公开(公告)号：US06906115B2

公开(公告)日：2005-06-14

申请号：US10481772

申请日：2002-06-10

申请人： Makoto Hanazawa ,  Yasuo Itami

发明人： Makoto Hanazawa ,  Yasuo Itami

IPC分类号： C08G18/28 ,  C08G18/50 ,  C08G18/67 ,  C08G18/79 ,  C09D175/16 ,  C08G18/62

CPC分类号： C08G18/2885 ,  C08G18/5015 ,  C08G18/67 ,  C08G18/672 ,  C08G18/791 ,  C08G18/792 ,  C09D175/16 ,  Y10T428/3154

摘要： A perfluoropolyether-containing composition, which can easily conform to a fluorine-free substrate and can form a film on a surface of the substrate to fix the composition to the substrate surface, wherein the composition is a carbon-carbon double bond-containing composition comprising (A) a triisocyanate prepared by trimerizing a diisocyanate, and (B) a combination of at least two active hydrogen-containing compounds, and the component (B) comprises (B-1) a perfluoropolyether having at least one active hydrogen, and (B-2) a monomer having active hydrogen and a carbon-carbon double bond.

摘要翻译： 一种含全氟聚醚的组合物，其可以容易地符合无氟基材并且可以在基材的表面上形成膜以将组合物固定到基材表面，其中所述组合物是含碳 - 碳双键的组合物，其包含 （A）通过三异氰酸酯制备的三异氰酸酯和（B）至少两种含活性氢的化合物的组合，组分（B）包含（B-1）具有至少一个活性氢的全氟聚醚和（ B-2）具有活性氢和碳 - 碳双键的单体。

公开(公告)号：US20030153460A1

公开(公告)日：2003-08-14

申请号：US10255729

申请日：2002-09-25

发明人： Mitsunobu Morita ,  Kunio Hayakawa ,  Masafumi Torii ,  Mitsuru Naruse

IPC分类号： B41M005/24

CPC分类号： C08G18/8022 ,  B41M5/3331 ,  B41M2205/04 ,  C08G18/329 ,  C08G18/3821 ,  C08G18/791 ,  C08G18/798 ,  Y10S430/165

摘要： A thermosensitive recording material comprising a thermosensitive layer provided on a substrate, and the thermosensitive layer comprises as main ingredients a leuco dye and a developer to make colored state of said leuco dye when heated, wherein the developer is an oligomer composition obtained from the reaction of a polyvalent isocyanate compound represented by following Formula (I) with an aromatic amine represented by following Formula (II); 1 where X represents a try- or more-valent group, a represents an integer numeral of 3 or more, b and c represent respectively integer numerals in the range of 0 to 5 and they satisfy a relation of bnullcnull1 to 5, Z represents hydrogen atom, alkyl group, allyl group or aryl group, and the aryl group may include condensed ling structure thereof, and d represents an integer numeral in the range of 0 to 4. This developer shows excellent reliabilities of both image and background area, and also shows an excellent color-developing characteristics (color developing sensitivity and image density).

摘要翻译： 一种热敏记录材料，其包含设置在基材上的热敏层，并且所述热敏层包含作为主要成分的无色染料和显影剂，以在加热时形成所述无色染料的着色状态，其中所述显影剂是由 由下式（I）表示的多价异氰酸酯化合物与由下式（II）表示的芳族胺组成的多元异氰酸酯化合物; 其中X表示一价或多价基团，a表示3以上的整数，b和c分别表示0〜5的整数，并且满足b + c = 1〜5的关系， Z表示氢原子，烷基，烯丙基或芳基，芳基可以包括其缩合结构，d表示0〜4的整数。该显色剂显示出优异的图像和背景面积的可靠性 并且还显示出优异的显色特性（显色灵敏度和图像浓度）。

公开(公告)号：US5204391A

公开(公告)日：1993-04-20

申请号：US917739

申请日：1992-07-23

申请人： Yoshihiro Nakata ,  Hirohide Tomoyasu

发明人： Yoshihiro Nakata ,  Hirohide Tomoyasu

IPC分类号： C08G18/79 ,  C08G18/80 ,  C08L75/00 ,  C09D127/06

CPC分类号： C08G18/8067 ,  C08G18/791 ,  C09D127/06 ,  C08G2190/00 ,  C08L75/00

摘要： Provided are novel blocked polyisocyanurates to be suitably used as an adhesiveness providing agent, coating material, sealant and crosslinking agent for polymers containing active hydrogens. Also provided are polyvinyl chloride plastisol compositions comprising a polyvinyl chloride resin, the above blocked polyisocyanurate as an adhesiveness providing agent, plasticizer and a specific agent for accelerating dissociation of the blocked polyisocyanurate. These compositions have excellent properties such as high adhesiveness even cured at low temperatures and resistance to yellowing, and are suitably used particularly as sealants for car body.

摘要翻译： 提供了适合用作粘合性提供剂，涂料，密封剂和含活性氢聚合物的交联剂的新型封端聚异氰脲酸酯。 还提供了包含聚氯乙烯树脂，上述封闭的聚异氰脲酸酯作为粘合性提供剂的聚氯乙烯增塑溶胶组合物，增塑剂和用于促进封端的聚异氰脲酸酯的解离的特定试剂。 这些组合物具有优异的性能，例如即使在低温下固化并且耐黄变性的高粘附性，并且特别适合用作车体用密封剂。

公开(公告)号：US4900800A

公开(公告)日：1990-02-13

申请号：US73927

申请日：1987-07-15

申请人： Reinhard Halpaap ,  Josef Pedain ,  Hans-Joachim Kreuder ,  Gerhard Klein ,  Walter Schafer ,  Dieter Arlt

发明人： Reinhard Halpaap ,  Josef Pedain ,  Hans-Joachim Kreuder ,  Gerhard Klein ,  Walter Schafer ,  Dieter Arlt

IPC分类号： C08G18/72 ,  C08G18/02 ,  C08G18/16 ,  C08G18/73 ,  C08G18/79 ,  C08G18/80 ,  C09D5/03 ,  C09D5/46 ,  C09D175/00 ,  C09D175/04

CPC分类号： C08G18/8058 ,  C08G18/791 ,  C08G18/8009 ,  C08G2150/20

摘要： The present invention relates to a powder lacquer containing a mixture of(A) a polyisocyanate component in power form which is solid below about 40.degree. C. and liquid above about 150.degree. C. and(B) a organic polyhydroxyl component in powder form which is solid below about 40.degree. C. and liquid above about 150.degree. C.,components (A) and (B) being present in quantities corresponding to an equivalent ratio of isocyanate groups to hydroxyl groups of about 0.6:1 to 1.2:1, characterized in that component (A) is based on a polyisocyanate or polyisocyanate mixture which(a) does not contain any blocking agents for isocyanate groups,(b) has a content of free isocyanate groups (expressed as NCO) attached to tertiary, aliphatic or cycloaliphatic carbon atoms of about 8 to 24% by weight and an average NCO functionality of at least 2.1,(c) has a urethane group content (expressed as --NH--CO--O--) of about 3 to 30% by weight and(d) has an isocyanurate group content (expressed as C.sub.3 N.sub.3 O.sub.3) of 0 to about 30% by weight.The present invention also relates to the use of this powder lacquer for the production of coatings on heat-resistant substrates by methods known in powder lacquer technology.

摘要翻译： 本发明涉及一种粉末漆，其含有（A）固体低于约40℃的功率形式的多异氰酸酯组分和高于约150℃的液体的混合物和（B）粉末形式的有机多羟基组分， 固体低于约40℃，液体高于约150℃，组分（A）和（B）的存在量相当于异氰酸酯基与羟基的当量比为约0.6:1至1.2:1， 其特征在于组分（A）是基于多异氰酸酯或多异氰酸酯混合物，其中（a）不含任何异氰酸酯基团的封端剂，（b）具有连接到叔脂族或叔碳原子上的游离异氰酸酯基团（表示为NCO） 约8至24重量％的脂环族碳原子和平均NCO官能度至少为2.1，（c）具有约3至30重量％的氨基甲酸酯基含量（表示为-NH-CO-O-）和（ d）具有0至约的异氰脲酸酯基含量（表示为C 3 N 3 O 3） 30重量％。 本发明还涉及这种粉末漆用于通过粉末漆技术中已知的方法在耐热基材上生产涂层的用途。

公开(公告)号：US4888442A

公开(公告)日：1989-12-19

申请号：US910579

申请日：1986-09-23

申请人： Kenneth L. Dunlap ,  Peter H. Markusch ,  Clarence D. Ferrell

发明人： Kenneth L. Dunlap ,  Peter H. Markusch ,  Clarence D. Ferrell

IPC分类号： B01D1/22 ,  C08G18/10 ,  C08G18/78 ,  C08G18/79 ,  C08G18/80

CPC分类号： C08G18/8003 ,  B01D1/222 ,  C08G18/10 ,  C08G18/7831 ,  C08G18/791

摘要： The present invention is directed to a process for reducing the free monomer content of polyisocyanate adduct mixtures wherein the adduct has an average isocyanate functionality of greater than about 1.8 which comprises treating the polyisocyanate adduct mixture in the presence of 2 to about 30 percent by weight of an inert solvent, based on the weight of the polyisocyanate mixture, in an agitated thin-layer evaporator under conditions sufficient to reduce the free monomer content of the polyisocyanate adduct mixture below that level which is obtainable in the absence of a solvent.

摘要翻译： 本发明涉及一种降低多异氰酸酯加合物混合物的游离单体含量的方法，其中加合物的平均异氰酸酯官能度大于约1.8，该方法包括在2-30重量％的聚异氰酸酯加合物混合物存在下， 惰性溶剂，基于多异氰酸酯混合物的重量，在搅拌的薄层蒸发器中，条件足以将多异氰酸酯加合物混合物的游离单体含量降低到不存在溶剂时可获得的多异氰酸酯加合物混合物。

公开(公告)号：US4742129A

公开(公告)日：1988-05-03

申请号：US82654

申请日：1987-08-07

申请人： Panagiotis I. Kordomenos ,  Andrew H. Dervan ,  Dennis J. Grebur

发明人： Panagiotis I. Kordomenos ,  Andrew H. Dervan ,  Dennis J. Grebur

IPC分类号： C08G18/42 ,  C08G18/64 ,  C08G18/79 ,  C08G18/80 ,  C08G59/02 ,  C08G59/42 ,  C08G59/62 ,  C09D163/00 ,  C08G59/16 ,  C08G63/06 ,  C08G63/08 ,  C08G63/18

CPC分类号： C08G18/8061 ,  C08G18/4269 ,  C08G18/4294 ,  C08G18/6407 ,  C08G18/791 ,  C08G18/8009 ,  C08G59/02 ,  C08G59/4284 ,  C08G59/625 ,  C09D163/00

摘要： An organic solvent based, thermosetting coating composition of a hydroxy functional epoxy-polyester graft copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended substantially simultaneously with diphenol and dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.

摘要翻译： 羟基官能环氧 - 聚酯接枝共聚物和封端多异氰酸酯交联剂的有机溶剂型热固性涂料组合物。 涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适用于通过石头，砾石和其它道路碎屑破碎的身体面板区域上。 或者，组合物可以配制成可用常规喷雾设备喷雾的高固体成分。 羟基官能的环氧 - 聚酯接枝共聚物是通过在羟基官能的环氧酯树脂前体的存在下聚合内酯单体来制备的。 这种前体树脂通过基本上与二酚和二羧酸同时延长的双环氧化物链和用包含伯羟基官能酸的酸组分封端的链的反应形成。

公开(公告)号：US4714745A

公开(公告)日：1987-12-22

申请号：US877645

申请日：1986-06-23

申请人： Panagiotis I. Kordomenos ,  Andrew H. Dervan

发明人： Panagiotis I. Kordomenos ,  Andrew H. Dervan

IPC分类号： C08G18/42 ,  C08G18/79 ,  C08G18/80 ,  C08G59/12 ,  C08G59/42 ,  C08G59/64 ,  C08G63/08 ,  C09D163/00 ,  C08G63/20 ,  C08G59/16

CPC分类号： C08G18/791 ,  C08G18/4269 ,  C08G18/4294 ,  C08G18/8061 ,  C08G59/12 ,  C08G59/4284 ,  C08G59/64 ,  C08G63/08 ,  C09D163/00

摘要： A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and polyfunctional, hydroxy-reactive crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. The composition also may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of lactone monomers in presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the product of modified diepoxide and hydroxy functional secondary amine, the modified diepoxide being the product of the polymerization of lactone monomers in the presence of diepoxide which has been chain extended with dicarboxylic acid.

摘要翻译： 羟基官能的环氧 - 聚酯接枝共聚物和溶剂型热固性涂料组合物，其包含所述共聚物和多官能的羟基反应性交联剂。 涂料组合物可以配制成适合用作耐磨损的机动车底漆的可热喷涂的高固含量涂料组合物，适用于通过石头，砾石和其它道路碎屑破碎的车身面板区域上。 组合物还可以配制成可用常规喷雾设备喷雾的高固体组分。 羟基官能环氧 - 聚酯接枝共聚物是在羟基官能环氧酯树脂前体存在下内酯单体聚合的产物。 前体树脂是改性二环氧化物和羟基官能仲胺的产物，改性二环氧化物是在二羧酸链延长的二环氧化物存在下内酯单体聚合的产物。

公开(公告)号：US4703099A

公开(公告)日：1987-10-27

申请号：US909543

申请日：1986-09-22

申请人： Dale F. Regelman

发明人： Dale F. Regelman

IPC分类号： C07D295/02 ,  C08G18/02 ,  C08G18/16 ,  C08G18/79 ,  C08G18/08

CPC分类号： C07D295/02 ,  C07C255/00 ,  C07C265/00 ,  C07C265/12 ,  C08G18/022 ,  C08G18/168 ,  C08G18/791 ,  C08G2105/02 ,  Y10S521/902

摘要： Disclosed are novel compositions capable of catalytically trimerizing organic isocyanates said compositions comprising solutions of the reaction products obtained by reacting in an inert solvent in substantially equimolar proportions electron-rich ketene-aminals with electron-poor olefins having the respective formulae (I) and (II) ##STR1## The variously substituted electron-rich ketene-aminals (I), as the name implies, have high electron density associated with the double bond because of the two tertiary amine groups while the electron-poor olefins (II) have the opposite situation due to the presence of electron withdrawing substituents R.sub.9 and R.sub.10.Also disclosed is an improved process for trimerizing organic isocyanates using the above catalyst compositions including the preparation of polyisocyanurate polymers and isocyanurate-modified polyisocyanates.

摘要翻译： 公开了能够催化三聚有机异氰酸酯的新型组合物，所述组合物包含通过在惰性溶剂中基本上等摩尔比例的富含电子的乙烯酮 - 胺与具有各自式（I）和（II）的电子不足烯烃反应而获得的反应产物的溶液 （I）如下所述，不同取代的富电子酮乙烯酮（I）由于两个叔胺基团而具有与双键相关的高电子密度，而电子 由于吸电子取代基R9和R10的存在，α-烯烃（II）具有相反的情况。 还公开了使用上述催化剂组合物三聚有机异氰酸酯的改进方法，包括制备聚异氰脲酸酯聚合物和异氰脲酸酯改性的多异氰酸酯。

公开(公告)号：US4699958A

公开(公告)日：1987-10-13

申请号：US800944

申请日：1985-11-22

申请人： Panagiotis I. Kordomenos ,  Andrew H. Dervan ,  Dennis J. Grebur

发明人： Panagiotis I. Kordomenos ,  Andrew H. Dervan ,  Dennis J. Grebur

IPC分类号： C08G18/40 ,  C08G18/64 ,  C08G18/79 ,  C08G18/80 ,  C08G63/66 ,  C08L63/02

CPC分类号： C08G18/4081 ,  C08G18/6407 ,  C08G18/791 ,  C08G18/8009 ,  C08G18/8061

摘要： A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy resin is formed by reaction of diepoxide, previously chain extended with diphenol, with hydroxy functional secondary amine in chain terminating reaction.

摘要翻译： 一种溶剂型热固性涂料组合物，其包含羟基官能环氧树脂，线性聚己内酯二醇和封端的多异氰酸酯交联剂。 涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适合用于通过石头，砾石和其它道路碎屑破碎的身体面板区域上。 或者，组合物可以配制成可用常规喷雾设备喷雾的高固体组分。 羟基官能环氧树脂通过在链终止反应中与预先延伸的双酚的双环氧化物与羟基官能的仲胺反应而形成。

公开(公告)号：US4699955A

公开(公告)日：1987-10-13

申请号：US800886

申请日：1985-11-22

申请人： Panagiotis I. Kordomenos ,  Andrew H. Dervan ,  Dennis J. Grebur

发明人： Panagiotis I. Kordomenos ,  Andrew H. Dervan ,  Dennis J. Grebur

IPC分类号： C08G18/40 ,  C08G18/42 ,  C08G18/46 ,  C08G18/64 ,  C08G18/79 ,  C08G18/80 ,  C08G63/18 ,  C08L63/02

CPC分类号： C08G18/8061 ,  C08G18/4081 ,  C08G18/4202 ,  C08G18/4294 ,  C08G18/4615 ,  C08G18/6407 ,  C08G18/791 ,  C08G18/8009

摘要： A solvent based thermosetting coating composition comprising hydroxy functional epoxy ester resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is formed by reaction of diepoxide, chain extended with diphenol and dicarboxylic acid, with hydroxy functional secondary amine in chain terminating reaction.

摘要翻译： 一种溶剂型热固性涂料组合物，其包含羟基官能环氧酯树脂，线性聚己内酯二醇和封端的多异氰酸酯交联剂。 该涂料组合物可以配制成适合用作抗碎屑机动车辆底漆的可热喷涂的高固含量涂料组合物，适合用于通过石头，砾石和其它道路碎屑破碎的车身面板区域上。 或者，组合物可以配制成可用常规喷雾设备喷雾的高固体组分。 羟基官能环氧酯树脂通过双环氧化物，延伸与二酚和二羧酸的链与羟基官能仲胺在链终止反应中反应而形成。