中科微点-全球专利检索

  1. Login
  2. Sign Up

Search Results

40 records (took 0.018 seconds)

    Catalyst compositions and process of making polyketones therewith
    36.
    发明授权
    Catalyst compositions and process of making polyketones therewith 失效
    催化剂组合物及其制备方法

    公开(公告)号：US5808121A

    公开(公告)日：1998-09-15

    申请号：US599704

    申请日：1996-02-12

    Applicant: Wilhelm Keim ,  Stefan Mecking

    Inventor： Wilhelm Keim ,  Stefan Mecking

    IPC: B01J31/24 ,  C08G67/02 ,  C07F15/00 ,  B01J27/185 ,  B01J31/00 ,  C07F17/02

    CPC classification number: B01J31/2247 ,  B01J31/2291 ,  B01J31/2404 ,  C08G67/02 ,  B01J2231/10 ,  B01J2231/12 ,  B01J2531/80 ,  B01J2531/824

    Abstract: There is disclosed a catalyst composition prepared by reacting together: (a) a source of a Group VIII metal, (b) a compound of the formula (I) R.sup.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3 (I) where R.sup.1 and R.sup.2 are independently an unsubstituted or substituted alkyl, cycloalkyl or aryl group, R.sup.3 is hydrogen, an unsubstituted or substituted alkyl, cycloalkyl or aryl group and R.sup.4 is a divalent organic group and (c) a source of an anion which is either non-coordinating or weakly-coordinating to the Group VIII metal. The catalyst compositions are used in the preparation of polyketones from carbon monoxide and one or more olefins. Novel compounds of the formula �(.eta..sup.3 -allyl)Pd(R.sub.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3)!A where A is a weakly or non-coordinating anion are useful as such catalysts.

    Abstract translation: 公开了通过一起反应制备的催化剂组合物：（a）VIII族金属源，（b）式（I）的化合物，R1R2PR4CO2R3（Ⅰ），其中R1和R2独立地是未取代或取代的烷基，环烷基 或芳基，R 3是氢，未取代或取代的烷基，环烷基或芳基，R 4是二价有机基团，和（c）与VIII族金属是非配位或弱配位的阴离子源。 催化剂组合物用于从一氧化碳和一种或多种烯烃制备聚酮。 式[（η3-烯丙基）Pd（R1R2PR4CO2R3）] A的新型化合物，其中A是弱或非配位阴离子可用作这种催化剂。

    Palladium phosphine ligand catalyst
    37.
    发明授权
    Palladium phosphine ligand catalyst 失效
    钯膦配体催化剂

    公开(公告)号：US5525566A

    公开(公告)日：1996-06-11

    申请号：US218518

    申请日：1994-03-25

    Applicant: Wilhelm Keim ,  Stefan Mecking

    Inventor： Wilhelm Keim ,  Stefan Mecking

    IPC: B01J31/24 ,  C08G67/02 ,  B01J31/00

    CPC classification number: B01J31/2247 ,  B01J31/2291 ,  B01J31/2404 ,  C08G67/02 ,  B01J2231/10 ,  B01J2231/12 ,  B01J2531/80 ,  B01J2531/824

    Abstract: There is disclosed a catalyst composition prepared by reacting together:(a) a source of a Group VIII metal,(b) a compound of the formula (I)R.sup.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3 (I) where R.sup.1 and R.sup.2 are independently an unsubstituted or substituted alkyl, cycloalkyl or aryl group, R.sup.3 is hydrogen, an unsubstituted or substituted alkyl, cycloalkyl or aryl group and R.sup.4 is a divalent organic group and(c) a source of an anion which is either non-coordinating or weakly-coordinating to the Group VIII metal.The catalyst compositions are used in the preparation of polyketones from carbon monoxide and one or more olefins. Novel compounds of the formula [(.eta..sup.3 -allyl)Pd(R.sup.1 R.sup.2 PR.sup.4 CO.sub.2 R.sup.3)]Y where Y is a weakly or non-coordinating anion are useful as such catalysts.

    Abstract translation: 公开了通过一起反应制备的催化剂组合物：（a）VIII族金属源，（b）式（I）的化合物，R1R2PR4CO2R3（Ⅰ），其中R1和R2独立地是未取代或取代的烷基，环烷基 或芳基，R 3是氢，未取代或取代的烷基，环烷基或芳基，R 4是二价有机基团，和（c）与VIII族金属是非配位或弱配位的阴离子源。 催化剂组合物用于从一氧化碳和一种或多种烯烃制备聚酮。 其中Y是弱或非配位阴离子的式[（η3-烯丙基）Pd（R1R2PR4CO2R3）] Y的新化合物可用作这样的催化剂。

    Nickel complexes in diol solvents and their use as oligomerization catalyst precursors
    38.
    发明授权
    Nickel complexes in diol solvents and their use as oligomerization catalyst precursors 失效
    二醇溶剂中的镍络合物及其作为低聚催化剂前体的用途

    公开(公告)号：US4377499A

    公开(公告)日：1983-03-22

    申请号：US207177

    申请日：1980-11-17

    Applicant: Albert E. O'Donnell ,  Clarence R. Gum

    Inventor： Albert E. O'Donnell ,  Clarence R. Gum

    IPC: B01J31/24 ,  C07C2/36 ,  B01J31/12

    CPC classification number: B01J31/2247 ,  B01J31/146 ,  B01J31/1875 ,  B01J31/2291 ,  C07C2/36 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2527/128 ,  C07C2531/04 ,  C07C2531/14 ,  C07C2531/24

    Abstract: Ethylene is oligomerized to even numbered alpha-monoolefins principally in the C.sub.4 to C.sub.40 range with minimal concomittant production of high molecular weight polyethylene by reacting ethylene in a diol solvent in an oligomerization reaction zone at elevated pressure with a nickel complex catalyst composition produced by combining in the reaction zone, (a) a stable preformed complex of nickel, ethylene and hydride in a diol solvent, said complex being prepared by contactng in a diol solvent and in the presence of ethylene, a nickel salt, a base and a boron hydride transfer agent and (b) a suitable bidentate ligand; the stable nickel complex solution and the bidentate ligand being added in separate portions to the reaction zone. These stable complexes of nickel, ethylene and hydride in diol solution are considered to be novel oligomerization catalyst precursor compositions.

    Abstract translation: 乙烯在C4至C40范围内低聚至偶数的α-单烯烃，最低限度的同时生产高分子量聚乙烯，通过乙烯在二醇溶剂中在低聚反应区中在升高的压力下与镍络合催化剂组合物 反应区，（a）镍，乙烯和氢化物在二醇溶剂中的稳定的预制配合物，所述络合物通过在二醇溶剂中接触并在乙烯，镍盐，碱和硼氢化物转移 试剂和（b）合适的二齿配体; 稳定的镍络合物溶液和二齿配体分别加入反应区。 镍，乙烯和氢化物在二醇溶液中的稳定配合物被认为是新的低聚催化剂前体组合物。

    Nickel ylides
    39.
    发明授权
    Nickel ylides 失效
    镍叶立德

    公开(公告)号：US4293502A

    公开(公告)日：1981-10-06

    申请号：US179079

    申请日：1980-08-18

    Applicant: David L. Beach ,  James J. Harrison

    Inventor： David L. Beach ,  James J. Harrison

    IPC: C07C2/32 ,  B01J31/00 ,  B01J31/18 ,  B01J31/22 ,  C07B61/00 ,  C07C1/00 ,  C07C2/36 ,  C07C11/02 ,  C07C67/00 ,  C07F9/535 ,  C07F9/54 ,  C07F9/72 ,  C07F9/74 ,  C07F9/90 ,  C07F9/92 ,  C07F15/04 ,  C08F110/02

    CPC classification number: C07F9/5407 ,  B01J31/2247 ,  C07C2/36 ,  C07F15/04 ,  C07F15/045 ,  C07F9/5352 ,  C07F9/5442 ,  C07F9/723 ,  C07F9/743 ,  C07F9/904 ,  C07F9/92 ,  C08F110/02 ,  B01J2231/20 ,  B01J2531/847 ,  B01J2540/32 ,  B01J31/1895

    Abstract: A new group of nickel ylides is provided that is highly active at relatively low operating temperatures and pressures in the oligomerization of ethylene. The compounds can be defined by the following Formula I: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are either alike or different members selected from the group consisting of hydrogen, alkyl radicals having from about one to about 24 carbon atoms, preferably from about one to about 10 carbon atoms; aryl radicals having from about six to about 20 carbon atoms, preferably from about six to about 10 carbon atoms; alkenyl radicals having from about two to about 30 carbon atoms, preferably from about two to about 20 carbon atoms; cycloalkyl radicals having from about three to about 40 carbon atoms, preferably from about three to about 30 carbon atoms; aralkyl and alkaryl radicals having from about six to about 40 carbon atoms, preferably from about six to about 30 carbon atoms; a halogen radical selected from the group consisting of fluorine, chlorine, bromine and iodine, preferably chlorine; a hydroxyl group; an alkoxy or aryloxy group; and a hydrocarbyl group, such as defined above, carrying halogen, hydroxyl or alkoxy or aryloxy; provided that at least one, preferably from about one to about four, of each of R.sub.1 to R.sub.8 is a sulfonato group (--SO.sub.3.sup.-) or an alkyl, aryl, alkenyl, cycloalkyl, aralkyl or alkaryl group carrying a sulfonato group; M is sulfur or oxygen, preferably oxygen; E is phosphorus, arsenic, antimony or nitrogen, preferably phosphorus; and F is phosphorus, arsenic or antimony, preferably phosphorus.

    Abstract translation: 提供了一组新的镍内鎓盐，其在乙烯低聚中的相对低的操作温度和压力下具有高活性。 化合物可以由下式I定义：其中R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8为相同或不同的选自氢，具有约一个 至约24个碳原子，优选约1至约10个碳原子; 具有约6至约20个碳原子，优选约6至约10个碳原子的芳基; 具有约2至约30个碳原子，优选约2至约20个碳原子的烯基; 具有约3至约40个碳原子，优选约3至约30个碳原子的环烷基; 具有约6至约40个碳原子，优选约6至约30个碳原子的芳烷基和烷芳基; 选自氟，氯，溴和碘的卤素，优选氯; 羟基; 烷氧基或芳氧基; 和如上所定义的含有卤素，羟基或烷氧基或芳氧基的烃基; 条件是R 1至R 8中的至少一个，优选约1至约4个为磺酸基（-SO 3 - ）或带有磺酸基的烷基，芳基，烯基，环烷基，芳烷基或烷芳基; M是硫或氧，优选氧; E是磷，砷，锑或氮，优选磷; F是磷，砷或锑，优选磷。

    Nickel complexes in diol solvents and their use as oligomerization catalyst precursors
    40.
    发明授权
    Nickel complexes in diol solvents and their use as oligomerization catalyst precursors 失效
    二醇溶剂中的镍络合物及其作为低聚催化剂前体的用途

    公开(公告)号：US4260844A

    公开(公告)日：1981-04-07

    申请号：US116687

    申请日：1980-01-30

    Applicant: Albert E. O'Donnell ,  Clarence; R. Gum

    Inventor： Albert E. O'Donnell ,  Clarence; R. Gum

    IPC: C07C2/34 ,  B01J31/24 ,  C07B61/00 ,  C07C1/00 ,  C07C2/36 ,  C07C11/02 ,  C07C67/00 ,  C07C2/02

    CPC classification number: B01J31/2247 ,  B01J31/1875 ,  C07C2/36 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2527/128 ,  C07C2531/04 ,  C07C2531/14 ,  C07C2531/24

    Abstract: Ethylene is oligomerized to even numbered alpha-monoolefins principally in the C.sub.4 to C.sub.40 range with minimal concomittant production of high molecular weight polyethylene by reacting ethylene in a diol solvent in an oligomerization reaction zone at elevated pressure with a nickel complex catalyst composition produced by combining in the reaction zone, (a) a stable preformed complex of nickel, ethylene and hydride in a diol solvent, said complex being prepared by contacting in a diol solvent and in the presence of ethylene, a nickel salt, a base and a boron hydride transfer agent and (b) a suitable bidentate ligand; the stable nickel complex solution and the bidentate ligand being added in separate portions to the reaction zone. These stable complexes of nickel, ethylene and hydride in diol solution are considered to be novel oligomerization catalyst precursor compositions.

    Abstract translation: 乙烯在C4至C40范围内低聚至偶数的α-单烯烃，最低限度的同时生产高分子量聚乙烯，通过乙烯在二醇溶剂中在低聚反应区中在升高的压力下与镍络合催化剂组合物 反应区，（a）镍，乙烯和氢化物在二醇溶剂中的稳定的预制配合物，所述络合物通过在二醇溶剂中和在乙烯，镍盐，碱和硼氢化物转移剂的存在下接触来制备 试剂和（b）合适的二齿配体; 稳定的镍络合物溶液和二齿配体分别加入反应区。 镍，乙烯和氢化物在二醇溶液中的稳定配合物被认为是新的低聚催化剂前体组合物。

Patent Agency Ranking