MULTIFUNCTIONAL SCAVENGER FOR HYDROCARBON FLUIDS
    42.
    发明申请
    MULTIFUNCTIONAL SCAVENGER FOR HYDROCARBON FLUIDS 有权
    多用途液化石油气净化器

    公开(公告)号:US20090095658A1

    公开(公告)日:2009-04-16

    申请号:US12250679

    申请日:2008-10-14

    Abstract: Compounds having the formulae and general formulae: wherein each R1, R2, R3 and R4 are the same or different and may be hydrogen, an alkyl group, an aryl group, a halogen, a nitro group, an alkyl or aryl ester, and an alkyl or aryl ether; compounds having the general formula: wherein R is an alkyl, aryl or electron withdrawing group; mixtures thereof; can be used as additives for crude oil and hydrocarbons. These compounds may be used to scavenge mercaptans, sulfides, cyanides, and primary or secondary amines; either alone or in combination.

    Abstract translation: 具有通式和通式的化合物:其中每个R 1,R 2,R 3和R 4相同或不同,可以是氢,烷基,芳基,卤素,硝基,烷基或芳基酯,和 烷基或芳基醚; 具有以下通式的化合物:其中R是烷基,芳基或吸电子基团; 其混合物; 可用作原油和碳氢化合物的添加剂。 这些化合物可用于清除硫醇,硫化物,氰化物和伯胺或仲胺; 单独或组合。

    Method for Improving Liquid Yield During Thermal Cracking of Hydrocarbons
    43.
    发明申请
    Method for Improving Liquid Yield During Thermal Cracking of Hydrocarbons 有权
    提高碳氢化合物热裂解过程中液体产率的方法

    公开(公告)号:US20090020455A1

    公开(公告)日:2009-01-22

    申请号:US12197791

    申请日:2008-08-25

    CPC classification number: C10B57/06 C10B55/00 C10G9/005

    Abstract: Metal additives to hydrocarbon feed streams give improved hydrocarbon liquid yield during thermal cracking thereof. Suitable additives include metal overbases and metal dispersions and the metals suitable include, but are not necessarily limited to, magnesium, calcium, barium, strontium, aluminum, boron, zinc, silicon, cerium, titanium, zirconium, chromium, molybdenum, tungsten, and/or platinum, overbases and dispersions. Particularly useful metals include magnesium alone or magnesium together with calcium, barium, strontium, boron, zinc, silicon, cerium, titanium, zirconium, chromium, molybdenum, tungsten, and/or platinum. In one non-limiting embodiment, no added hydrogen is employed. Coker feedstocks and visbreaker feeds are particular hydrocarbon feed streams to which the method can be advantageously applied, but the technique may be used on any hydrocarbon feed that is thermally cracked.

    Abstract translation: 碳氢化合物进料流的金属添加剂在其热裂解期间提供了改善的烃液体产率。 合适的添加剂包括金属高碱性物和金属分散体,适合的金属包括但不限于镁,钙,钡,锶,铝,硼,锌,硅,铈,钛,锆,铬,钼,钨和 /或铂,过碱性和分散体。 特别有用的金属包括单独的镁或镁,以及钙,钡,锶,硼,锌,硅,铈,钛,锆,铬,钼,钨和/或铂。 在一个非限制性实施方案中,不使用加入的氢。 Coker原料和减粘剂进料是可以有利地应用该方法的特定烃进料流,但是该技术可以用于任何热裂化的烃进料。

    METHOD FOR IMPROVING BIODIESEL FUEL
    44.
    发明申请
    METHOD FOR IMPROVING BIODIESEL FUEL 有权
    改善生物柴油燃料的方法

    公开(公告)号:US20080282605A1

    公开(公告)日:2008-11-20

    申请号:US11749853

    申请日:2007-05-17

    Abstract: The addition of strong neutralizing amines to react with free fatty acid in biodiesel fuels that may be left from some synthesis routes can lower the total acid number (TAN) of the biodiesel fuel. Surprisingly, the strong neutralizing amines do not interfere with the biodiesel fuel itself which may be primarily fatty acid methyl esters. These strong neutralizing amines may also improve the oxidative stability of biodiesel fuels.

    Abstract translation: 在一些合成途径中残留的生物柴油燃料中加入强中和胺与游离脂肪酸反应可以降低生物柴油燃料的总酸值(TAN)。 令人惊奇的是,强中和胺不会干扰生物柴油本身,它本来可以主要是脂肪酸甲酯。 这些强中和胺还可以改善生物柴油燃料的氧化稳定性。

    METHOD OF SCAVENGING MERCAPTANS FROM HYDROCARBONS
    45.
    发明申请
    METHOD OF SCAVENGING MERCAPTANS FROM HYDROCARBONS 审中-公开
    从碳氢化合物中萃取麦芽糖的方法

    公开(公告)号:US20080230445A1

    公开(公告)日:2008-09-25

    申请号:US12042536

    申请日:2008-03-05

    Abstract: Hydrogen sulfide and mercaptans in hydrocarbons, gas mixtures of hydrocarbons and the like may be scavenged therefrom by being brought into intimate contact with a mercaptan scavenger formulation of quaternary ammonium alkoxide or hydroxide in the presence of a high oxidative state metal such as cobalt, iron, chromium and/or nickel. The high oxidative state metal, being an oxidizer, acts as a catalyst when combined with the quaternary ethoxide or hydroxide for improved mercaptan scavenging performance.

    Abstract translation: 烃类中的硫化氢和硫醇,碳氢化合物的气体混合物等可以通过在高氧化态金属如钴,铁等的存在下与硫醇季铵盐或氢氧化物的硫醇清除剂配方紧密接触而被清除, 铬和/或镍。 作为氧化剂的高氧化态金属与季戊四醇或氢氧化物结合时用作催化剂,以改善硫醇清除性能。

    Process for Removing Nickel and Vanadium From Hydrocarbons
    46.
    发明申请
    Process for Removing Nickel and Vanadium From Hydrocarbons 审中-公开
    从碳氢化合物中除去镍和钒的工艺

    公开(公告)号:US20080179221A1

    公开(公告)日:2008-07-31

    申请号:US12019276

    申请日:2008-01-24

    CPC classification number: C10G31/08 C10G21/00 C10G29/08

    Abstract: Nickel and/or vanadium can be removed or transferred from a hydrocarbon phase to a water phase using an Extractant Composition selected from an isocyanate, a thiocyanate, a cyanides, mercaptides, nitrites, and mixtures thereof. The Extractant Composition may also include at least one mineral acid, a solvent, and other additives. The invention permits transfer of vanadium and nickel from a hydrocarbon into an aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase. The composition is particularly useful in treating crude oil.

    Abstract translation: 可以使用选自异氰酸酯,硫氰酸酯,氰化物,硫醇盐,亚硝酸盐及其混合物的萃取剂组合物将烃和/或钒从烃相移除到水相中。 萃取剂组合物还可以包括至少一种无机酸,溶剂和其它添加剂。 本发明允许将钒和镍从烃转移到含有少量或不含烃相的水相中进入水相。 该组合物特别可用于处理原油。

    Fatty acid amide lubricity aids and related methods for improvement of lubricity of fuels
    47.
    发明授权
    Fatty acid amide lubricity aids and related methods for improvement of lubricity of fuels 失效
    脂肪酸酰胺润滑助剂及相关的改善燃料润滑性的方法

    公开(公告)号:US06562086B1

    公开(公告)日:2003-05-13

    申请号:US08883634

    申请日:1997-06-26

    Abstract: A fuel composition of improved lubricity comprises a lubricity-increasing amount of a lubricity aid dissolved in low sulfur diesel fuel and spark ignition fuels. The lubricity aid is an alkanolamide of a fatty acid, an alkanolamide of a modified fatty acid or a mixture thereof. If the lubricity aid is other than an alkanolamide of an aryl-substituted fatty acid, the composition further necessarily comprises a haze-inhibiting amount of a dehazer. The lubricity of such fuels may be enhanced without acceptably increasing the tendency of the fuel to become hazy upon contact with water.

    Abstract translation: 具有改善的润滑性的燃料组合物包括溶解在低硫柴油燃料和火花点燃燃料中的润滑增加量的润滑助剂。 润滑助剂是脂肪酸的链烷醇酰胺,改性脂肪酸的链烷醇酰胺或其混合物。 如果润滑助剂不是芳基取代的脂肪酸的链烷醇酰胺,则组合物还必须包含雾度抑制量的除雾剂。 这种燃料的润滑性可以增强,而不会可接受地增加燃料在与水接触时变得模糊的倾向。

    Quaternary ammonium hydroxides as mercaptan scavengers

    公开(公告)号:US5840177A

    公开(公告)日:1998-11-24

    申请号:US931675

    申请日:1997-09-16

    CPC classification number: C10G29/20 C07C213/04

    Abstract: A method for scavenging mercaptans in a hydrocarbon fluid is disclosed. According to the method, an effective mercaptan-scavenging amount of an aqueous scavenging composition is added to the fluid. The composition comprises a quaternary ammonium hydroxide of the formula R.sup.1 R.sup.2 R.sup.3 R.sup.4 NOH. R.sup.1 and R.sup.2 are, independently, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. R.sup.3 is an alkyl group of from two to about eighteen carbon atoms, an aryl group of from two to about eighteen carbon atoms or an alkylaryl group of from four to about eighteen carbon atoms. R.sup.2 and R.sup.3 may be joined to form a heterocyclic ring including the N and optionally an oxygen atom. R.sup.4 is --(CH.sub.2 CH.sub.2 O).sub.n H, wherein n is an integer from one to about eighteen, or --CHR.sup.5 CHR.sup.6 Y, wherein R.sup.5 and R.sup.6 are, independently, hydrogen, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. Y is a non-acidic group. Related compositions and methods are also disclosed.

    Use of olefinic imines to scavenge sulfur species
    49.
    发明授权
    Use of olefinic imines to scavenge sulfur species 失效
    使用烯属亚胺清除硫物质

    公开(公告)号:US5567212A

    公开(公告)日:1996-10-22

    申请号:US430208

    申请日:1995-04-27

    CPC classification number: C10L1/2283 C09K8/532 C10G29/20

    Abstract: A method for scavenging sulfur species from a petroleum-derived medium is disclosed. The method comprises contacting the medium with sulfur species scavenging amount of an imine of the formula ##STR1## wherein x is an integer from 1 to 10, R' is an organic moiety having a number of valences equal to x, R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In an alternative embodiment, the imine is produced by a condensation reaction between an amine having at least one primary amino group and a carbonyl of the formula ##STR2## wherein R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In yet other embodiments, the imine is produced by a condensation reaction between an amine having at least one primary amino group and an aldehyde having at least one alpha-hydrogen in an aldehyde to primary amino group molar ratio of at least about 2:1, are also disclosed.

    Abstract translation: 公开了一种从石油衍生的介质中清除硫物质的方法。 该方法包括使培养基与清除硫的物质接触式为式的亚胺,其中x是1至10的整数,R'是具有等于x的价数的有机部分,R 1是氢或 一价有机部分,R是一价烯烃部分,条件是R和R 1含有总共约4至约40个碳原子。 在另一个实施方案中,亚胺是通过具有至少一个伯氨基的胺和式的羰基之间的缩合反应产生的,其中R1是氢或一价有机部分,R是一价的 烯烃部分,条件是R和R 1含有总共约4至约40个碳原子。 在其它实施方案中,亚胺通过具有至少一个伯氨基的胺与具有至少一个α-羟基的醛与醛与伯氨基摩尔比至少约2:1的缩合反应产生, 也被披露。

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