胀比不低于50倍，并且被热膨胀成具有 重复压缩耐久性不低于75％。 制造热膨胀性微球的方法包括以下步骤：将含有可聚合组分和发泡剂的油性混合物分散在含有特定水溶性化合物的水性分散介质中，并使包含在油性混合物中的可聚合组分聚合。

公开(公告)号：US08216952B2

公开(公告)日：2012-07-10

申请号：US12311772

申请日：2007-10-17

申请人： Tatsuya Oki ,  Masateru Kotera ,  Yoshihiro Kando

发明人： Tatsuya Oki ,  Masateru Kotera ,  Yoshihiro Kando

IPC分类号： B32B5/02

CPC分类号： D06M13/02 ,  D06M15/53 ,  D06M15/70 ,  Y10T442/2311 ,  Y10T442/2336

摘要： The object of the present invention is to provide a fabric treating agent to satisfy good sewability required to interior material fabrics for vehicles including automobiles and trains, the good sewability which arises from the trend toward ultrafiner fibers for manufacturing the fabrics, change in fabric structure from weave to knit, and increasing sewing machine speed.The present invention provides the fabric treating agent comprising at least one wax (a) selected from the group consisting of a paraffin wax having a melting point of 60° C. or higher, an oxidized paraffin wax having a melting point of 60° C. or higher, a polyethylene wax having a melting point of 100° C. or higher, and an oxidized polyethylene wax having a melting point of 100° C. or higher; and a nonionic surfactant (b). The present invention also provides a process for producing fabrics applied with the fabric treating agent, and provides vehicle interior material fabrics.

摘要翻译： 本发明的目的是提供一种织物处理剂，以满足包括汽车和火车在内的车辆内部材料织物所需的良好的缝合性，由织造织物的超细纤维的趋势产生的良好缝合性，织物结构的变化 编织编织，增加缝纫机速度。 本发明提供了包含至少一种选自熔点为60℃以上的石蜡，熔点为60℃的氧化石蜡的蜡（a）的织物处理剂。 以上，熔点为100℃以上的聚乙烯蜡和熔点为100℃以上的氧化聚乙烯蜡; 和非离子表面活性剂（b）。 本发明还提供一种用于生产应用了织物处理剂的织物的方法，并提供车辆内部材料织物。

公开(公告)号：US20100199624A1

公开(公告)日：2010-08-12

申请号：US12677253

申请日：2008-09-02

申请人： Shinichi Tatemoto ,  Tatsuo Harada ,  Kaori Kimoto

发明人： Shinichi Tatemoto ,  Tatsuo Harada ,  Kaori Kimoto

IPC分类号： D02G3/02 ,  C08K5/521 ,  D06M15/53 ,  D01H13/30

CPC分类号： D06M13/292 ,  D02G1/04 ,  D06M7/00 ,  D06M13/184 ,  D06M13/207 ,  D06M13/342 ,  D06M2200/40 ,  Y10T428/2933

摘要： The present invention aims to provide a finish for synthetic filament yarn processed in friction false-twist texturing, which decreases broken filaments and ends down in false-twist texturing with a synthetic filament yarn applied with the finish, finish-application emulsion of the finish, synthetic filament yarn applied with the emulsion, manufacturing process of the synthetic filament yarn, and resultant yarns.The finish for synthetic filament yarn processed in friction false-twist texturing of the present invention comprises 40 to 98 wt % of a polyether compound, and essentially comprises components (A) and (B); wherein the component (A) is at least one member selected from the group consisting of (A1) a C1-C10 fatty acid, (A2) a C1-C10 hydroxyfatty acid, (A3) a sarcosine derivative, and salts thereof, and the amount of the component (A) in the finish ranges from 0.05 to 5 wt %; and wherein the component (B) is an alkylphosphate salt and the amount of the component (B) in the finish ranges from 0.01 to 3 wt %.

摘要翻译： 本发明的目的在于提供一种在摩擦假捻加工中加工的合成长丝纱线的精加工，其中使用合成长丝纱线，用精加工的表面处理乳液， 施用乳液的合成长丝纱线，合成长丝纱线的制造过程以及合成纱线。 在本发明的摩擦假捻变形中处理的合成长丝纱线的表面处理包含40至98重量％的聚醚化合物，并且基本上包含组分（A）和（B）; 其中组分（A）为选自（A1）C1-C10脂肪酸，（A2）C1-C10羟基脂肪酸，（A3）肌氨酸衍生物及其盐的至少一种，和 组分（A）的含量在0.05〜5重量％范围内; 并且其中组分（B）是烷基磷酸盐，并且组合物（B）的量在0.01至3重量％范围内。

公开(公告)号：US20090176098A1

公开(公告)日：2009-07-09

申请号：US12067771

申请日：2006-10-04

申请人： Toshiaki Masuda ,  Kenichi Kitano ,  Katsushi Miki ,  Takeshi Inohara ,  Takayuki Aoki

发明人： Toshiaki Masuda ,  Kenichi Kitano ,  Katsushi Miki ,  Takeshi Inohara ,  Takayuki Aoki

IPC分类号： C08J9/16 ,  B32B1/00

CPC分类号： B01J13/14 ,  Y10T428/2982 ,  Y10T428/2984 ,  Y10T428/2985 ,  Y10T428/2987 ,  Y10T428/2998

摘要： A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microspheres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.

摘要翻译： 热膨胀性微球的方法包括使用热塑性树脂的壳和封入其中的沸点不高于热塑性树脂的软化点的非氟发泡剂。 该方法包括将含有可聚合组分的油性混合物，发泡剂和含有过氧化二碳酸酯的聚合引发剂分散在水性分散介质中以使包含在油性混合物中的可聚合组分聚合的步骤。 所得到的热膨胀性微球体的外壳不易于其理论值变薄，在其壳内含有最少量的树脂颗粒，并且具有优异的热膨胀性能。

公开(公告)号：US20090105394A1

公开(公告)日：2009-04-23

申请号：US12253311

申请日：2008-10-17

申请人： Takamasa Kitamura ,  Makio Mori ,  Naoki Kushida ,  Toshiaki Masuda ,  Kenichi Kitano ,  Yoshiaki Shirakabe

发明人： Takamasa Kitamura ,  Makio Mori ,  Naoki Kushida ,  Toshiaki Masuda ,  Kenichi Kitano ,  Yoshiaki Shirakabe

IPC分类号： C08L21/00

CPC分类号： C08K9/10 ,  C08J9/32 ,  C08J2203/22 ,  C08J2321/00 ,  C08L21/00 ,  C08L51/00 ,  C08L51/003 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/04

摘要： A rubber composition for a tire containing (i) 100 parts by weight of a diene-based rubber and (ii) 0.5 to 25 parts by weight of a heat-expandable microcapsule including a shell, and a substance capable of vaporizing or expanding under heating to thereby generate a gas and a nonpolar oil, both encapsulated in the shell,wherein the shell is made of a thermoplastic resin obtained by polymerization of a nitrile-based monomer (I), a monomer (II) having an unsaturated double bond and a carboxyl group in the molecule thereof, an optional monomer (III) having two or more polymerizable double bonds, and an optional copolymerizable monomer (IV) for adjusting the expansion properties.

摘要翻译： 一种轮胎用橡胶组合物，其含有（i）100重量份的二烯系橡胶和（ii）0.5〜25重量份的包含壳的热膨胀性微囊和能够在加热下蒸发或膨胀的物质 从而产生包封在壳中的气体和非极性油，其中壳由通过腈基单体（I），具有不饱和双键的单体（II）和具有不饱和双键的单体（II））聚合而获得的热塑性树脂 分子中的羧基，具有两个或更多个可聚合双键的任选单体（III）和用于调节膨胀性质的任选的可共聚单体（IV）。

公开(公告)号：US06858043B2

公开(公告)日：2005-02-22

申请号：US10147852

申请日：2002-05-20

申请人： Yo Shingai ,  Ikuya Ujino ,  Hirohumi Ishida ,  Tatsuo Harada

发明人： Yo Shingai ,  Ikuya Ujino ,  Hirohumi Ishida ,  Tatsuo Harada

IPC分类号： D06M15/53 ,  D06M10/00 ,  D06M13/00 ,  D06M13/17 ,  D06M13/224 ,  D06M13/248 ,  D06M13/256 ,  D06M13/292 ,  D06N13/256

CPC分类号： D06M13/17 ,  D06M2200/40

摘要： A finish for synthetic filament to be processed in friction-texturing, which is applicable to various yarns and in a wide range of texturing speed, having been considered as difficult finish application field, such as low-speed friction texturing (with contact heaters), high-speed friction texturing (with non-contact heaters), coarse denier yarns and fine denier yarns, with satisfactory POY package buildup and POY release from packages, minimum fluffs and loops of POY, and with minimum fluffs of DTY and minimum fume and stain on heaters in texturing; and which contains 50 to 85 weight percent of Component A and 10 to 30 weight percent of Component B, having the following structures and a total ranging from 60 to 95 weight percent: Component A having a structure of R1[O(C2H4O)x.(C3H6O)yH]z, wherein R1 is a trihydric or tetrahydric alcohol residue, z is an integer of 3 or 4 corresponding to the number of hydroxyl groups in R1, and x and y are integers of 1 or greater attaining a weight ratio of oxytehylene group and oxypropylene group from 90:10 to 60:40 and a molecular weight of the resultant compound from 1000 to 4000; and Component B having a structure of R2[O(C2H4O)a.(C3H6O)b]COR3, wherein R2 is a C4-18 monohydric alcohol residue, R3 is a C7-17 fatty acid residue, a is an integer from 3 to 15, b is an integer from 0 to 12 and the total of a and b ranges from 6 to 15.

摘要翻译： 在摩擦纹理中加工的合成长丝的精加工，其适用于各种纱线和宽范围的纹理速度，被认为是难以完成的涂覆领域，例如低速摩擦纹理（具有接触式加热器）， 高速摩擦纹理（非接触加热器），粗旦尼尔纱和细旦尼尔纱线，具有令人满意的POY包装积累和POY从包装中释放，最小绒毛和POY环，并具有DTY和最小烟雾和污渍的最小绒毛 加热器在纹理; 并且其包含50至85重量％的组分A和10至30重量％的组分B，其具有以下结构，总计为60至95重量％：具有R 1 [O（C 2 H 4 O）x的结构的组分A。 （C 3 H 6 O）y H] z，其中R 1是三元醇或四元醇残基，z是对应于R 1中羟基数的3或4的整数，x和y是1或更大的整数，其重量比为 氧乙烯基和氧丙烯基，90:10至60:40，所得化合物的分子量为1000至4000; 并且具有R 2 [O（C 2 H 4 O）a。（C 3 H 6 O）b] COR 3的结构的组分B，其中R 2是C 4--18一元醇残基，R 3是C 7-17脂肪酸残基，a是3至15的整数 b为0〜12的整数，a和b的合计为6〜15。

公开(公告)号：US6106946A

公开(公告)日：2000-08-22

申请号：US147017

申请日：1998-09-11

申请人： Koji Tanaka ,  Toshihiko Shibamoto ,  Akihiko Nishizaki

发明人： Koji Tanaka ,  Toshihiko Shibamoto ,  Akihiko Nishizaki

IPC分类号： B01J13/02 ,  C09D5/23 ,  H01F1/44

CPC分类号： H01F1/44 ,  B01J13/02 ,  Y10T428/2984 ,  Y10T428/2987

摘要： Provided are microcapsules enclosing therein a magnetic fluid, which are useful for imparting sound-absorbing and insulating ability to building materials, etc. by incorporation thereinto or adhesion thereto by means of an adhesive, and processes for producing the microcapsules. The heat-expandable microcapsule of the present invention comprises (i) a shell composed of a thermoplastic resin and (ii) a magnetic fluid which is a dispersion of magnetic substance fine particles having an average particle diameter of 5-200 nm in a hydrophobic organic solvent and a hydrophobic liquid foaming agent, both enclosed in the shell. The hollow microcapsule of the present invention comprises (i) a shell composed of a thermoplastic resin, and (ii) a magnetic fluid which is a dispersion of magnetic substance fine particles having an average particle diameter of 5-200 nm in a hydrophobic organic solvent and a vacant cell both included in the shell. The coating material of the present invention comprises at least one of these sound-absorbing and insulating microcapsules.

摘要翻译： PCT No.PCT / JP97 / 00646 Sec。 371日期：1998年9月11日 102（e）日期1998年9月11日PCT 1997年3月4日PCT公布。 WO97 / 33686 PCT公开号 日期1997年9月18日提供了包含磁性流体的微胶囊，其可用于通过结合到其中来赋予建筑材料等的吸声和绝缘能力或通过粘合剂粘附到其上，以及用于生产微胶囊的方法。 本发明的热膨胀性微胶囊包含：（i）由热塑性树脂构成的壳，和（ii）作为在疏水性有机物中具有平均粒径为5〜200nm的磁性物质微粒的分散体的磁性流体 溶剂和疏水性液体发泡剂，均封入壳中。 本发明的中空微胶囊包含（i）由热塑性树脂构成的壳，和（ii）在疏水性有机溶剂中作为平均粒径为5〜200nm的磁性物质微粒的分散体的磁性液体 和一个空的电池都包含在外壳中。 本发明的涂料包括这些吸音和绝缘微胶囊中的至少一种。

公开(公告)号：US5559202A

公开(公告)日：1996-09-24

申请号：US466422

申请日：1995-06-06

申请人： Hirofumi Yoshikawa

发明人： Hirofumi Yoshikawa

IPC分类号： B01J13/00 ,  B01J13/14 ,  C08F2/00 ,  C08F2/18 ,  C08F2/32 ,  C06F2/18

CPC分类号： C08F2/18 ,  Y10S526/909 ,  Y10S526/93

摘要： The present invention provides new non-spherical microparticles. The microparticles are a hemisphere or a half elliptic sphere having a big opening at the central portion, say bowl-shape microparticles, and a water uptake of from 80 to 140 ml/100 g, which can be produced by suspension polymerization of polymerizable monomers in the presence of crosslinking agents and hydrophobic liquids in water. The microparticle of the present invention has an excellent extending ability, adhesiveness and water uptake. The new bowl-shape microparticles having the big opening at the center can be easily produced according to the present invention, and the size and shape can be easily controlled.

摘要翻译： 本发明提供新的非球形微粒。 微粒是在中心部分具有大开口的半球形或半椭圆形球体，例如碗形微粒，80至140ml / 100g的吸水率，其可通过可聚合单体的悬浮聚合 交联剂和疏水性液体在水中的存在。 本发明的微粒具有优异的延伸能力，粘合性和吸水性。 根据本发明，可以容易地制造在中心具有大开口的新的碗状微粒，并且可以容易地控制尺寸和形状。

公开(公告)号：US5536756A

公开(公告)日：1996-07-16

申请号：US311714

申请日：1994-09-23

申请人： Sueo Kida ,  Kenichi Kitano ,  Kyuno Seiji

发明人： Sueo Kida ,  Kenichi Kitano ,  Kyuno Seiji

IPC分类号： B01J13/02 ,  B01J13/14 ,  C01B37/00 ,  B01J13/18 ,  C08J9/14

CPC分类号： B01J13/14 ,  Y10T428/2987

摘要： The present invention provides a thermoplastic microcapsule which is softened by heat, has a good thermoexpandability, and can provide a MICROBALLOON which shows a high heat resistance after thermoexpanded; such a thermoexpandable microcapsule is composed of a shell and an expanding agent therein, in which said shell is made from a copolymer essentially consisting of a polymerizable monomer having two or more polymerizable double bonds and a monomer which can produce a homopolymer having a high glass transition temperature, and said expanding agent is vaporizable at a temperature lower than the softening temperature of the copolymer.

摘要翻译： 本发明提供一种通过热软化的热塑性微胶囊，具有良好的热膨胀性，并且可以提供在热膨胀后显示出高耐热性的MICROBALLOON; 这种可热膨胀的微胶囊由壳和其中的发泡剂组成，其中所述外壳由基本上由具有两个或多个可聚合双键的可聚合单体组成的共聚物和可以生产具有高玻璃化转变率的均聚物的单体制成 并且所述发泡剂在低于共聚物的软化温度的温度下可蒸发。