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    Diene-based carboxylate anion and salt thereof, and polymerizable or curable composition thereof
    31.
    发明授权
    Diene-based carboxylate anion and salt thereof, and polymerizable or curable composition thereof 有权
    二烯系羧酸根阴离子及其盐及其可聚合或可固化的组合物

    公开(公告)号：US09499466B2

    公开(公告)日：2016-11-22

    申请号：US13877751

    申请日：2011-10-05

    Applicant: Tomomasa Kaneko

    Inventor： Tomomasa Kaneko

    IPC: C07C57/13 ,  C07C59/60 ,  C07F5/00 ,  C07F7/00 ,  C07F7/22 ,  C08F136/20 ,  C07C69/734 ,  C07F9/00 ,  C07F9/94 ,  C07F15/02 ,  C07F15/04

    CPC classification number: C07C57/13 ,  C07C59/60 ,  C07C69/734 ,  C07F5/00 ,  C07F7/003 ,  C07F7/2224 ,  C07F9/005 ,  C07F9/94 ,  C07F15/025 ,  C07F15/045 ,  C08F136/20

    Abstract: The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

    Abstract translation: 要求保护的发明提供了一种未经过研究的新化合物，即含有特定结构的二烯羧酸盐阴离子及其盐。 要求保护的发明还可以提供一种易于溶于一般有机溶剂，反应性稀释剂和树脂的二烯羧酸盐阴离子及其盐，特别是其金属盐，在常温下可根据结构处于液态， 具有高聚合性。 这些聚合/固化产生了引入许多离子键和金属的树脂，提供了各种性能，例如硬度，耐擦伤性，抗指纹性，阻气性，水蒸气阻隔性，氧吸收性，紫外线防护 红外线保护，显色和着色，高折射率，附着力，各种催化能力，荧光能力和发光能力，光学放大，分散性和抗静电性能。 此外，阴离子和盐可用于功能性细颗粒和金属纳米颗粒复合材料的原料，也可用于MOD材料。 所要求保护的发明还提供了制备二烯羧酸根阴离子及其盐的有利方法。

    DISPERSING AGENT FOR INORGANIC FILLERS AND METHOD OF PRODUCING SAME
    35.
    发明申请
    DISPERSING AGENT FOR INORGANIC FILLERS AND METHOD OF PRODUCING SAME 审中-公开
    无机填料的分散剂及其生产方法

    公开(公告)号：US20140080978A1

    公开(公告)日：2014-03-20

    申请号：US14081398

    申请日：2013-11-15

    Applicant: Takemoto Yushi Kabushiki Kaisha

    Inventor： Yuji Ohi ,  Makoto Hattori ,  Ippei Noda ,  Akira Miyano ,  Hironari Matsumoto

    IPC: C08F236/10 ,  C08F136/08 ,  C08F136/20

    CPC classification number: C08F236/10 ,  B60C1/00 ,  C08C19/20 ,  C08F136/06 ,  C08F136/08 ,  C08F136/20 ,  C08K3/013 ,  C08K3/36 ,  C08L7/00 ,  C08L9/00 ,  C08L15/00 ,  C08L21/00

    Abstract: The invention provides dispersing agents for inorganic fillers capable of uniformly dispersing inorganic fillers in a substrate such as made of a rubber or resin material such that molded products with improved mechanical strength and abrasion resistance can be produced from such a substrate material and more specifically that rubber compositions with improved abrasion resistance and workability can be obtained and that automobile tires with improved low fuel consumption and handling stability can be produced from such rubber compositions, as well as a method of producing such dispersing agents characterized as using a modified conjugated diene polymer obtained by introducing specified structural units with improved mutual reaction with inorganic fillers into a conjugated diene polymer having affinity with rubber and resin materials.

    Abstract translation: 本发明提供了能够将无机填料均匀分散在诸如由橡胶或树脂材料制成的基材中的无机填料的分散剂，使得可以由这种基材生产具有改善的机械强度和耐磨性的成型产品，更具体地说，橡胶 可以获得具有改进的耐磨性和可加工性的组合物，并且可以由这种橡胶组合物制备具有改善的低燃料消耗和操作稳定性的汽车轮胎，以及制备这种分散剂的方法，其特征在于使用由 将具有改善的与无机填料相互反应的指定结构单元引入具有与橡胶和树脂材料具有亲和性的共轭二烯聚合物中。

    SYNTHESIS OF METHYLENE MALONATES USING RAPID RECOVERY IN THE PRESENCE OF A HEAT TRANSFER AGENT
    36.
    发明申请
    SYNTHESIS OF METHYLENE MALONATES USING RAPID RECOVERY IN THE PRESENCE OF A HEAT TRANSFER AGENT 有权
    在热转印剂存在下使用快速回收合成甲基丙烯酸甲酯

    公开(公告)号：US20130281580A1

    公开(公告)日：2013-10-24

    申请号：US13880471

    申请日：2011-10-19

    Applicant: Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan ,  Yangbin Chen ,  Stanley C. Wojciak ,  Michael C. Cockrem

    Inventor： Bernard M. Malofsky ,  Adam G. Malofsky ,  Tanmoy Dey ,  Jeffrey M. Sullivan ,  Yangbin Chen ,  Stanley C. Wojciak ,  Michael C. Cockrem

    IPC: C08F122/14 ,  C08L35/02 ,  C08L47/00 ,  C08F136/20

    CPC classification number: C07C69/602 ,  C07C67/343 ,  C07C69/593 ,  C08F122/14 ,  C08F136/20 ,  C08G63/00 ,  C08L35/02 ,  C08L47/00 ,  C09D167/00 ,  Y02P20/127 ,  Y10T428/249921

    Abstract: The present invention provides a method of making a methylene malonate monomer that includes the steps of reacting a malonic acid ester with a source of formaldehyde optionally in the presence of an acidic or basic catalyst and optionally in the presence of an acidic or non-acidic solvent to form reaction complex. The reaction is optionally performed in the presence of or contacted with an energy transfer means such as a heat transfer agent, a heat transfer surface, a source of radiation or a laser such that reaction complex is substantially vaporized to produce a vapor phase comprising methylene malonate monomer which may be isolated. The present invention further provides methylene malonate monomers prepared by the method of the invention, as well as compositions and products formed from the methylene malonate monomers, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

    Abstract translation: 本发明提供一种制备亚甲基丙二酸单体的方法，其包括以下步骤：使丙二酸酯与甲醛源任选地在酸性或碱性催化剂存在下反应，并任选在酸性或非酸性溶剂存在下反应 形成反应复合物。 该反应任选地在诸如传热剂，传热表面，辐射源或激光的能量转移装置的存在或接触的情况下进行，使得反应复合物基本上蒸发以产生包含亚甲基丙二酸酯的气相 可以分离的单体。 本发明还提供了通过本发明方法制备的亚甲基丙二酸单体，以及由亚甲基丙二酸酯单体形成的组合物和产品，包括基于单体的产品（例如油墨，粘合剂，涂料，密封剂或反应性模塑）和聚合物 （如纤维，薄膜，薄片，医用聚合物，复合聚合物和表面活性剂）。

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